4.2 Article

Excitation of the 4 lowest electronic transitions in methanol by low-energy electrons

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/48/11/115208

Keywords

electronic excitation; differential cross sections; electron scattering

Funding

  1. National Science Foundation [NSF-RUI-AMO 1306742, 0968874]
  2. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division [DE-FG02-97ER14814]
  3. U.S. Department of Energy [DE-AC02-05CH11231]
  4. U.S. DOE Office of Basic Energy Sciences, Division of Chemical Sciences
  5. National Science Foundation
  6. Direct For Mathematical & Physical Scien
  7. Division Of Physics [1305470] Funding Source: National Science Foundation
  8. Division Of Physics
  9. Direct For Mathematical & Physical Scien [1303071, 1306742] Funding Source: National Science Foundation
  10. U.S. Department of Energy (DOE) [DE-FG02-97ER14814] Funding Source: U.S. Department of Energy (DOE)

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We report differential and integral cross sections for electronic excitation of methanol by low-energy electron impact. Cross sections were measured for the four lowest-lying excited states at incident electron energies from 9 to 20 eV and at scattering angles from 5 degrees through 130 degrees. The measured cross sections were normalized against previously reported elastic scattering data determined using the relative flow method. Corresponding cross-section calculations were carried out using the complex Kohn variational method within a 7-channel close-coupling scheme and using the Schwinger multichannel method within an 11-channel close-coupling scheme.

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