4.6 Article

Porous polyaniline exhibits highly enhanced electrochemical capacitance performance

Journal

ELECTROCHIMICA ACTA
Volume 55, Issue 20, Pages 5819-5822

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.05.030

Keywords

Porous polyaniline; Conducting polymer; Supercapacitor; Capacitance

Funding

  1. NSF [50702006, 50873015]
  2. NCET
  3. MOE
  4. Fundamental Research Funds for the Central Universities of China, Beijing Municipal Science Technology [20078026]
  5. Fok Ying-Tong Education Foundation

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Porous polyaniline (PANI) is prepared by using sodium dodecylsulfate as a soft template and ammonium persulfate as an oxidant. Transmission electron microscopy and nitrogen adsorption-desorption isotherms suggest the existence of both macro/mesopores and micropores, and the specific surface area of 211 m(2) g(-1). As a result of its porous structure, the porous PANI exhibits highly enhanced utilization ratio during the charge-discharge cycles. This porous PANI also displays high cycle stability and rate capability. (C) 2010 Elsevier Ltd. All rights reserved.

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