Journal
ELECTROCHIMICA ACTA
Volume 116, Issue -, Pages 292-299Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.10.196
Keywords
Carbon/iron carbide composite; Pyrolytic carbon; Voltage hysteresis; Anode; Lithium ion battery
Categories
Funding
- major program of Beijing Municipal Natural Science Foundation [20110001]
- National Natural Science Foundation of China [11179001]
- National High Technology Research and Development Program (863) [2012AA052201]
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A novel C/Fe3C composite prepared by simple polymerization-pyrolysis of iron phthalocyanine (PcFe) at 700 degrees C in an Ar atmosphere, exhibits a high reversible capacity, stable cyclability, excellent rate performance, improved initial efficiency and reduced hysteresis as an anode material for lithium ion batteries. In-situ embedded Fe3C nanoparticles and N doping can enhance electrical conductivity and facilitate the reaction of C/Fe3C electrode effectively. This work provides a new way for developing high performance non-graphitic carbon electrode materials in the future. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.
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