Article
Chemistry, Analytical
E. Mladenova, M. Slavova, E. Mihaylova-Dimitrova, B. Burdin, B. Abrashev, M. Krapchanska, G. Raikova, D. Vladikova
Summary: The article introduces a novel approach for developing carbon-free ceramic gas diffusion electrodes for rechargeable Zn-air batteries, which exhibit good catalytic activity and enhanced stability, durability, and performance. The proposed method includes a planar design incorporating both gas diffusion and catalytic layers in a common body made from commercial perovskites.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Green & Sustainable Science & Technology
Shijiao Sun, Qihang Yan, Meifen Wu, Xiangyu Zhao
Summary: Carbon aerogels are highly attractive materials for secondary batteries due to their unique properties. They can function as electroactive materials or carbon matrices in various applications. Different types of carbon aerogels, derived from different precursors, have been developed and studied, showing potential in battery applications.
SUSTAINABLE MATERIALS AND TECHNOLOGIES
(2021)
Article
Nanoscience & Nanotechnology
Gwangseok Oh, Samuel Seo, Wonkeun Kim, Youngsuk Cho, Hoimin Kwon, Suhyun Kim, Seunghyo Noh, Eunji Kwon, Yeonjong Oh, Jongchan Song, Jiyong Lee, Kyounghan Ryu
Summary: The morphology of Li2O2 discharge products in lithium-air batteries is determined by a seed layer formed by the combination of a cathode and an electrolyte, leading to improved reversibility and cyclability. The formation of a favorable interface between the carbon electrode and electrolyte also enhances oxygen evolution reaction, minimizing electrolyte decomposition. These advancements demonstrate critical progress towards practical applications of lithium-air batteries with good reversibility in pouch-type cell arrangements with 1.34 Ah.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Hieu Quang Pham, Minh Tri Nguyen, Mohamed Tarik, Mario El Kazzi, Sigita Trabesinger
Summary: Control of electrode-electrolyte interfacial reactivity at high voltage is crucial for obtaining high-energy-density lithium-ion batteries. The addition of 2-aminoethyldiphenyl borate (AEDB) as an electrolyte additive has been shown to effectively stabilize both cathode and anode materials, leading to improved overall performance of the battery. The study emphasizes the importance of full-cell testing and demonstrates the significant impact of AEDB on enhancing battery performance.
Article
Chemistry, Multidisciplinary
Yusong Choi, Mark H. Griep, Ji-Youn Kim, Tae-Young Ahn, Tae Ryong Park, Hye-Ryeon Yu, Jang-Hyeon Cho
Summary: The study investigates the potential use of lithium-protective hybrid lithium-air batteries (HLABs) as a power source for the next generation of defense technologies. The cells with SP-CF(x)composite cathode showed significantly higher specific capacity and extended discharge duration, demonstrating significant potential for use in next-generation energy-independent tactical defense units.
Review
Nanoscience & Nanotechnology
Yun Zhao, Yuqiong Kang, John Wozny, Jian Lu, Hao Du, Chenglei Li, Tao Li, Feiyu Kang, Naser Tavajohi, Baohua Li
Summary: Sodium-ion batteries (SIBs), a promising alternative to lithium-ion batteries (LIBs), are essential for future electric vehicles and energy storage systems. While the recycling of spent SIBs and LIBs face similar environmental and economic challenges, the recycling of SIBs is more economically demanding. Proactive strategies must be implemented during the early commercialization stage to ensure easy recycling, low operation costs, and optimal efficiency of SIBs. This Perspective article provides an overview of the components of SIBs, discusses recycling strategies, and highlights the challenges and future prospects of SIB recycling.
NATURE REVIEWS MATERIALS
(2023)
Review
Chemistry, Physical
Claude Delmas, Dany Carlier, Marie Guignard
Summary: This paper provides an overview of research on lithium and sodium layered materials as positive electrodes in lithium (sodium)-ion batteries, focusing on the solid-state chemistry's role in discovering new materials and optimizing properties for different applications. Layered structures, especially lithium-based ones, are considered as the best candidates for high energy density batteries for mobile applications. Through high-temperature solid-state chemistry, many substituted phases have been obtained to stabilize the layered structure and increase the specific capacity.
