4.8 Article

Acidification and Buffering Mechanisms in Acid Sulfate Soil Wetlands of the Murray-Darling Basin, Australia

Journal

ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 45, Issue 7, Pages 2591-2597

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/es103535k

Keywords

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Funding

  1. National Water Commission
  2. Australian Government
  3. NSW Murray Wetlands Working Group
  4. Murray-Darling Freshwater Research Centre

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The acid generation mechanisms and neutralizing capacities of sulfidic sediments from two inland wetlands have been studied in order to understand the response of these types of systems to drying events. The two systems show vastly different responses to oxidation, with one (Bottle Bend (BB) lagoon) having virtually no acid neutralizing capacity (ANC) and the other (Psyche Bend (PB) lagoon) an ANC that is an order of magnitude greater than the acid generation potential. While BB strongly acidifies during oxidation the free acid generation is less than that expected from the measured proton production and consumption processes, with additional proton consumption attributed to the formation of an acid-anion (chloride) Fe-III (oxyhydr)oxide product, similar to akaganeite (Fe(OH)(2.7)Cl-0.3). While such products can partially attenuate the acidification of these systems, resilience to acidification is primarily imparted by sediment ANC.

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