Article
Geochemistry & Geophysics
Pradeep Reddy Punnam, Balaji Krishnamurthy, Vikranth Kumar Surasani
Summary: Carbon capture and sequestration (CCS) technology is an important alternative for reducing CO2 emissions. Geologic carbon sequestration (GCS) involves injecting CO2 into deep geological formations for long-term storage. The study shows that the morphology of the top surface caprock has an influence on the solubility trapping mechanism.
Article
Geochemistry & Geophysics
Pradeep Reddy Punnam, Balaji Krishnamurthy, Vikranth Kumar Surasani
Summary: The study investigates the influence of top surface caprock morphology on the solubility trapping mechanism in geological carbon sequestration. Simulation results indicate that the geological formations with complex structures impact the solubility trapping phenomena and entrapment percentage over time scales. These findings highlight the importance of caprock morphology in solubility trapping and injection rate selection.
Article
Engineering, Civil
Ayon Kumar Das, Hassan Hassanzadeh
Summary: This study presents a novel mathematical model that considers both brine invasion and abandoned well flow in subsurface CO2 storage. The model evaluates the leakage rate across abandoned well segments and provides a higher degree of certainty in determining the radial coordinates of abandoned wells. The study finds that the leakage rate decreases with an increase in permeability ratio and the reduction is greater in late times. This research is important for accurately modeling old-well leakage and has practical implications for CO2 storage.
JOURNAL OF HYDROLOGY
(2023)
Review
Geosciences, Multidisciplinary
Faizan Ali, Berihun Mamo Negash, Syahrir Ridha, Hesham Abdulelah
Summary: This study provides an overview of research on wettability and interfacial tension in the shale-CO2-brine system, as well as the investigation of representative caprock minerals. It highlights the potential adverse effects of long-term CO2 interaction with clay-rich shale on wettability and interfacial tension, and the possibility of altering shale characteristics through the use of nanoparticles and surfactants. The study also identifies knowledge gaps in the understanding of acidic conditions caused by CO2 dissolution and the presence of free water in CO2-shale interactions, and recommends further research in these areas.
EARTH-SCIENCE REVIEWS
(2023)
Article
Energy & Fuels
Oladoyin Kolawole, Ion Ispas, Mallika Kumar, Joachim Weber, Bo Zhao, Giovanni Zanoni
Summary: This study investigated how localized and bulk biogeomechanical alterations induced by microbial processes in shale formations can enhance the long-term caprock integrity and CO2 storage security, providing valuable insights for solving challenges in the long-term geological CO2 storage application in depleted hydrocarbon reservoirs.
Article
Engineering, Geological
Ameh Peter, Xiaoqiang Jin, Xianfeng Fan, Kenneth Imo-Imo Eshiet, Yong Sheng, Dongmin Yang
Summary: This research used digital rock physics to evaluate the pore geometry properties of rocks saturated with different phases of CO2-brine under reservoir conditions. The results show that the phase of CO2 significantly affects the porosity and pore surface characteristics, providing valuable information for simulating CO2 storage in reservoir rocks.
ROCK MECHANICS AND ROCK ENGINEERING
(2022)
Review
Energy & Fuels
Dorcas S. Eyinla, Smith Leggett, Foued Badrouchi, Hossein Emadi, Olajide J. Adamolekun, Olumuyiwa T. Akinsanpe
Summary: Enhanced oil recovery (EOR) through carbon dioxide (CO2) injection is a crucial technique for decarbonization. It involves injecting CO2 into hydrocarbon reservoirs to increase oil recovery. CO2-EOR has proven effective in enhancing oil recovery and reducing greenhouse gas emissions by sequestering CO2 in reservoirs. However, CO2 injection can react with rock minerals and water, altering petrophysical properties and potentially reducing performance and storage integrity.
Article
Chemistry, Multidisciplinary
Hasanthi L. Senevirathna, Shunnian Wu, Cathie Lee, Jin-Young Kim, Sang Sub Kim, Kewu Bai, Ping Wu
Summary: The formation of MgCO3 hampers CO2 capture efficiency in MgO. By engineering the MgO/Mg(OH)(2) interfaces with Cl-, SO42-, and PO43- additives, a novel MgO-Mg(OH)(2)-MgCl2 composite with enhanced CO2 adsorption and stability was synthesized. This breakthrough paves the way for effective strategies to overcome CO2 transport barriers in MgO-based adsorbents.
