4.8 Article

Atomic-Scale Magnetism of Cr-Doped Bi2Se3 Thin Film Topological Insulators

Journal

ACS NANO
Volume 9, Issue 10, Pages 10237-10243

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsnano.5b03980

Keywords

magnetic topological insulator; spin and orbital moments; XMCD; density functional theory; spintronics

Funding

  1. State Key Program for Basic Research of China [2014CB921101, 2013CB934600, 2011CB921404]
  2. NSFC [61274102, 61474061, 21473168, 11174244, 51390474, 11234011]
  3. Zhejiang Provincial Natural Science Foundation of China [LR12A04002]
  4. Ministry of Education [20120101110087, IRT13037]
  5. UK STFC
  6. Defense Award Research Project Agency (DARPA) [N66001-12-1-4304]
  7. US Department of Energy (DOE) [DE-SC0002623]
  8. NERSC [DE-AC02-05CH11231]

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Magnetic doping is the most common method for breaking time-reversal-symmetry surface states of topological insulators (TIs) to realize novel physical phenomena and to create beneficial technological applications. Here we present a study of the magnetic coupling of a prototype magnetic TI, that is, Cr-doped Bi2Se3, in its ultrathin limit which is expected to give rise to quantum anomalous Hall (QAH) effect. The high quality Bi2-xCrxSe3 epitaxial thin film was prepared using molecular beam epitaxy (MBE), characterized with scanning transimission electron microscopy (STEM), electrical mag :to t :ran sport, and it X-ray magnetic circularly dichroism (XMCD) techniques, and the results were simulated using density functional theory (DFT) with (SOC). We observed a sizable spin moment m(spin) = (2.05 +/- 0.20) mu B/Cr and a small and negative orbital moment m(orb) = (-0.05 +/- 0.02) mu(B)/Cr of the Bi1.94Cr0.06Se3 thin film at 2.5 K. A remarkable fraction of the (Cr-Bi-Cr)(3+) antiferromagnetic dimer in the Bi2-xCrxSe3 for 0.02 < 0.40 was obtained using first-principles simulations, which was neglected in previous studies. The spontaneous coexistence of ferro- and antiferromagnetic Cr defects in Bi1.94Cr0.06Se3 explains our experimental observations and those based on conventional magnetometry which universally report magnetic moments significantly lower than 3 AtB/Cr predicted by Hund's rule.

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