Journal
ELECTROCHIMICA ACTA
Volume 76, Issue -, Pages 288-291Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2012.05.020
Keywords
Electrodeposition; Palladium nanoparticles; Fullerene; Methane
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Funding
- Hundred Talent Programme of Shanxi Province
- Shanxi International S&T Cooperation Program of China [2011081017]
- National Natural Science Foundation of China [21175086]
- Shanxi Scholarship Council of China [2011-014]
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A novel nanocomposite of palladium nanoparticles-modified fullerene (Pd NPs-C-60) was fabricated by an electrodeposition technique on a glassy carbon (GC) electrode and its electrochemical properties were studied. It was found that Pd NPs incorporating with C-60 can enhance its sensitivity and selectivity to CH4 at ambient conditions. The Pd NPs-C-60 modified GC electrode shows better electron-transfer behavior than that of bare GC, pristine C-60 modified GC, and Pd NPs modified GC electrodes. The Pd NPs-C-60 modified GC electrode displays stable and reproducible response to CH4 and could be used repeatedly. Our results demonstrate that the Pd NPs-C nanocomposite should be a promising and useful nanomaterial for developing sensitive electrochemical sensors. (C) 2012 Elsevier Ltd. All rights reserved.
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