Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 6, Issue 18, Pages 3645-3649Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.5b01756
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Funding
- National Science Foundation [DMR-1105185, CHE-1266154]
- Lilly Endowment, Inc.
- Indiana METACyt Initiative
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1266154] Funding Source: National Science Foundation
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Graphene fluorination with XeF2 is an attractive method to introduce a nonzero bandgap to graphene under mild conditions for potential electro-optical applications. Herein, we use well-defined graphene nanostructures as a model system to study the reaction mechanism of graphene fluorination by XeF2. Our combined experimental and theoretical studies show that the reaction can proceed through a radical cation mechanism, leading to fluorination and sp(3)-hybridized carbon in the basal plane.
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