Journal
ENERGY & FUELS
Volume 29, Issue 1, Pages 122-129Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ef5022413
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Funding
- National Science and Technology Major Project [2011ZX05026-004]
- National 973 Project of China [2012CB215005]
- National Natural Science Foundation of China [U1162205, 51376195]
- Science Foundation of China University of Petroleum, Beijing [2462013YXBS004]
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The feasibility of evaluating the performance of anti-agglomerants from analyzing the variation of morphologies and chord length of particles was examined using an autoclave installed with a particle video microscope and focused beam reflectance measurement probes. The experimental results from methane + water + diesel oil systems show that the agglomeration of hydrate can be judged directly from two laser probes. With the action of an effective anti-agglomerant, the size of droplets/hydrate particles is uniform and tends to that before hydrate formation when most water converts to hydrate or the system stops stirring for 9 h, although the agglomeration occurs when water droplets initially convert into hydrates. The evaluation method was examined under different anti-agglomerant concentrations, water cuts, and subcoolings for water + diesel oil systems. The action mechanism of anti-agglomerants was also proposed.
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