4.6 Article

Net currents obtained from zero-average potentials in single amphoteric nanopores

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 31, Issue -, Pages 137-140

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2013.03.026

Keywords

Nanofluidic ratchet; Amphoteric pore; Rectification; pH sensing and regulation; Energy conversion

Funding

  1. Ministry of Economy and Competitiveness [MAT2012-32084]
  2. Generalitat Valenciana [PROMETEO/GV/0069]

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We have studied experimentally and theoretically the rectifying properties of a single asymmetric nanopore functionalized with amphoteric lysine groups and characterized the net current obtained with zero-average time dependent potentials. The pH-controlled rectification phenomena may be relevant to bio-electrochemistry, pH sensing and regulation, and energy conversion. (C) 2013 Elsevier B.V. All rights reserved.

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