Journal
ENVIRONMENTAL MONITORING AND ASSESSMENT
Volume 184, Issue 9, Pages 5829-5839Publisher
SPRINGER
DOI: 10.1007/s10661-012-2550-z
Keywords
Organic phosphorus; Sediment; Lake; Fractionation; P-31 NMR
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Funding
- National Basic Research Program of China (973 Project) [2006CB403303]
- National Science Foundation for Distinguished Young Scholars [50625926]
- National Water Pollution Control and Treatment Project [2008ZX07209-009]
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Organic phosphorus (OP) species in sediments of the Baiyangdian Lake in China was investigated via fractionation and phosphorus-31 nuclear magnetic resonance (P-31 NMR) spectroscopy. Results of chemical fractionation showed that different OP fractions ranked in the order: humic acid-P > HCl-OP > fulvic acid-P a parts per thousand aEuro parts per thousand NaHCO3-OP > residual OP. Labile OP and moderately labile OP, which can be degraded for phytoplankton uptake, contributed to 58.7-68.5% of total extracted OP, indicative of the potential P release from sediments in the lake. P-31 NMR spectroscopy results suggested the rank order of P species present in the NaOH-EDTA extractant of the sediments: orthophosphate > monoester-P > DNA-P > pyrophosphate-P. Phytate, polyphosphates, and phosphonates, which appeared in sediments of some deeper lakes, were not detected in the shallow lake. Significant correlations were identified between total P (TP) in water column and sediment TP, monoester-P and DNA-P, positively indicating that sediment P species, especially OP components, should probably contribute to the contents of P in water column and further to the lake eutrophication.
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