Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 13, Issue 12, Pages 1340-1343Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2011.08.007
Keywords
Cobalt-free; Composite cathode; Solid oxide fuel cells; Electrochemical impedance spectroscopy
Categories
Funding
- China National Funds to Distinguished Young Scientists [51025209]
- Outstanding Young Scholar Grant at Jiangsu Province [2008023]
- Fok Ying Tung Education [111073]
- Chinese Ministry of Education
- National Basic Research Program of China [2007CB209704]
- Australian Research Council (ARC) [DP1095089]
- Australian Research Council [DP1095089] Funding Source: Australian Research Council
Ask authors/readers for more resources
Cobalt-free perovskite cathode with excellent oxygen reduction reaction (ORR) properties below 800 degrees C is a key material toward wide implementation of intermediate-temperature solid oxide fuel cells. This work reports the phase structure, microstructure and performance of such cathode based on the composite phases of triclinic Ba(0.9)Bi(0.1)FeO(3-delta), cubic BaFeO(3) and orthorhombic BaFe(2)O(4) prepared by sol-gel route. The resultant barium ferrites composite cathode exhibits uniform particles, pores and elements distribution. In particular, favorable ORR properties of this cathode is demonstrated by very low interfacial resistance of only 0.036 and 0.072 Omega cm(2) at 750 and 700 degrees C and maximum power density of 1295 and 840 mW cm(-2) at 750 and 700 degrees C. (C) 2011 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available