Article
Energy & Fuels
Yingmei Wang, Aili Niu, Wenze Jiao, Ji Chen, Peng Zhang, Jinping Li
Summary: Carbon dioxide hydrate formation rate is improved by using different accelerator systems. The combination of nanographite-TBAB and SDS-TBAB shows better performance in reducing the nucleation time. TBAB shows the best nucleation amount, formation rate, and conversion rate among the single acceleration systems.
Article
Engineering, Chemical
Bin-Bin Ge, Jin Yan, Dong-Liang Zhong, Yi-Yu Lu, Xi-Yue Li
Summary: CO2 capture was experimentally investigated by forming TBAB semiclathrate in a new system of TBAB + graphite nanofluids. The system of TBAB + graphite nanofluids showed preference for CO2 capture compared to TBAB solution and TBAB + SDS solution. The optimal concentration of 0.2 wt.% graphite nanoparticles was found to enhance hydrate growth in TBAB + graphite nanofluids.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Thermodynamics
Xiaoya Zang, Jing Wang, Yong He, Xuebing Zhou, Deqing Liang
Summary: In this study, TBAB hydrates were synthesized and their carbon capture capacity from a ternary gas mixture of CH4/CO2/N-2 was investigated. The addition of TBAB increased the specific surface area of the hydrate crystals and transformed the hydrate structure. These findings are important for the development of hydrate gas separation technology.
Article
Thermodynamics
Fengyuan Zhang, Xiaolin Wang, Xia Lou, Wojciech Lipinski
Summary: This study investigated the effects of anionic surfactant SDS and cationic surfactant DTAC on the kinetics of CO2-TBAB hydrate formation and found that adding SDS can accelerate hydrate formation, while the best CO2 separation performance is achieved in the presence of DTAC.
Article
Engineering, Chemical
Xi-Yue Li, Jin Yan, Dong-Liang Zhong, Shi-Jian Lu, Bin-Bin Ge
Summary: This study investigated the formation of tetra-n-butyl ammonium bromide (TBAB) semiclathrate hydrate for CO2 capture through experiments and in situ Raman spectroscopy. The impacts of TBAB concentration and operating temperature on CO2 incorporation into TBAB semiclathrates were analyzed. The results showed that the structure transition of TBAB semiclathrates from type A to type B occurred in the presence of CO2, resulting in increased CO2 consumption. The TBAB semiclathrate formed at 2.57 mol % TBAB and 282.15 K was found to be a suitable system for CO2 capture.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Physical
Parisa Naeiji, Tom K. Woo, Ryo Ohmura, Saman Alavi
Summary: This study investigated the interfacial behavior of tetrabutylammonium bromide (TBAB) aqueous solutions under different conditions. The results showed that TBAB solutions have lower interfacial tension and higher gas adsorption at the interface, which facilitate the formation of semiclathrate hydrates. CO2 exhibits preferential adsorption compared to CH4 due to stronger interactions in the solution. The increased adsorption of CH4 at the solution surface is attributed to the hydrophobic interactions between the TBAB cation and methane gas.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Energy & Fuels
Yanhong Wang, Jinfeng Lu, Jing Qi, Xuemei Lang, Shuanshi Fan, Chi Yu, Gang Li
Summary: This study utilized HCFC-141b as an additive to capture CO2, enhancing the kinetics difference in methane and carbon dioxide hydrate formation, effectively reducing energy consumption and improving separation efficiency.
