4.5 Article

The challenge of decomposition and melting of gallium nitride under high pressure and high temperature

Journal

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
Volume 85, Issue -, Pages 138-143

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2015.05.006

Keywords

Semiconductors; High pressures; Phase equilibria; Phase transitions; Crystal growth

Funding

  1. FP7 START Project Boosting EU-Ukraine cooperation in the field of Superhard Materials [295003]
  2. Polish Grant MNiSW Kwantowe nanostruktury polprzewodnikowe do zastosowan w biologii i medycynie [POIG 01.01.02-008/08-00]
  3. Grant NCN (Poland) [UMO-2012/05/N/ST3/02545]
  4. National Science Centre (Poland) [2011/03/B/ST3/02352]

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Gallium nitride (GaN) is considered to be one of the most important semiconductors nowadays. In this report a solution of the long standing puzzle regarding GaN decomposition and melting under high pressure and high temperature is presented. This includes the discussion of results obtained so far. The possibility of a consistent parameterisation of pressure (P) evolution of the melting temperature (T-m) in basic semiconductors (GaN, germanium, silicon...), independently from signs of dT(m)/dP is also presented. (C) 2015 The Authors. Published by Elsevier Ltd.

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