Article
Engineering, Geological
Dawei Zhou, Guangqing Zhang, Zhongwei Huang, Jianlin Zhao, Linlin Wang, Renyi Qiu
Summary: The study investigates the changes in microstructure and mechanical properties of shale exposed to supercritical CO2, showing that the mechanical properties of shale are significantly altered by microstructural variations induced by strong interactions between CO2-rich fluid and rock minerals.
INTERNATIONAL JOURNAL OF ROCK MECHANICS AND MINING SCIENCES
(2022)
Article
Energy & Fuels
Arman Najafi, Javad Siavashi, Mohammad Ebadi, Denis Orlov, Mohammad Sharifi, Jalal Fahimpour, Mostafa Keshavarz Moraveji, Dmitry Koroteev
Summary: Global warming is considered a severe crisis in the coming years, and Carbon Capture and Storage (CCS) has been proposed as a feasible solution. For the successful implementation of CCS, it is crucial to understand the relevant mechanisms, particularly the multiphase flow. Relative permeability is recognized as a parameter to describe the physics of multiphase flow. However, previous studies have shown that microscopic phenomena strongly influence relative permeability data. This research uses micro X-ray Computed Tomography (mu xCT) and Computational Fluid Dynamics (CFD) to analyze the impact of pore geometry on relative permeability data.
Article
Green & Sustainable Science & Technology
Raoof Gholami, Arshad Raza, Pal Andersen, Alejandro Escalona, Nestor Cardozo, Dora Marin, Mohammad Sarmadivaleh
Summary: Many studies have been conducted to evaluate the long-term integrity of seals in CO2 storage sites, focusing on the geochemical reactions, mineral transformations, and surface wettability alterations that may occur. This study specifically examined changes in mineralogy and surface wettability of shales exposed to supercritical CO2 for 6 months, finding that quartz dissolution and kaolinite precipitation can be induced in the presence of CO2. The study suggests that maintaining water wettability of clay surfaces in storage sites is important to prevent CO2 migration. Further research is needed to ensure the integrity of seals in storage sites during and after injection.
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2021)
Article
Energy & Fuels
Amir Jahanbakhsh, Qi Liu, Mojgan Hadi Mosleh, Harshit Agrawal, Nazia Mubeen Farooqui, Jim Buckman, Montserrat Recasens, Mercedes Maroto-Valer, Anna Korre, Sevket Durucan
Summary: The study aimed to investigate the interactions between CO2-brine and cement-caprock/reservoir rock through a series of experiments simulating deep wellbore environments. The results showed significant changes in permeability and mechanical properties of the composite samples after exposure to CO2-rich brine.
Article
Geosciences, Multidisciplinary
Elizabeth T. Baruch, Stefan C. Lohr, Shujun Han, David N. Dewhurst, Alan S. Collins
Summary: The thermal maturity gradient approach is commonly used to study the evolution of pore systems in mudrocks. However, regional variations in depositional controls can lead to unrecognized microtextural differences between samples, making it difficult to isolate the effects of thermal alteration. We used samples from the siliceous Woodford Shale to emphasize the importance of sample screening in pore evolution characterization studies.
MARINE AND PETROLEUM GEOLOGY
(2023)
Article
Energy & Fuels
Si-Yong Lee, Farid Reza Mohamed, Kwang-Ho Lee, Brian Mcpherson, Robert Balch, Sangcheol Yoon
Summary: This study focuses on the probabilistic uncertainty assessment of geomechanical risk, specifically caprock failure due to CO2 injection. The study utilizes a multilaminate model, response surface model, numerical modeling experiments, and Monte Carlo simulations to evaluate the risk. The findings highlight the importance of the Young modulus and mechanical strength properties in determining caprock integrity, and introduce the F value as a reliable indicator for caprock failure.
