Article
Chemistry, Physical
Yingying Zuo, Junfeng Lv, Ning Wei, Xiguang Chen, Jing Tong
Summary: Ionic liquid surfactants have shown potential as substitutes for traditional amphiphiles due to their tunability and superior properties. However, the effect of cationic structure and anion type on their surface properties remains unclear.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Biochemistry & Molecular Biology
Md. Anamul Hoque, Mohammad Idrish Ali, Malik Abdul Rub, Marzia Rahman, Shahed Rana, Mohammad Majibur Rahman, Dileep Kumar, Naved Azum, Abdullah M. Asiri, Mohammed Abdullah Khan
Summary: In this study, the association behavior of bovine serum albumin (BSA) and cetyl-trimethylammonium bromide (CTAB) was investigated using the conductivity method. The association phenomenon was detected by changes in conductivity and various physico-chemical properties. The interaction between BSA and CTAB was influenced by temperature and hydration extent. The binding interactions were believed to involve H-bonding, ion-dipole, and hydrophobic interactions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
Xiaoxing Lu, Zhizhuo Lu, Rong Zhang, Lijiang Zhao, Hujun Xie
Summary: This study investigates the phase behaviors and pigment extraction performance of ionic liquid-based aqueous two-phase systems formed by piperazinium ILs and anionic surfactants, showing a preference for curcumin separation. Factors influencing extraction efficiency and distribution coefficients, as well as the separation mechanism, were evaluated.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Wenjing Ma, Bin Yang, Hao Zhang, Dalong Sun
Summary: In this study, two ionic liquid surfactants were synthesized using oleic acid, behenic acid, and N, N-dimethylcyclohexylamine. These surfactants greatly reduce the surface tension of water and can form stable emulsions or interfacial gels at specific concentrations. The interfacial gel exhibits a layered structure and can transition between liquid and gel states at different temperatures. However, high temperature and the presence of salt can affect its stability.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Anjali, Abhirup Guha, Siddharth Pandey
Summary: Surfactant self-aggregation behavior within ionic liquid-based media was investigated and compared with that in water. It was found that ionic liquids could effectively screen the charge of surfactant head groups, leading to the formation of mixed micelles. The miscibility of the surfactant mixture was improved with increased ionic liquid content, indicating enhanced charge screening between the ionic liquid and surfactant head groups.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Marcia M. S. Alves, Joao M. M. Araujo, Ivo C. Martins, Ana B. Pereiro, Margarida Archer
Summary: The study investigates the interaction of fluorinated ionic liquids with bovine serum albumin (BSA), demonstrating the potential application value of fluorinated ionic liquids in stabilizing and structurally affecting BSA.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Ana F. C. S. Rufino, Mafalda R. Almeida, Mukesh Sharma, Joao A. P. Coutinho, Mara G. Freire
Summary: With a novel ionic-liquid-based aqueous biphasic system, efficient extraction and separation of bovine serum albumin (BSA) from bovine serum was achieved, with a recovery yield of 85.6% and purity of 61.2% under optimal conditions. The system shows potential as a platform for purifying BSA from serum samples and can be applied to other valuable proteins.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Physical
Lavkesh Kumar Singh Tanwar, Manoj Kumar Banjare, Srishti Sharma, Kallol K. Ghosh
Summary: The effect of [Dmim][BF4] on micellization of anionic surfactants SDS and LDS was studied using surface tension and conductivity techniques, and various physical and chemical parameters were determined. Additionally, fluorescence measurement was used to analyze the aggregation behavior of micellar solutions.
