Journal
ENVIRONMENTAL ENGINEERING SCIENCE
Volume 26, Issue 4, Pages 849-859Publisher
MARY ANN LIEBERT, INC
DOI: 10.1089/ees.2008.0277
Keywords
iron; citrate; TCE droplet; DNAPL; groundwater; hydroxyl radical
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Funding
- NIEHS/SBRP [P42ES007380]
- NSF-IGERT,
- DOE-KRCEE [DE-FG05-03OR2302]
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The primary objective of this research was to model and understand the chelate-modified Fenton reaction for the destruction of trichloroethylene (TCE) present in both the aqueous and organic (in the form of droplets) phases. The addition of a nontoxic chelate (L), such as citrate or gluconic acid, allows for operation at near-neutral pH and controlled release of Fe(II)/Fe(III). For the standard Fenton reaction at low pH in two-phase systems, an optimum H2O2:Fe(II) molar ratio was found to be between 1:1 and 2:1. Experimentation proved the chelate-modified Fenton reaction effectively dechlorinated TCE in both the aqueous and organic phases at pH 6-7 using low H2O2: Fe(II) molar ratios (4:1 to 8:1). Increasing the L: Fe ratio was found to decrease the rate of H2O2 degradation in both Fe(II) and Fe(III) systems at near-neutral pH. Generalized models were developed to predict the concentration of TCE in the aqueous phase and TCE droplet radius as a function of time using literature-reported hydroxyl radical reaction kinetics and mass transfer relationships. Additional aspects of this work include the reusability of the Fe-citrate complex under repeated H2O2 injections in real water systems as well as packed column studies for simulated groundwater injection.
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