ADVANCED ENERGY MATERIALS
(2021)
Review
Materials Science, Multidisciplinary
Ruiwang Zhang, Sijie Yang, Haobo Li, Tianyou Zhai, Huiqiao Li
Summary: With the development of electrode materials and the shifting of battery systems, the air sensitivity of electrode materials has become increasingly important. It is of great significance to understand the air degradation mechanism and explore new methods to enhance the air stability of electrode materials for the development of batteries with better performance. This review summarizes the issues related to air exposure of electrode materials in Li/Na ion batteries, including factors related to air sensitivity, degradation mechanisms, and recent progress in improving air stability.
Article
Physics, Applied
Zisheng Liu, Ning Zhao, Xiaohui Zhao, Chenggong Wang, Tao Zhang, Sheng Xu, Xiangxin Guo
Summary: Li-O-2 batteries based on the conversion reaction of oxygen cathodes can deliver high specific capacity. Combining Li-rich layered-oxide cathodes with oxygen cathodes improves cell performance and extends cycle life.
APPLIED PHYSICS LETTERS
(2022)
Article
Electrochemistry
Aroa R. Mainar, J. Alberto Blazquez, Domenico Frattini, Marina Enterria, Nagore Ortiz-Vitoriano, Idoia Urdampilleta, Hans-Jurgen Grande
Summary: Secondary zinc-air batteries (ZABs) show potential as sustainable energy storage, but their current capability is unsatisfactory. The limitations are mainly due to the air electrodes, hindering practical applications and commercialization. This study explores the use of metallic nickel as a conductive additive in the air electrodes, compared to carbon nanotubes (CNT), and demonstrates that the density and interaction of the additive with the active material are crucial for achieving long cycle life. The use of Ni as a conductive agent significantly increased the cycle life of secondary ZABs, delivering more than 2,400 cycles compared to only 88 cycles for carbon-based batteries.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Samira Ait Bahadou, Hamid Ez-Zahraouy
Summary: Rechargeable multivalent metal-ion batteries have great potential for future demands, with V2O3 identified as a promising negative electrode material for Mg/Al-ion batteries based on its calculated properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Xiaolei Li, Zifeng Lin, Na Jin, Xiaojiao Yang, Yibo Du, Li Lei, Patrick Rozier, Patrice Simon, Ying Liu
Summary: Perovskite-type oxide SrVO3 exhibits excellent electrochemical performance as a lithium-ion battery anode, delivering high specific capacity, high areal capacity, and good cycling stability. This study highlights SrVO3 as a promising candidate for future metal-ion battery anodes, opening up opportunities for exploring a variety of perovskite oxides.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Hongjiao Huang, Aoming Huang, Di Liu, Wentao Han, Chun-Han Kuo, Han-Yi Chen, Linlin Li, Hui Pan, Shengjie Peng
Summary: In this study, oxygen vacancy-rich porous perovskite oxide (CaMnO3) nanofibers coated with reduced graphene oxide (rGO) were developed as the air electrode catalyst for low-temperature and knittable Zn-air batteries. The V-CMO/rGO exhibited top-level oxygen reduction reaction (ORR) activity among perovskite oxides and showed impressive kinetics under low temperature. The V-CMO/rGO demonstrated high peak power density of 56 mW cm(-2) and long cycle life of over 80 h at a low temperature of -40°C.
