Article
Chemistry, Physical
Bingxu Liu, Yinghui Sun, Yonghuang Wu, Kai Liu, Huanyu Ye, Fangtao Li, Limeng Zhang, Yong Jiang, Rongming Wang
Summary: The high-performance MoS2-based phototransistor with enhanced photoresponse is achieved by interfacing few-layer MoS2 with an ultrathin TiO2 layer. The significantly improved photoresponse of the TiO2/MoS2 device is attributed to both interface charge transfer and photogating effects. These findings provide valuable insights into interactions at TiO2/MoS2 interface and may inspire the development of novel optoelectronic devices based on 2D layered materials.
Article
Engineering, Chemical
Yanyan Li, Chaojun Ren, Wenjun Li, Xiaohui Ma, Mei Dong, Liang Geng, Mengchao Li, Hualei Zhou, Ye Liu
Summary: A novel CoAl-LDH/CdSe heterojunction photocatalyst with improved photocatalytic activity was successfully prepared using a facile hydrothermal method. The introduction of CoAl-LDH effectively enhanced the separation efficiency of charge carriers and reduced the surface overpotential. The optimal sample exhibited a H2 generation rate of 602 mu mol g-1 h-1, which was approximately 12 times higher than that of pure CdSe. This work provides an innovative assumption for modifying CdSe-based photocatalysts to achieve excellent hydrogen evolution activity.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Materials Science, Multidisciplinary
Chan Qin, Huan Li, Junbo Zhong, Jianzhang Li, Shengtian Huang, Lan Ma
Summary: The study successfully prepared Cypress leave-like Ag2WO4/BiVO4 heterojunctions using a two-step synthesis technique. Characterization tests including HRTEM, XRD, and EDS confirmed the formation of the heterojunctions. The Ag2WO4/BiVO4 heterojunctions demonstrated significantly higher photocatalytic performance for RhB degradation compared to single BiVO4 and Ag2WO4, with performance 4 and 2 times higher, respectively.
Article
Materials Science, Multidisciplinary
Tongyu Han, Haifeng Shi, Yigang Chen
Summary: In this study, a novel S-scheme system was built by combining CuO with BiVO4 to activate PMS for antibiotic degradation. The system exhibited excellent visible light absorption performance and remarkable charge separation ability, suggesting its potential application in enhancing PMS activation and purifying antibiotics in water.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Xuhao Li, Minghao Zuo, Jiahao Wu, Li Feng, Zizeng Wang, Bingzhi Liu
Summary: The CuFe2O4/CdSe heterostructure photocatalyst shows improved utilization of visible light, enhanced hydrogen production from water splitting, and more efficient charge separation, mainly due to the higher specific surface area and better charge transfer efficiency.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Caitlin R. McGranahan, David F. Watson
Summary: Carbodiimide-mediated coupling chemistry was used to synthesize heterostructures of CdSe and CdTe quantum dots with varying ratios of electron-donating CdTe QDs and electron-accepting CdSe QDs. The relative concentration of electron-accepting CdSe QDs within the mixtures greatly influenced the rate and efficiency of electron transfer.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Yuyan Xu, Zhongkai Xie, Rui Yu, Min Chen, Deli Jiang
Summary: The Co(OH)(2)/CdS photocatalyst, prepared through a solvothermal and co-precipitation method, shows enhanced CO2 reduction activity with high light absorption, efficient charge separation, and complete CO product selectivity. The integration of Co(OH)(2) cocatalyst offers a new pathway for constructing cost-effective photocatalytic materials to achieve highly efficient CO2 reduction activity.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Dengji Yu, Yunfang Zhang, Fang Wang, Jun Dai
Summary: By enhancing the fabrication methods of TiO2 nanotubes and increasing ZnO deposition, significant improvements in photoconversion efficiency and photocurrent response can be achieved, providing new insights for the development of efficient photoanode materials.
