Article
Chemistry, Physical
Seongmo Ahn, Jin Hyeok Jang, Jungtaek Kang, Moony Na, Jia Seo, Vikram Singh, Jung Min Joo, Hye Ryung Byon
Summary: The study developed a new class of pyridinium-based negolytes, which improved molecular stability by introducing benzothiazole and suppressed material crossover with cationic ammonium functional groups. The solubility of the negolyte was increased to around 1 M, showing promising results in terms of capacity-fading rate in RFBs.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Jocasta Avila, Chiara Corsini, Cintia M. Correa, Martin Rosenthal, Agilio Padua, Margarida Costa Gomes
Summary: This Perspective highlights the pathways to prepare porous ionic liquids using easily accessible materials for reduced environmental impact. The study demonstrates that suspensions of porous solids are stable in eutectic mixtures, which indicates their potential in preparing porous ionic liquids. Porous ionic liquids maintain the wide electrochemical window observed in their precursor pure ionic liquids, making them suitable for green electrochemical reactions, especially those involving gases with enhanced solubility in the porous suspensions. Furthermore, their capacity as gas-rich media suggests potential sustainable biomedical and pharmaceutical applications, provided that non-toxic, biocompatible ionic liquids and porous solids are utilized.
Article
Chemistry, Multidisciplinary
Jiaqi Wei, Lixiang Zhong, Huarong Xia, Zhisheng Lv, Caozheng Diao, Wei Zhang, Xing Li, Yonghua Du, Shibo Xi, Mathieu Salanne, Xiaodong Chen, Shuzhou Li
Summary: Ion adsorption inside electrified carbon micropores is crucial for supercapacitor operation, with transition-metal cations forming oligomer species when confined in negatively charged micropores. These oligomers exhibit sluggish dissociation kinetics, leading to capacitance fading, but can be dissolved by applying a positive potential. An intermittent reverse cycling strategy is proposed to periodically evacuate micropores and revivify capacitance.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Li Sun, Kelei Zhuo, Yujuan Chen, Quanzhou Du, Suojiang Zhang, Jianji Wang
Summary: This review introduces the use of ionic liquid (IL) electrolytes combined with redox active species to enhance the energy density of supercapacitors (SCs). The introduction of redox active species contributes to pseudocapacitance and various IL-REs and their energy storage mechanisms are discussed. Future research needs to address current challenges in order to advance this promising field.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Physical
Beichen Liu, Wenxiao Guo, Matthew A. Gebbie
Summary: In this study, we investigate the influence of ionic correlations on the reaction rates and selectivity of CO2 electroreduction. Through experiments, we find that at intermediate concentrations, the reduction rates of CO2 are accelerated and the efficiency of CO production is enhanced. The acceleration of CO2 reduction is due to the amplification of potential-dependent driving forces, rather than changes in onset potential. These findings are applicable to both cocatalytic and noncatalytic ions.
Article
Chemistry, Multidisciplinary
Kohei Miyazaki, Atsushi Mizawa, Yuta Ito, Fumihiro Sagane, Takeshi Abe
Summary: In this study, the formation kinetics of graphite intercalation compounds (GICs) were investigated, and it was found that the activation energy of interfacial anion transfer resistance is correlated with the viscosity of the ionic liquid electrolytes. This relationship provides important insights for the construction of dual-ion batteries with high capacity and high rate capability.