Article
Thermodynamics
Jose M. Chima-Maceda, Alfredo Pimentel-Rodas, Luis A. Galicia-Luna, Angel M. Notario-Lopez
Summary: Experimental measurements of hydrate dissociation conditions were conducted for three multi-component systems, with good agreement found between the experimental data and literature data, indicating the viability of the experimental technique. The uncertainties in temperature and pressure were determined to be 0.16 K and 0.04 MPa, respectively, with a relative standard uncertainty in composition estimated to be 0.0014.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2021)
Article
Energy & Fuels
Shu-Li Wang, Yan-Yun Xiao, Shi-Dong Zhou, Kun Jiang, Yi-Song Yu, Yong-Chao Rao
Summary: In this study, the thermodynamics and kinetics of hydrate formation in 9.01 wt% TBAB mixed with MWCNTol were investigated. The results showed that MWCNTols had little effect on CO2 hydrate formation phase equilibrium, but they significantly shortened the induction time. The addition of nanoparticles increased the final gas consumption, with the 9.01 wt% TBAB + 0.08 wt% GN system showing the highest increase. The best system was the 9.01 wt% TBAB + 0.02 wt% MWCNTol at 3.5 MPa and 277.15 K, reducing the induction time by 66.67% and increasing the final gas consumption by 284.11%. This work contributes to the industrial application of hydrate technology in CO2 capture and storage.
Article
Thermodynamics
Hong Huang, Shuanshi Fan, Yanhong Wang, Xuemei Lang, Gang Li
Summary: The two-stage hydrate-based biogas De-CO2 process in the presence of TBAB was simulated and analyzed using ASPEN plus software. The effects of key process parameters on energy consumption and the exergy of the whole process were determined. Optimization of process energy utilization resulted in a reduction in total energy consumption and lower energy cost compared to other carbon capture processes.
Article
Energy & Fuels
Qian Xue, Faping Liu, Zunzhao Li, Xiaolin Wang, Xiaozhe Sun, Mingrui Liu, Peixian Wang, Shuanshi Fan, Xuemei Lang
Summary: In this study, a 15 L pilot-scale reactor was designed to achieve pilot-scale biogas separation using a novel jet impingement stream. By multistage separation, methane recovery and carbon dioxide capture were achieved, obtaining pure methane. The results showed that the methane concentration could be increased from 50.0% to about 95.1% through a four-stage hydrate-based gas separation process. This work provides insights for the industrial application of continuous hydrate-based biogas separation.
Article
Chemistry, Physical
Alberto Maria Gambelli, Giulia Stornelli, Andrea Di Schino, Federico Rossi
Summary: The study found that the addition of CuSn12 alloy powder significantly promoted the hydrate formation and dissociation processes, with the pure quartz porous medium acting as an inhibitor for CO2 hydrate. Different concentrations of CuSn12 powder added in different conditions affected the formation and dissociation processes of hydrates.
Article
Energy & Fuels
Xiao-Yan Deng, Ying Yang, Dong-Liang Zhong, Xi-Yue Li, Bin-Bin Ge, Jin Yan
Summary: This study investigates the morphology and kinetics of CO2 hydrate formation in the presence of sodium dodecyl sulfate (SDS). It was found that the growth of CO2 hydrate above the gas-liquid interface became stronger with higher SDS concentration, indicating an enhanced promoting effect of SDS on CO2 hydrate formation. The highest efficiency for CO2 hydrate formation was achieved at 1500 and 3000 ppm of SDS, showing potential for improving hydrate-based CO2 capture technology in the future.
Article
Thermodynamics
Feng-Mei Xie, Xi-Yue Li, Dong-Liang Zhong, Peter Englezos, Guo-Xiang Lu
Summary: This study demonstrates the phase behavior of TBPB and CO2 hydrates at different concentrations, with the addition of surfactant affecting phase equilibrium and CO2 consumption during formation. Further research should focus on increasing the CO2 storage capacity of TBPB semiclathrate hydrate.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2021)
Article
Thermodynamics
Huan-Ran Zhang, Zhi-Gao Sun
Summary: The formation of CO2 hydrate requires strict conditions, but the equilibrium conditions can be improved by using 2,5-dihydrofuran as a thermodynamic promoter.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2023)
Article
Energy & Fuels
Juan He, Xiaosen Li, Zhaoyang Chen, Qingping Li, Yu Zhang, Yi Wang, Zhiming Xia, Changyu You
Summary: The study found that initiating electrical heating before depressurization and performing soaking at a pressure below equilibrium can increase hydrate dissociation rate and improve energy efficiency. Additionally, not using electrical heating during depressurization can significantly reduce water production rate and increase energy efficiency. The results suggest that careful consideration of the timing and conditions of electrical heating can optimize hydrate dissociation and energy use in hydrate exploitation.