Article
Chemistry, Multidisciplinary
Xuewei Wang, Wenming Sun, Yang Tian, Kun Dang, Qimeng Zhang, Zhurui Shen, Sihui Zhan
Summary: Novel heterostructures were constructed by coating rutile TiO2 nanorods with metal organic framework (MOF) materials UiO-66 or UiO-67, resulting in enhanced charge separation efficiency and photocurrent density for photoelectrochemical water splitting.
Article
Chemistry, Physical
Aditya Singh, Sujay Karmakar, Suddhasatwa Basu
Summary: A WO3-BiVO4 (WO-60s/BVO) heterojunction was successfully synthesized, with Cr-doped NiFe-LDH co-catalyst significantly promoting OER kinetics. The sputtered WO3 underlayer facilitated enhanced electron-hole separation, while the NiFeCr-LDH co-catalyst improved LDH electrical conductivity, leading to more efficient transfer of photogenerated charge-carriers.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Physics, Applied
Yongle Zhang, Hanyi Xue, Meng Zhu, Zhaona Wang
Summary: A self-powered photodetector with distinguishable wavelength detection has been developed by using two tandem p-n junctions, which effectively reduce wavelength interference and separate photo-generated carriers. The photodetector achieves bidirectional transient photocurrents for ultraviolet and visible detection, and significantly improves peak-to-peak current through the pyro-phototronic effect.
JOURNAL OF APPLIED PHYSICS
(2023)
Review
Chemistry, Inorganic & Nuclear
Zhengang Guo, Zhifeng Liu
Summary: Photoelectrochemical water splitting is an effective way to capture and convert solar energy into chemical energy, addressing current energy and environmental issues. Enhancing the efficiency of solar energy conversion relies on optimizing the performance of semiconductor photoelectrodes, including photon absorption, charge separation, and surface chemical reactions.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Physical
Deben Li, Jiaxin Zhou, Zhijie Zhang, Ying Jiang, Zhongliang Dong, Jiayue Xu, Chunxia Yao
Summary: A novel S-scheme heterojunction of CsPbBr(3) nanocrystals/CoAl LDH nanosheets was successfully prepared and exhibited superior CO2 photocatalytic reduction activity under visible light. The composite containing 60 wt % CsPbBr(3) showed the best photocatalytic performance, which was enhanced by 2.6 and 9.9 times compared to CsPbBr(3) and CoAl-LDH, respectively. Additionally, the composite demonstrated stable photocatalytic activity even after four cycles. This study provides a new perspective for designing and manufacturing perovskite-based S-scheme photocatalytic systems for CO2 reduction.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Environmental Sciences
G. Ramalingam, C. Maria Magdalane, B. Arjun Kumar, R. Yuvakkumar, G. Ravi, A. Irudaya Jothi, Naresh Kumar Rotte, G. Murugadoss, Antony Ananth
Summary: Cadmium selenide (CdSe) semiconductor nanorods were prepared using hydrazine hydrate and ammonia as reducing agents in a hydrothermal process, resulting in reduced stacking faults and high photocatalytic efficiency. The CdSe nanorods exhibited a crystalline size of 20-30 nm and a bandgap of 2.17 eV, with the presence of oxygen vacancy defects indicated in the photoluminescence spectrum.
ENVIRONMENTAL RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
Yu-Jie Dong, Yong Jiang, Jin-Feng Liao, Hong-Yan Chen, Dai-Bin Kuang, Cheng-Yong Su
Summary: This study designs a ternary WO3/CsPbBr3/ZIF-67 heterostructure for efficient CO2 photoreduction. The results show that this structure has good photoelectric properties, promotes the transfer and separation of photogenerated charge carriers, and enhances CO2 adsorption and activation, thus greatly improving the photocatalytic activity.