Article
Engineering, Environmental
Benoit Villemejeanne, Sophie Legeai, Eric Meux, Sandrine Dourdain, Hakima Mendil-Jakani, Emmanuel Billy
Summary: The one-step electroleaching-electrochemical deposition process using ionic liquid mixtures is a promising alternative for palladium and gold recovery, with chloride-based mixtures proving to be the most suitable electrolyte. The use of low viscous electrolytes allows for metal leaching at low anodic potential, leading to a more sustainable process compared to conventional processes.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Correction
Chemistry, Physical
Yury A. Budkov, Nikolai N. Kalikin, Andrei L. Kolesnikov
Summary: The correction for 'Electrochemistry meets polymer physics: polymerized ionic liquids on an electrified electrode' by Yury A. Budkov et al. published in Phys. Chem. Chem. Phys., 2022, DOI: 10.1039/d1cp04221a addresses any errors in the original article.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Vinicius Piccoli, Leandro Martinez
Summary: Ionic liquids (ILs) are widely used in biotechnological applications for their interactions with proteins. In this study, we investigated the solvation of different ubiquitin folding states in IL aqueous solutions and found that ILs preferentially solvate protein structures and are considered denaturants. The exposure of low-polarity residues during protein denaturation allows favorable interactions with ILs, stabilizing the protein core.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Review
Chemistry, Multidisciplinary
Olga Lebedeva, Dmitry Kultin, Leonid Kustov
Summary: This review explores the characteristics of electrochemical synthesis of nanostructures in ionic liquids, emphasizing the production of various nanomaterials and nanoscale polymer films. It highlights the potential application of ILs as an electrochemical medium and the relative simplicity of experimental procedures.
Review
Chemistry, Physical
Gagandeep Kaur, Harsh Kumar, Meenu Singla
Summary: This article presents the extensive utilization and range of ionic liquids in various fields, based on available literature. It provides a systematic and concise analysis of the applications of different ionic liquids, highlighting recent significant advances in each area. This review contributes to enhancing the understanding of the substantial knowledge in every research branch using ionic liquids. Additionally, it discusses the challenges associated with the industrial use of ionic liquids, which require further investigation.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Engineering, Chemical
Lie Ma, Chi Zhang, Saisai Lin, Shengfu Chen, Zhikan Yao, Zhilin Sun, Congjie Gao, Lin Zhang
Summary: This study enhanced the antifouling property of polyamide reverse osmosis membranes by tethering the aminated imidazolium cation of ionic liquids onto the membrane surface, resulting in balanced charge, strong hydrophilicity, low protein adsorption, and excellent antifouling behavior. The integration of high performance ionic liquids and mild conditions is expected to expand the application of superb antifouling materials in various biofouling areas.
Article
Chemistry, Multidisciplinary
Juliette I. Phillips, Shinya Azuma, Junqiao Lee, Tadaharu Ueda, Debbie S. Silvester
Summary: This study examined the kinetics and thermodynamics of POM reduction products using a variety of RTILs, revealing the impact of ion structure on solvation effects and ion-pairing effects. The findings highlight the importance of tuning RTIL structure for achieving optimal kinetics and thermodynamics in electrochemical processes.
AUSTRALIAN JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Christian Balischewski, Biswajit Bhattacharyya, Eric Sperlich, Christina Guenter, Alkit Beqiraj, Tillmann Klamroth, Karsten Behrens, Stefan Mies, Alexandra Kelling, Susanne Lubahn, Lea Holtzheimer, Anne Nitschke, Andreas Taubert
Summary: The study synthesized fifteen N-butylpyridinium salts and investigated their structures, thermal properties, and electrochemical properties. All compounds are ionic liquids with melting points between 64 and 101 degrees C, isostructural, with electrochemical stability windows between 2 and 3 V, and conductivities ranging from 10(-5) to 10(-6) S cm(-1).
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Valentin Radtke, Niklas Gebel, Denis Priester, Andreas Ermantraut, Monika Baeuerle, Daniel Himmel, Regina Stroh, Thorsten Koslowski, Ivo Leito, Ingo Krossing
Summary: The study successfully measured the Gibbs energy of transfer of silver ions in different solvents using an ideal ionic liquid salt bridge, establishing a consistent data set and laying the foundation for the experimental thermodynamic framework of ion solvation chemistry. By defining solvent-independent indicators, comparison of electronating potential of redox systems was achieved, unifying the redox potential scales of all conventional solvents.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Electrochemistry
Silvia Mena, Cyril Loault, Veronica Mesa, Iluminada Gallardo, Gonzalo Guirado
Summary: In this study, a new simple molecule was synthesized for controlling and tuning CO2 reactivity based on electrode potential. The compound showed different reaction processes in inert atmosphere and CO2 atmosphere, opening up new possibilities for manipulating reaction processes associated with CO2.