Article
Energy & Fuels
Richard Seely, Thomas J. Liddy, Christopher A. Rochelle, Robin S. Fletcher, Sean P. Rigby
Summary: This study provides a detailed analysis of the structural and chemical changes in the Nordland shale caused by exposure to supercritical carbon dioxide. The use of a novel iodononane pre-adsorption technique allows for the identification and mapping of different pore networks in the shale. The findings suggest that both small and large-sized pore networks are present in the shale and are associated with the illite matrix phase.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Green & Sustainable Science & Technology
Pratanu Roy, Joseph P. Morris, Stuart D. C. Walsh, Jaisree Iyer, Susan Carroll
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2018)
Article
Green & Sustainable Science & Technology
Yue Hao, Megan M. Smith, Susan A. Carroll
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2019)
Article
Green & Sustainable Science & Technology
Harris E. Mason, Megan M. Smith, Susan A. Carroll
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2019)
Article
Green & Sustainable Science & Technology
Megan M. Smith, Yue Hao, Lee H. Spangler, Kristin Lammers, Susan A. Carroll
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2019)
Article
Green & Sustainable Science & Technology
Xianjin Yang, Thomas A. Buscheck, Kayyum Mansoor, Zan Wang, Kai Gao, Lianjie Huang, Delphine Appriou, Susan A. Carroll
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2019)
Article
Engineering, Environmental
Jaisree Iyer, Xiao Chen, Susan A. Carroll
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2020)
Review
Green & Sustainable Science & Technology
Signe White, Susan Carroll, Shaoping Chu, Diana Bacon, Rajesh Pawar, Lydia Cumming, Jared Hawkins, Mark Kelley, Inci Demirkanli, Richard Middleton, Joel Sminchak, Ashwin Pasumarti
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2020)
Article
Green & Sustainable Science & Technology
Thomas A. Buscheck, Kayyum Mansoor, Xianjin Yang, Haruko M. Wainwright, Susan A. Carroll
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2019)
Article
Engineering, Environmental
Elvia A. Chavez Panduro, Benoit Cordonnier, Kamila Gawel, Ingrid Borve, Jaisree Iyer, Susan A. Carroll, Leander Michels, Melania Rogowska, Jessica Ann McBeck, Henning Osholm Sorensen, Stuart D. C. Walsh, Francois Renard, Alain Gibaud, Malin Torsaeter, Dag W. Breiby
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2020)
Article
Energy & Fuels
J. T. Birkholzer, J. Morris, J. R. Bargar, F. Brondolo, A. Cihan, D. Crandall, H. Deng, W. Fan, W. Fu, P. Fu, A. Hakala, Y. Hao, J. Huang, A. D. Jew, T. Kneafsey, Z. Li, C. Lopano, J. Moore, G. Moridis, S. Nakagawa, V Noel, M. Reagan, C. S. Sherman, R. Settgast, C. Steefel, M. Voltolini, W. Xiong, J. Ciezobka
Summary: This paper introduces a new modeling framework for simulating hydraulic fracturing and production from microscopic to reservoir scales, which combines high-performance simulators and laboratory scale studies. The framework is currently being tested using field data and core samples from the HFTS. This approach aims to incorporate micro-scale processes into reservoir-scale simulations for enhanced accuracy.
Article
Green & Sustainable Science & Technology
K. Rhino, J. Iyer, S. D. C. Walsh, S. A. Carroll, M. M. Smith
Summary: The study showed that the nature and rates of chemical reactions between cement and CO2 were not affected by effective stress. The observed permeability responses were interpreted in terms of competition between dissolution of cement phases (leading to enhanced permeability) and mechanical deformation of reacted regions (leading to reduced permeability). This research contributes to a better understanding of the alteration of wellbore cement under conditions relevant to geologic carbon storage.
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
(2021)
Article
Engineering, Chemical
Yunwei Sun, Charles Carrigan, William Cassata, Yue Hao, Souheil Ezzedine, Tarabay Antoun
Summary: Isotopic ratios of radioactive xenons can be used to detect underground nuclear explosions and civilian nuclear reactors. Differences in half-lives of the decay chains result in time-dependent concentrations of xenon isotopes. Modern detection capabilities and contrasting timescales make xenon isotopes a desirable surrogate for UNE detection.
TRANSPORT IN POROUS MEDIA
(2021)
Article
Nanoscience & Nanotechnology
Jeremy A. Scher, Stephen E. Weitzner, Yue Hao, Tae Wook Heo, Stephen T. Castonguay, Sylvie Aubry, Susan A. Carroll, Matthew P. Kroonblawd
Summary: Bare aluminum surfaces quickly form a protective oxide layer, but the structure and dynamics of water at this interface can influence corrosion kinetics. Using simulations, we studied the behavior of aqueous aluminum ions in adsorbed water films on aluminum oxide surfaces. We found that water and metal ion diffusion strongly depends on humidity and location within the water film. The diffusivity of aluminum ions in water films at 30% relative humidity is over 100 times slower than water self-diffusion in bulk. Our findings emphasize the importance of considering interfacial water properties in predictive models of aluminum corrosion.
ACS APPLIED MATERIALS & INTERFACES
(2023)