Article
Energy & Fuels
Jiamin Zhao, Tao Liu, Wei Han, Liang Ren, Le Zhang, Lishun Dai, Dadong Li
Summary: This study investigated the molecular structure of sulfur compounds in residual oils and their desulfurization reactivity during the RHT process. It showed that different classes of sulfur compounds exhibit varied reactivity, with S1 class compounds being more refractory and 52/53 class compounds easier to remove. The research provides insights into the complex desulfurization chemistry in the RHT process.
Article
Energy & Fuels
Rafal Gieleciak, Hena Farooqi, Jinwen Chen
Summary: In this study, diesel fractions were obtained by co-hydroprocessing blends of low-grade canola oil and Canadian oil sand bitumen-derived heavy vacuum gas oil (HVGO). The characterization results showed that an increased content of canola oil in the feed blends led to a higher content of normal paraffins (n-paraffins) in the diesel fractions, while the contents of aromatics and cycloparaffins decreased. The formation of n-heptadecane and n-octadecane in the diesel fractions resulted in improved physical and combustion properties.
Article
Energy & Fuels
Chao-yu Sie, Quoc P. Nguyen
Summary: This study focuses on the natural gas huff-n-puff process for enhanced oil recovery in shale formations, examining the impact of operating conditions on oil production. Results show a marginal increase in oil recovery factor with higher huff pressure and a modest increase with lower pressure depletion rate during the puff. The study also highlights the impact of soaking time on incremental oil production and changes in produced oil composition over time.
Article
Energy & Fuels
E. V. Parkhomchuk, K. V. Fedotov, A. I. Lysikov, A. V. Polukhin, E. E. Vorobyeva, I. A. Shamanaeva, N. N. Sankova, D. O. Shestakova, D. M. Reshetnikov, A. V. Volf, A. V. Kleymenov, V. N. Parmon
Summary: The study focuses on testing hierarchical meso-macroporous catalysts for three-stage hydroprocessing of atmospheric and vacuum residues. The properties of fresh and spent catalysts, the selection of optimal parameters for hydroprocessing, and the properties of petroleum products produced under optimal conditions were investigated. Various characterization techniques were used, including XRD, nitrogen adsorption-desorption, Hg-intrusion, SRXRF, TPD-NH3, and SEM. The proposed technology allows for the production of valuable oil products and MARPOL marine fuel that meet modern technical and environmental requirements. A pilot setup for three-stage residue hydroprocessing has been developed and is currently being tested.
Article
Chemistry, Applied
M. Slezackova, A. Peller, J. Mikulec, M. Banic, J. Blasko, E. Hajekova
Summary: Inedible camelina oil (CSO) can be used as diesel components after hydrotreatment. Under suitable conditions, CSO with high unsaturation can be converted into alkanes, aromatics and higher olefins. The co-hydrotreatment with paraffinic solvents can achieve high triacylglyceride conversion into hydrocarbons.
Article
Chemistry, Physical
Sivabalan Sakthivel, Safwat Abdel-Azeim, Vishnu Chandrasekharan Nair
Summary: Chemical enhanced oil recovery often involves the injection of chemicals to alter the rock-oil-water interactions and mobilize the oil towards the production well. This study investigated the effect of functionalized silica nanofluids on improving oil recovery in a carbonate reservoir as a function of the oil acidity. Through experiments and simulations, the study revealed the complex mechanisms behind oil recovery and provided insights into the applicability of nanofluids for enhanced oil recovery.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Thermodynamics
Kun Wang, Fu Chen, Jianyang Yu, Yanping Song, Ghader Ghorbaniasl
Summary: This study comprehensively investigates the impact of six uncertain operating conditions on the aerodynamic performance of a turbine, and uses a new UQ framework to reduce computational cost. The research findings reveal that uncertain operating conditions can cause variations in energy loss, which directly affects the efficiency of the turbine. The suction surface and trailing edge of the blade are particularly sensitive to uncertain operating conditions. Inlet total pressure and outlet static pressure are identified as the primary factors impacting turbomachinery aerodynamics.
