Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 119, Issue 11, Pages 6121-6127Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b00503
Keywords
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Funding
- National Natural Science Foundation of China [21203189, 51222212, 21303006, 21321091]
- National Basic Research Program of China [2013CB834605]
- Chinese Academy of Science [KGZD-EW-T05]
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Although it has been widely accepted that the crystal phase, morphology, and facet significantly influence the catalytic and photocatalytic activity of TiO2, establishing the correlation between structure and activity of heterogeneous reactions is very difficult because of the complexity of the structure. Utilizing ultrahigh vacuum (UHV) based temperature-programmed desorption (TPD) and density functional theory (DFT) calculations, we have successfully assessed the photoreactivity of two well characterized rutile surfaces ((011)-(2x1) and (110)-(1x1)) through examining the photocatalyzed oxidation of methanol. The photocatalytic products, such as formaldehyde and methyl formate, are the same on both surfaces under UV illumination. However, the reaction rate on (011)-(2x1) is only 42% of that on (110)-(1x1), which contradicts previous reports in aqueous environments where characterization of TiO2 structure is difficult. The discrepancy probably comes from the differences of the TiO2 structure in these studies. Our DFT calculations reveal that the rate-determining step of methanol dissociation on both surfaces is C-H scission,; however, the barrier of this elementary step on (011)-(2x1) is about 0.2 eV higher than that on (110)-(1x1) because of their distinct surface atomic configurations. The present work not only demonstrates the importance of surface structure in the photoreactivity of TiO2, but also provides an example for building the correlation between structure and activity using surface science techniques and DFT calculations.
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