Journal
ELECTROCHEMISTRY
Volume 77, Issue 8, Pages 670-672Publisher
ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.77.670
Keywords
Fluorescence; Lanthanides; Pyrochemical Processing; Electrorefining
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Funding
- Ministry of Education, Science and Technology. Republic of Korea
- National Research Foundation of Korea [2007-2000132] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Laser-induced fluorescence was applied for the detection of lanthanide ions such as Tb3+ and Sm3+ in a pyrochemical processing. The fluorescence signals of Tb3+ and Sm3+ in LiCl-KCl molten salts were successfully observed at room temperature. Moreover, the fluorescence method was identified to be sensitive enough to detect a trace of Eu2+, originated from a reduction of Eu3+ contained in a LiCl-KCl eutectic reagent at a given high temperature molten salt condition. The non-destructive and direct fluorescence measurement can be an alternative method in on-line and in situ determination of the species and concentrations of lanthanides in a molten salt along with absorption measurement.
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