Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 12, Issue 9, Pages 1165-1169Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2010.06.008
Keywords
EE mechanisms; ECE; ECE-DISP1; DISP1; Simulation
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Funding
- CNRS [UMR 8640]
- Ecole Normale Superieure (ENS)
- Universite Pierre et Marie Curie (UPMC)
- French Ministry of Research
- Foreign Ministry of France
- Embassy of France in Ukraine
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The new strategy for adaptive simulation of electrochemical reaction mechanisms described in a previous paper (C. Amatore, O. Klymenko, I. Svir. Electrochem. Commun., (2010), doi:10.1016/j.elecom.2010.06.009) [1] provides an efficient method of obtaining accurate concentration distributions and electrochemical currents. In this paper, this strategy is illustrated and tested more deeply upon simulating several representative classical electrochemical mechanisms involving fast homogeneous comproportionation or disproportionation reactions that pose severe difficulties when simulated by classical finite difference methods including those based on exponentially expanding grids. (C) 2010 Elsevier B.V. All rights reserved.
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