Journal
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 22, Issue 8, Pages 5686-5698Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-014-3526-z
Keywords
Ecocatalysis; Bio-based chemistry; Protecting groups; Metal hyperaccumulating plants; Phytoextraction
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Funding
- Agence Nationale de la Recherche [ANR 11ECOT 011 01]
- Centre National de la Recherche Scientifique (CNRS)
- Agence de l'Environnement et de la Maitrise de l'Energie (ADEME)
- Fond Europeen de Developpement Regional (FEDER) program
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We propose for the first time using metal hyperaccumulating plants for the construction of a repertoire of protection and deprotection conditions in a concept of orthogonal sets. Protection of alcohol, carbonyl, carboxyl, and amino groups are considered. The ecocatalysts derived from metal-rich plants allow selective, mild, eco-friendly, and efficient protection or deprotection reactions. The selectivity is controlled by the choice of the metal, which is hyperaccumulated by the metallophyte.
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