Article
Thermodynamics
I. S. Girnik, Yu. I. Aristov
Summary: This study examines the dynamic effect of residual air on pressure-initiated and temperature-initiated adsorption heat transformation cycles, finding that the pressure-initiated adsorption is less sensitive to the presence of residual air, especially at low partial air pressure. This suggests that closed adsorption heat transformation cycles based on the pressure-initiated process are more robust and resistant against residual air, potentially offering a significant practical advantage.
APPLIED THERMAL ENGINEERING
(2022)
Article
Engineering, Geological
Qiong Wang, Wei Su, Yu-Jun Cui, Wei-Min Ye, Yong-Gui Chen
Summary: This study investigates the swelling pressure of compacted MX80 bentonite and COx claystone mixture with different initial stress states, showcasing the impact of compaction induced residual lateral stress on swelling pressure. Results suggest that Transfer method is more practical for specimen preparation in the laboratory.
ENGINEERING GEOLOGY
(2021)
Article
Energy & Fuels
Yapeng Tian, Zhan Qu, Ping Wang, Nannan Liu, Binshan Ju, Jie Zhan, Mingxian Wang, Yintao Dong
Summary: This study is the first to use the modified Peng-Robinson equation of state (PR-EOS) considering fluid-solid interaction to study the effect of wettability on asphaltene precipitation in CO2 injection into shale reservoirs. The results show that wettability plays a significant role in asphaltene precipitation, and there is a coupling effect between wettability and CO2 in shale oil.
Article
Engineering, Chemical
Katrina Avery, Mackenzie Roach, Erdogan Kiran, John Hassler, Mark T. Devlin
Summary: This study investigates the impact of polyisobutylene (PIB) on the volumetric properties and viscosity of synthetic poly(alpha-olefin) base oil. Experimental evaluations were conducted to examine the effects of different molecular weights and addition levels of PIB on the base oil. Correlations between density and viscosity were analyzed to understand the changes caused by PIB. The results provide insights into the alterations in the base oil's packing and other parameters induced by PIB.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Engineering, Chemical
Katrina Avery, Mackenzie Roach, Erdogan Kiran, John Hassler, Mark T. Devlin
Summary: This study reports on the effect of polyisobutylene (PIB) on the volumetric properties and viscosity of a synthetic poly(alpha-olefin) base oil. The results show that PIB can cause changes in the packing of the base oil and affect parameters such as dissipative length, free-volume overlap, diffusive energy barrier, and density scaling parameter.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Yan-Jie Wang, Yang He, Si Yu Zheng, Ziyang Xu, Jia Li, Yiping Zhao, Li Chen, Wenguang Liu
Summary: The loss factor tan delta determines the viscoelasticity of a material, with higher or lower values indicating viscous or elastic properties. Most polymer pressure-sensitive adhesives (PSAs) have limited operational temperature ranges, affecting their viscosity and elasticity. A new underwater PSA with short hydrophobic side chains and weak hydrogen bond interactions shows promising adhesion efficiency underwater over a temperature range of 0-100 degrees C, and with the addition of Teflon particles, the adhesion can operate under silicon oil up to 150 degrees C.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Engineering, Environmental
Isai Vazquez-Garrido, Alfredo Guevara-Lara, Acela Lopez-Benitez
Summary: This study investigates the operational conditions for the hydroprocessing of new and waste soybean oil using a NiMo/Al2O3 catalyst to obtain biofuel. The optimal operational conditions were determined to avoid waxes formation and achieve high conversion of triglycerides.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Yuyang Kang, Yiqing Luo, Xigang Yuan
Summary: The hybrid extraction-distillation process is more energy efficient than the pure distillation process. However, the current sequential iterative optimization method neglects the optimization of distillation column operating pressure, leading to suboptimal designs. In this study, a rigorous pseudo-transient tray model and a steady-state optimization algorithm were used to simultaneously optimize the column's structural parameters and operating conditions. Two case studies were conducted to validate the proposed method, and the results showed that considering product purity as inequality constraints in the optimization process expanded the search space and led to more economically favorable designs.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)