CHEMICAL PHYSICS LETTERS
(2021)
Article
Chemistry, Physical
Yu Chen, Jiaqi Li, Liping Zhao, Huan Chen, Xia Xin, Haihua Wang, Shenshen Li, Wenbing Kang
Summary: Due to the high electronegativity of fluorine atoms, incorporating fluorinated moieties in a polymer can result in unique properties such as low surface energy and self-assembling ability in solution. In this study, a series of amphiphilic copolymers were prepared using three monomers, and their properties were regulated by changing the length of the fluorinated block. One specific copolymer (FAA02) demonstrated low surface tension and self-assembled into pH-sensitive micelles in water.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Zhihao Xu, Meng Mu, Ye Fan, Yinjun Fang, Yongmin Zhang
Summary: In this study, a unique choline-type silicon-containing ionic liquid surfactant SiOCho was developed for the first time, which exhibited excellent surface/interfacial activity, thermodynamic properties, and non-foaming behavior. SiOCho could self-assemble into vesicles, making it a potential alternative to conventional low-foam surfactants.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Environmental Sciences
Sara Ranjbari, Ali Ayati, Bahareh Tanhaei, Amani Al-Othman, Fatemeh Karimi
Summary: In this study, bi-functionalized chitosan beads were successfully prepared and used for the efficient removal of anionic food dye from polluted water. The experimental data showed high adsorption efficiency, fitting well with the pseudo-first-order kinetic model and the Langmuir isotherm model under optimal conditions. The conjugation of chitosan beads with surfactant and ionic liquid introduced a new type of adsorbents for wastewater treatment.
ENVIRONMENTAL RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Risa Kawai, Shiho Yada, Tomokazu Yoshimura
Summary: The study investigated the adsorption and aggregation behavior of different quaternary-ammonium-salt-type amphiphilic compounds with various surfactants, revealing that the surface tension of the mixtures depended on the surfactant structure. The composition and type of mixtures were found to affect the structure of the micelles formed.
Review
Chemistry, Physical
Cornelia S. Buettner, Alice Cognigni, Christian Schroeder, Katharina Bica-Schroeder
Summary: The combination of water and surface-active ionic liquids provides a unique reaction medium for chemical reactions in bulk water. Ionic liquids act as surfactants in aqueous solutions, resulting in solvent systems with unique properties. The use of surface-active ionic liquids is rapidly growing and has applications across various fields of chemistry.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
Beibei Wang, Bangqi Yin, Zhao Zhang, Yixuan Yin, Yang Yang, Haiqiao Wang, Thomas P. Russell, Shaowei Shi
Summary: By using the interactions between nanoparticles and polymeric ligands, nanoparticle surfactants can be generated at the liquid-liquid interface, increasing the binding energy. Through a simplified model, it is found that competitive ligands can reduce the binding energy, leading to the dissociation and disassembly of the surfactants at the interface and allowing the construction of responsive and reconfigurable all-liquid systems.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Nahir Dib, R. Dario Falcone, Angel Acuna, Luis Garcia-Rio
Summary: This study investigates the rate of hydrogen-deuterium exchange in the cation of the ionic liquid-surfactant when it forms reverse micelles. The results show a significant inhibition of deuterium exchange when compared to the bulk solution. The analysis of deuterium exchange in the 2-position of the cation is proposed as a useful tool to explore the properties of reverse micelles formed by this cation.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Gagandeep Singh, Manvir Kaur, Harmandeep Kaur, Tejwant Singh Kang
Summary: A new biodegradable surface active ionic liquid (SAIL) based on caffeine and AOT has been synthesized and investigated for its complexation with lysozyme (LYZ) to develop antimicrobial SAIL-LYZ colloidal complexes. Various techniques have been employed to characterize the formed complexes and monitor their enhanced antimicrobial activity, showing promising results for potential biomedical applications.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Pharmacology & Pharmacy
Dilpreet Singh, Ashok K. Tiwary, Tejwant Singh Kang, Neena Bedi
Summary: This study aimed to optimize the oral formulation of the BCS class IV drug canagliflozin (CFZ) using SS SMEDDS, and evaluate the drug's bioavailability and release rate. The optimized formulation showed a higher dissolution rate of CFZ and significantly increased permeation rate across rat intestines following oral administration.