SCIENCE CHINA-MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Vivek Kumar, Hector A. Fuster, Nuri Oh, You Zhai, Kishori Deshpande, Moonsub Shim, Paul J. A. Kenis
Review
Materials Science, Multidisciplinary
Yiran Jiang, Seong-Yong Cho, Moonsub Shim
JOURNAL OF MATERIALS CHEMISTRY C
(2018)
Article
Chemistry, Multidisciplinary
Ajit Vikram, Vivek Kumar, Utkarsh Ramesh, Karthik Balakrishnan, Nuri Oh, Kishori Deshpande, Trevor Ewers, Peter Trefonas, Moonsub Shim, Paul J. A. Kenis
Article
Chemistry, Multidisciplinary
Hohyun Keum, Yiran Jiang, Jun Kyu Park, Joseph C. Flanagan, Moonsub Shim, Seok Kim
Article
Chemistry, Physical
Nuri Oh, Logan P. Keating, Gryphon A. Drake, Moonsub Shim
CHEMISTRY OF MATERIALS
(2019)
Article
Nanoscience & Nanotechnology
Sangheon Lee, Joseph C. Flanagan, Jaewook Kim, Alan Jiwan Yun, Byungho Lee, Moonsub Shim, Byungwoo Park
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Physical
Joseph C. Flanagan, Logan P. Keating, Muttanagoud N. Kalasad, Moonsub Shim
CHEMISTRY OF MATERIALS
(2019)
Article
Chemistry, Physical
Gryphon A. Drake, Joseph C. Flanagan, Moonsub Shim
JOURNAL OF CHEMICAL PHYSICS
(2019)
Article
Chemistry, Physical
Ajit Vikram, Arwa Zahid, Saket S. Bhargava, Logan P. Keating, Andre Sutrisno, Ankur Khare, Peter Trefonas, Moonsub Shim, Paul J. A. Kenis
CHEMISTRY OF MATERIALS
(2020)
Review
Chemistry, Multidisciplinary
Gryphon A. Drake, Logan P. Keating, Moonsub Shim
Summary: Colloidal nanocrystal heterostructures with variable three-dimensional morphology have size-, shape-, and composition-dependent electronic structure, enabling the design of solution-processable materials with high performance and programmable functionality. Understanding the thermodynamic and kinetic factors that govern nanocrystal growth is crucial for designing and synthesizing complex materials. This review focuses on the growth mechanisms of nanorod heterostructures, the simplest form of anisotropic nanocrystal heterostructures, and explores the effects of various factors on their growth.
Article
Chemistry, Multidisciplinary
Logan P. Keating, Hyunho Lee, Steven P. Rogers, Conan Huang, Moonsub Shim
Summary: By using transient electroluminescence and time-resolved photoluminescence measurements, the effects of offset voltage on charging and charge transport were examined, revealing different charging processes and mechanisms.
Article
Chemistry, Multidisciplinary
Ajit Vikram, Ken Brudnak, Arwa Zahid, Moonsub Shim, Paul J. A. Kenis
Summary: Colloidal semiconductor nanocrystals with tunable optical and electronic properties offer exciting opportunities for various applications, but identifying optimal synthesis conditions and screening of recipes remain major challenges. An autonomous experimentation platform incorporating machine-learning and automated reactor can accelerate synthesis screening and optimization.
Article
Chemistry, Multidisciplinary
Logan Keating, Moonsub Shim
Summary: This study addresses the unusual phenomena observed during the growth of CuGaS2 nanorods from Cu2-xS seeds, proposing a concurrent seed growth and cation exchange (CSC) mechanism to explain the diverse morphologies and substantial volume increase. It sheds light on the regioselective nucleation of CuInSe2 on kinked CuGaS2 nanorods and provides insights into the growth mechanisms of nanocrystals.
NANOSCALE ADVANCES
(2021)
Article
Nanoscience & Nanotechnology
Ajit Vikram, Arwa Zahid, Saket S. Bhargava, Hyukjin Jang, Andre Sutrisno, Ankur Khare, Peter Trefonas, Moonsub Shim, Paul J. A. Kenis
ACS APPLIED NANO MATERIALS
(2020)
Review
Chemistry, Multidisciplinary
Hyunho Lee, Hyung-Jun Song, Moonsub Shim, Changhee Lee
ENERGY & ENVIRONMENTAL SCIENCE
(2020)