Article
Nanoscience & Nanotechnology
Sara Santiago, Pablo Gimenez-Gomez, Xavier Munoz-Berbel, Jordi Hernando, Gonzalo Guirado
Summary: By using ionogels as an alternative to supporting solid matrices, the challenges of fabricating multistimuli-responsive chromic materials and devices can be overcome, allowing molecular switches to retain their solution-like properties and be exposed to a variety of different stimuli for optimal photo-, halo-, thermo-, and electrochromic switching behaviors.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Silvia Mena, Esteve Ribas, Clara Richart, Iluminada Gallardo, Jordi Faraudo, Scott K. Shaw, Gonzalo Guirado
Summary: The paper focuses on the role of carbon dioxide in controlling the Earth's temperature and the environmental problems caused by its increased concentration in the atmosphere. It discusses the use of ionic liquids for efficient CO2 capture and conversion, utilizing electrochemical, spectroscopic, and molecular dynamics techniques to understand the reduction mechanism under various conditions. The research opens up possibilities for theoretical-experimental approaches to determine the CO2 reduction mechanism and the dependency of product formation on the electrode material and solvent used.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Analytical
Jiri Dietvorst, Amparo Ferrer-Vilanova, Sharath Narayana Iyengar, Aman Russom, Nuria Vigues, Jordi Mas, Lluisa Vilaplana, Maria-Pilar Marco, Gonzalo Guirado, Xavier Munoz-Berbel
Summary: This study introduces a cyanotype-based photochemical amplification reaction for detecting low bacterial concentrations efficiently and simply, which is expected to have a significant impact on clinical diagnosis of infectious diseases.
ANALYTICAL CHEMISTRY
(2022)
Article
Electrochemistry
Sara Santiago, Clara Richart, Silvia Mena, Iluminada Gallardo, Jordi Hernando, Gonzalo Guirado
Summary: This manuscript discusses the use of carbon capture and utilization to synthesize high-added chemicals using CO2. The study reveals that carboxylated spiropyran derivatives can be synthesized with high yields and conversion rates through an electrocarboxylation process using a silver cathode and polar aprotic solvents. This research provides a new sustainable strategy for designing and building smart surfaces with switchable physical properties.
Article
Biotechnology & Applied Microbiology
Naroa Uria-Molto, Ruben D. Costa, Cybeles Nunziata, Sara Santiago, Gonzalo Guirado, Xavier Munoz-Berbel, Lukasz Kowalski
Summary: The study aims to develop a compact, portable, and self-sustaining format of energy production based on Microbial Fuel Cell (MFC) technologies. By assembling and comparing three different MFC configurations, it was found that the hybrid-MFC performed the best, with sustained operation for over a month, making it suitable for long-term power supply of low-power electronic devices in the field.
ELECTRONIC JOURNAL OF BIOTECHNOLOGY
(2022)
Article
Chemistry, Analytical
Carolina Gasco, Luis Rodriguez-Santiago, Mariona Sodupe, Rosa Maria Sebastian, Gonzalo Guirado
Summary: This paper proposes a new electroinduced approach to increase the crosslinking density of electroactive polybenzoxazines by designing new monomers and investigating the electrochemical reactions of polybenzoxazines in solution or ionogel matrices. These studies lay the foundations for the design of smart polybenzoxazines that can undergo dual-cure mechanisms at low electrochemical potential values.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
Sara Santiago, Hugo Cruz, Noemi Jordao, Pablo Gimenez-Gomez, Karolina Zalewska, Xavier Munoz-Berbel, Andreia F. M. Santos, Jordi Hernando, Luis C. Branco, Gonzalo Guirado
Summary: This study establishes the photoelectrochromic properties of four diarylethene ionic liquids (DAE-ILs) and demonstrates their potential applications in smart ionogels for photoelectrochemical devices.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Joao Sarrato, Ana Lucia Pinto, Hugo Cruz, Noemi Jordao, Gabriela Malta, Paula S. Branco, J. Carlos Lima, Luis C. Branco
Summary: The use of ionic liquid and organic salts as additives for electrolyte systems in dye-sensitized solar cells have been widely studied. The tunability of their physical-chemical properties contributes toward their high efficiencies. In this study, several iodide-based organic salts were tested and compared for their photovoltaic parameters. It was found that 1-ethyl-2,3-dimethylimidazolium iodide ([C2DMIM]I) showed the best efficiency. Furthermore, the performance was further improved by incorporating other compounds, and [C2DMIM]I demonstrated the highest synergy. The effects of the additives were analyzed using electrochemical impedance spectroscopy, and properties related to polarity were found to be consistent with the counter-electrode resistance.