Article
Energy & Fuels
Chun-Gang Xu, Min Wang, Gang Xu, Xiao-Sen Li, Wei Zhang, Jing Cai, Zhao-Yang Chen
Summary: Research demonstrates that CO2-CP binary hydrate and CO2 hydrate are formed successively and coexist in the final hydrate in the CP-CO2 system. The formation of these two hydrates causes two pressure drops.
Article
Energy & Fuels
Xuan Kou, Xiao-Sen Li, Yi Wang, Kun Wan, Zhao-Yang Chen
Summary: The study analyzed the effects of particle size and hydrate saturation on hydrate growth habits, pore structure properties, and permeability reduction through microscale experiments and pore-network models. The results showed the evolution of gas hydrate pore-habit and its distribution in pores, highlighting the importance of pore interconnectivity in hydrate-bearing sediments. The study also proposed an equation for absolute permeability in the presence of gas hydrate, validated by experimental results.
Article
Energy & Fuels
Ke-Feng Yan, Hao Chen, Zhao-Yang Chen, Xiao-Sen Li, Chun-Gang Xu, Yu Zhang, Zhi-Ming Xia, Yi-Song Yu
Summary: This study investigates the impact of H2O on CH4-CO2 displacement behavior using molecular dynamics simulation and quantum mechanics calculation. It reveals that the electrostatic interaction of H2O-H2O and H2O-gas is a key factor in the CH4-CO2 replacement mechanism, suggesting that modifying the electrostatic interaction with H2O molecules could enhance the replacement efficiency.
Article
Thermodynamics
Juan He, Xiaosen Li, Zhaoyang Chen, Changyu You, Kefeng Yan, Zhiming Xia, Qingping Li
Summary: The distribution of hydrates in sediment affects the changing trends of effective thermal conductivity, especially influenced by gas saturation, water saturation or pressure. Different formation processes of hydrates exhibit various trends in thermal conductivity changes, with non-uniform distribution causing different behaviors.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2021)
Article
Energy & Fuels
Hao Chen, Ke-Feng Yan, Zhao-Yang Chen, Xiao-Sen Li, Yu Zhang, Chun-Gang Xu
Summary: This study systematically investigated the characteristics of host-guest interactions in gas hydrates using quantum mechanics calculations. It highlighted the significant impact of electrostatic interactions on stability, with molecules with higher maximum ESP values showing higher stabilization. The findings suggest that van der Waals volumes/surface areas and V-s,V-max values of guest molecules are key factors for gas hydrate stability.
Article
Energy & Fuels
Yu Zhang, Lei Zhang, Chuan-Yu Zhu, Li-Xin Xu, Xiao-Sen Li, Zhao-Yang Chen
Summary: The formation rates of methane hydrate are significantly affected by the grain size of the sediments, with lower rates observed in sand compared to powders. The final water conversion rate is similar in powders and can reach nearly 100% with sufficient gas supply, while the rate declines sharply at a certain water conversion point in all three types of porous media.
Article
Energy & Fuels
Lei Zhang, Yu Zhang, Chang Chen, Xiao-Sen Li, Zhao-Yang Chen
Summary: A two-dimensional numerical model was established on the hydrate reservoir at station W17, Shenhu area of the South China Sea to study the response of the reservoir to drilling fluid temperature and salinity values. Results showed that temperature and pressure changes during drilling process promoted hydrate decomposition, leading to secondary hydrate formation. Increasing drilling fluid temperature significantly enhanced hydrate decomposition and pressure increase near the wellbore, potentially causing pore fluid flow into the wellbore.
