4.6 Article

Electrodeposition of polypyrrole-Au nanoparticles composite from one solution containing gold salt and monomer

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 12, Issue 5, Pages 624-627

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2010.02.015

Keywords

Au nanoparticles; Polypyrrole; Composite material; Electrodeposition

Funding

  1. Polish Ministry of Science and Higher Education [NN204 244534]

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An easy method of preparation of polymer/metal-nanoparticle composites is reported. KAu(CN)(2) and pyrrole do not react (redox reaction) in solutions of moderate pH. The gold complex, due to its inertness, is stable in the presence of 10 mu M CN- for weeks. Therefore the electrodeposition of controlled amounts of polypyrrole and Au nanoparticles on the graphite surface can be done in one solution by applying a sequence of 0.75 and -1.6 V potentials. Pulse deposition of both components leads to substantial improvement of the layer smoothness and homogenous distribution of Au nanocrystallites. (c) 2010 Published by Elsevier B.V.

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