Article
Chemistry, Physical
Alison N. Roth, Jemima Opare-Addo, Eunbyeol Gi, Silvia Mena, Gonzalo Guirado, Richard D. Schaller, Emily A. Smith, Javier Vela
Summary: Mixed-metal chalcohalide semiconductors, specifically Pb2SbS2I3 and Pb2BiS2I3, were synthesized in solution phase using readily available precursors. The reaction parameters were fine-tuned to produce rod-like structures with tunable dimensions. The quaternary chalcohalides exhibited photoluminescence both as an ensemble and at the single particle level, as observed through fluorescence microscopy. Electronic structure calculations were used to evaluate the stability and band gap of Pb2SbS2I3 polymorphs and their coloring patterns. These synthetic methods pave the way for further exploration of complex chalcohalides and other multinary semiconductors for new technological applications.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Diogo Inacio, Ana Lucia Pinto, Ana B. Paninho, Luis C. Branco, Sunny K. S. Freitas, Hugo Cruz
Summary: Five Covalent Organic Frameworks (COFs) were synthesized and tested as dyes and additives in Dye-Sensitized Solar Cells (DSSCs). These porous nanomaterials were made from commercially available ionic dyes and antibiotics, and the most promising COF, RIO-60, showed improved performance compared to previous COFs in similar devices. This research indicates the potential of using the RIO family for enhancing DSSCs and increasing their lifespan.
Article
Chemistry, Multidisciplinary
Arnau Marco, Gonzalo Guirado, Rosa Maria Sebastian, Jordi Hernando
Summary: This study develops optical chemosensors for CO2 by preparing hydrogels functionalized with spiropyrans, which exhibit acidochromic properties and undergo color changes upon exposure to CO2.
FRONTIERS IN CHEMISTRY
(2023)
Article
Biophysics
Joan Aymerich, Amparo Ferrer-Vilanova, Jose Cisneros-Fernandez, Roger Escude-Pujol, Gonzalo Guirado, Lluis Teres, Michele Dei, Xavier Munoz-Berbel, Francisco Serra- Graells
Summary: Early detection of low bacterial concentrations is crucial for minimizing healthcare and safety issues. In this study, a potentiostatic-amperometric Delta-Sigma modulator with the ability to cancel flicker noise and improve the limit of detection was developed. The integrated circuit, with an area of 2.3 mm2, was attached to an inkjet-printed electrochemical sensor. The disposable device was capable of detecting live bacterial concentrations as low as 102 CFU/mL within an hour.
BIOSENSORS & BIOELECTRONICS
(2023)
Article
Multidisciplinary Sciences
S. Mena, N. Karkour, V. Alaphilippe, J. P. Botero, M. Jimenez, D. Linget, L. Gibelin, V. Le Ven, A. Marquet, S. Mellouh, E. Josson, W. Benassou, X. Munoz-Berbel, G. Guirado, C. Guardiola
Summary: This work presents the validation of a new OptoElectro-Mechanical system for two-dimensional dose evaluation using radiochromic films. The results show that the proposed system is feasible and provides similar results to the standard method. Further developments are being conducted to improve the spatial resolution and real-time performance of the system for better clinical application of radiochromic films.
SCIENTIFIC REPORTS
(2023)
Article
Electrochemistry
Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro
Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao
Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha
Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li
Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo
Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu
Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda
Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen
Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Berna Dalkiran, Havva Bekirog
Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Sijun Ren, Jianguo Huang
Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian
Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings
Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou
Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane
Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado
Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.
ELECTROCHIMICA ACTA
(2024)
