Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 54, Issue 6, Pages 758-764Publisher
WILEY
DOI: 10.1002/pola.27908
Keywords
polyhydroxyurethanes; NIPUs; glycerol carbonate; sebacic acid; TBD
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Funding
- Haute Normandie region
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Novel fully renewable AA-BB type non-isocyanate polyhydroxyurethanes were synthesized by the classical reaction between a diamine and a dicyclocarbonate. Sebacic acid was first reacted with an excess of glycerol carbonate, in presence of DCC and DMPA, leading to a renewable dicyclocarbonate monomer. Then, this monomer was reacted with several renewable diamines, in presence of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD), as organocatalyst, to afford linear and branched polymers. The obtained materials exhibited T-g values varied from -27 to -8 degrees C, T-m values varying from 100 to 165 degrees C, and thermal stabilities above 200 degrees C. (c) 2015 Wiley Periodicals, Inc.
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