Problems with Sb analysis of environmentally relevant samples

Antimony is found in elevated concentrations in the roadside environment, industrial sites and generally in urban areas. An extended use of multielement analysis has produced more concentration data for metals in the environment. However, volatilisation of elements in the digestion step may be a problem as some of the certified and recommended digestion methods are performed in open vessels. The aim of the current study was to focus on wet digestion-derived problems for the analysis of volatile elements, with specific reference to Sb. Both soils and products, namely tyres and brake linings, were sampled. The samples were digested using different methods with variations in temperature, acid mix, and the use of open or closed vessels. For some methods, the recovery was <10%, indicating a need for revision of certified and recommended digestion procedures. For a multielement analysis, a closed vessel method must be used. If the aim is to study only Sb, a wet-digestion method optimised for Sb is the natural choice. This may be valuable to consider when handling environmentally relevant samples such as soils contaminated with Sb from point or diffuse sources.