Article
Physics, Multidisciplinary
Haopeng Zeng, Yu Zhang, Lei Zhang, Zhaoyang Chen, Xiaosen Li
Summary: Depressurization combined with brine injection is a potential method for improving the production efficiency of natural gas hydrate fields and avoiding secondary formation of hydrate. The experimental results show that high-water production reduces the final gas recovery, while increasing NaCl concentration only effectively promotes gas production rate in the early stage. The injection of NaCl solution decreases the lowest temperature in sediments during hydrate production and increases heat transfer.
Article
Physics, Multidisciplinary
Zhiwen Zhang, Xiaosen Li, Zhaoyang Chen, Yu Zhang, Hao Peng
Summary: In this study, the electrical resistivity properties of gas-water-sand fluid were experimentally investigated. The effects of various factors on the resistivity of the multiphase fluid were studied, and the measurement devices and operating parameters were optimized. A novel combined resistivity method was developed, which showed promising results for measuring the phase fractions of gas-water-sand fluid.
Article
Engineering, Marine
Haopeng Zeng, Yu Zhang, Lei Zhang, Zhaoyang Chen, Xiaosen Li
Summary: The presence of salts and sea mud affects the formation of natural gas hydrates (NGH). Low NaCl concentration and low montmorillonite content can reduce the induction time of hydrate formation, while high NaCl concentration and high montmorillonite content significantly increase the induction time. The increase in NaCl concentration enhances the inhibition of hydrate formation and reduces the final water conversion.
JOURNAL OF MARINE SCIENCE AND ENGINEERING
(2022)
Review
Energy & Fuels
Hao Peng, Xiaosen Li, Zhaoyang Chen, Yu Zhang, Changyu You
Summary: This paper focuses on the seepage studies of hydrate-bearing sediment (HBS), including the application of theories, normalized permeability models, extension with new technology, and development. There is currently no review that has predicted the original permeability of sediments without hydrates, and there are limited studies on seepage theories using new technologies. However, this review summarizes the prospects, evolution, and application of HBS seepage theories from the perspectives of experiments, numerical simulation, and microscopic visualization, and discusses the current limitations and directions of these theories.
Article
Energy & Fuels
Hongfei Ji, Xiao-Sen Li, Zhaoyang Chen, Changyu You, Hao Peng, Yun Feng
Summary: This study employs an improved multiple-point geostatistics simulation method to generate a series of images of porous media that accurately reproduce the distribution of hydrates in sediments. The algorithm successfully solves the problem of hydrate blockage and ensures similarity in variogram and visual properties with the training image. The feasibility of predicting the pore habit of hydrates with time using this novel method is proven by a verification case. This research offers a new approach to predict hydrate distribution behavior and the algorithm may be widely applied by scanning training images from different reservoirs.
Article
Energy & Fuels
Hao-Yang Li, Xiao-Sen Li, Yi-Song Yu, Zhao-Yang Chen
Summary: In this study, the morphologies of methane hydrate formation in a system containing different mole ratios of tetrahydrofuran (THF) and cyclopentane (CP) at two different temperatures were systematically studied. The results showed that a hydrate film quickly formed at the interface between CP and the THF solution phase, significantly decreasing gas-liquid mass transfer efficiency. Interestingly, the hydrate layer broke when the temperature increased. Three stages of hydrate formation were observed in the system at the higher temperature. Furthermore, the type of promoters used in the system had no effect on CH4 occupancy in sII cages after the hydrate layer ruptured.
Article
Energy & Fuels
Hao Peng, Xiaosen Li, Zhaoyang Chen, Yu Zhang, Hongfei Ji, Changyu You
Summary: This research reveals the evolution of growth modes in hydrates by analyzing the competition parameter and saturation, providing a new approach for industrial exploitation and simulation calculation.
GAS SCIENCE AND ENGINEERING
(2023)