Journal
ELECTROANALYSIS
Volume 25, Issue 6, Pages 1557-1566Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201300076
Keywords
Biosensors; Dopamine; Point-of-care; Polyelectrolyte electrodes; Redox polymers
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Funding
- Office of Basic Energy Science, DOE [DE-SC0001302]
- NSF [CMMI-0926381]
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Redox ions are deposited on a polyelectrolyte-coated gold electrode by an electric field to fabricate an ion-selective thin film electrode. The Fe(CN)${{{4- \hfill \atop 6\hfill}}}$ ions are deposited on a few monolayer-coated polyelectrolyte gold electrode by a slow periodic potential cycle. The deposition process and electrode properties are quantitatively and simultaneously monitored by cyclic voltammetry and a novel technique, using a Scanning Electrometer for Electrical Double-layers (SEED). No redox properties are obtained without the electric-field-deposition. Owing to the redox mediation and net charge due to the redox ion, the electrode is ion-selective. We demonstrate the principle to detect 1 mu M of dopamine in a mixture with 1mM of ascorbic acid.
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