ADVANCED MATERIALS
(2023)
Article
Engineering, Environmental
Lingcong Li, Ruike Zhang, Zhujie Wu, Yao Wang, Jin Hong, Huashang Rao, Zhenxiao Pan, Xinhua Zhong
Summary: The preparation of high-efficiency perovskite solar cells in ambient air environment is challenging. In this study, a simple component engineering strategy is proposed to regulate the crystallization process of perovskite film, leading to improved crystallinity, reduced defect state density, and suppressed non-radiative recombination processes. The efficiency of the carbon-based perovskite solar cells reached a record high.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Yan Lu, Yalin Zhou, Xiaoshi Lang, Tan Wang, Tingting Qu, Lan Li, Chuangang Yao, Xindou Yu, Yuhan Teng, Kedi Cai
Summary: In this work, Ag@NiO is prepared as a highly efficient air electrode catalyst for Li-O2 batteries, using the interface and doping synergistic effect engineering strategy. The interface binding between Ag and NiO is strengthened by generating Ag nanoparticles on the surface of NiO, and the electronic structure is regulated after Ag+ doping, leading to more active sites and high conductivity which boost the catalytic activity. Therefore, Ag@NiO exhibits superior electrochemical performance and opens up new paths for highly efficient air electrode catalysts of Li-O2 batteries through the interface and doping synergistic effect engineering strategy.
Article
Electrochemistry
Y. Yui, Y. Ono, M. Hayashi, Y. Nemoto, K. Hayashi, K. Asakura, H. Kitabayashi
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2015)
Article
Chemistry, Physical
Yuhki Yui, Masahiko Hayashi, Katsuya Hayashi, Jiro Nakamura
SOLID STATE IONICS
(2016)
Article
Multidisciplinary Sciences
Yuhki Yui, Masahiko Hayashi, Jiro Nakamura
SCIENTIFIC REPORTS
(2016)
Article
Chemistry, Physical
Yuhki Yui, Shuhei Sakamoto, Masaya Nohara, Masahiko Hayashi, Jiro Nakamura, Takeshi Komatsu
JOURNAL OF POWER SOURCES
(2017)
Article
Electrochemistry
Masahiko Hayashi, Hironobu Minowa, Masaya Takahashi, Takahisa Shodai
Article
Chemistry, Physical
Elly Setiawati, Masahiko Hayashi, Masaya Takahashi, Takahisa Shodai, Keiichi Saito
JOURNAL OF POWER SOURCES
(2011)
Article
Chemistry, Physical
Elly Setiawati, Masahiko Hayashi, Masayuki Tsuda, Katsuya Hayashi, Ryuichi Kobayashi
JOURNAL OF POWER SOURCES
(2013)
Article
Chemistry, Physical
Hironobu Minowa, Masahiko Hayashi, Katsuya Hayashi, Ryuichi Kobayashi, Kazue Takahashi
JOURNAL OF POWER SOURCES
(2013)
Article
Chemistry, Physical
Elly Setiawati, Masahiko Hayashi, Masayuki Tsuda, Katsuya Hayashi, Ryuichi Kobayashi
SOLID STATE IONICS
(2014)
Article
Chemistry, Physical
Hironobu Minowa, Yuhki Yui, Yoko Ono, Masahiko Hayashi, Katsuya Hayashi, Ryuchi Kobayashi, Kazue I. Takahashi
SOLID STATE IONICS
(2014)
Article
Electrochemistry
Masahiko Hayashi, Shuhei Sakamoto, Masaya Nohara, Mikayo Iwata, Takeshi Komatsu
Article
Electrochemistry
Masahiko Hayashi, Shuhei Sakamoto, Masaya Nohara, Mikayo Iwata, Kota Suzuki, Masaaki Hirayama, Jiro Nakamura, Hajime Arai, Ryoji Kanno, Takeshi Komatsu
Article
Electrochemistry
Shuhei Sakamoto, Hironobu Minowa, Masaya Nohara, Mikayo Iwata, Masahiko Hayashi, Takeshi Komatsu
Article
Electrochemistry
Yuhki Yui, Shuhei Sakamoto, Masaya Nohara, Masahiko Hayashi, Jiro Nakamura, Kota Suzuki, Masaaki Hirayama, Ryoji Kanno, Takeshi Komatsu