CURRENT DRUG DELIVERY
(2021)
Article
Chemistry, Physical
Komal Arora, Manvir Kaur, Harjinder Singh, Sekar Karthikeyan, Tejwant Singh Kang
Summary: By utilizing SAIL for aqueous phase exfoliation of graphene sheets and subsequent exposure to sunlight, Ag/AgBr@Graphene nanocomposite with enhanced photocatalytic activity for degrading pollutants was successfully prepared, outperforming other materials in the process.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Amrit Kaur, Manpreet Singh, Harjinder Singh, Raman Kamboj, Sukhprit Singh, Tejwant Singh Kang
Summary: This study investigated the effects of three aromatic salts on the micellization of surface active ionic liquids (SAILs) through various experimental techniques. It was found that the functionalization of the alkyl chain length of SAIL and the relative hydrophobicity and bulkiness of the aromatic anions control the characteristic properties of micellization. The results from different techniques were correlated and found to be in good agreement with each other.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Multidisciplinary
Gagandeep Singh, Manvir Kaur, Manpreet Singh, Harmandeep Kaur, Tejwant Singh Kang
Summary: This study reveals the role of time-dependent hydrolysis of [BF4](-) anion in ionic liquid [BF4] on inducing conformational changes in bovine serum albumin (BSA) and resulting in amyloid fiber formation. The addition of 10% IL in aqueous solution promotes the fibrillation of BSA most effectively among the investigated systems.
Article
Chemistry, Physical
Pallavi Sohal, Rupinder Kaur, Manpreet Singh, Tarlok Singh Banipal, Parampaul Kaur Banipal, Tejwant Singh Kang
Summary: In this study, the binding interactions between dopamine HCl drug and micellar system were investigated using experimental and computational techniques. By studying the physicochemical and thermodynamic properties, it provided insights into the physiological actions of biologically active additives. The results showed that hydrophilic-hydrophilic/ionic and electrostatic interactions play a dominant role in the binding between dopamine HCl, AOT, and SDS in mixed micelles.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Applied
Manpreet Kaur Aulakh, Harjinder Singh, Aseem Vashisht, Tejwant Singh Kang, Renu Sharma
Summary: Sunlight driven Mnn+-ZnO nanohybrids were prepared, and the oxidation state of the co-catalyst greatly influenced the photoactive-response of the nanocomposites in the degradation of organic pollutants.
TOPICS IN CATALYSIS
(2022)
Article
Chemistry, Physical
Manpreet Singh, Harjinder Singh, Omish Sethi, Ashwani Kumar Sood, Tejwant Singh Kang
Summary: The solvation behavior and thermophysical properties of protic ionic liquids (PILs) in other polar solvents have been studied. The density and speed of sound of binary mixtures of a PIL, ethyl ammonium nitrate (EAN), with diethylene glycol (DEG) and its derivatives were measured. Various thermodynamic parameters were determined and discussed, and the role of different functional groups in governing the thermophysical properties was analyzed. Density Functional theory (DFT) calculations were employed to explain the variation in excess molar properties.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Omish Sethi, Manpreet Singh, Ashwani Kumar Sood, Tejwant Singh Kang
Summary: Deep eutectic solvents (DESs) are environmentally friendly solvents with unique properties. This study investigated the self-assembly of a surfactant in DES-water mixtures and explored the catalytic activity of Cytochrome-c (Cyt-c) in the formed colloidal systems. The results showed that DES-water mixtures promote the aggregation of the surfactant and enhance the catalytic activity of Cyt-c.
Article
Thermodynamics
Himani Singh, Qammer Majid, Manpreet Richu, Manpreet Singh, Tejwant Singh Kang, Ashwani Kumar
Summary: This research investigates the thermophysical properties and interactions of tripotassium citrate and sodium benzoate in aqueous solutions with 1-ethyl-3-methylimidazolium ethyl sulfate. The results suggest that hydrophilic-hydrophilic interactions dominate in these systems.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2023)
Article
Chemistry, Multidisciplinary
Manpreet Singh, Sugam Kumar, Vinod Kumar Aswal, Tejwant Singh Kang
Summary: The aggregation behavior of the SAIL and GS in aqueous medium has been studied using various techniques. The extent of synergistic interactions between the components depends on the composition of the surfactant mixture. The properties of the aggregates are influenced by hydrophobic and dipolar interactions, as well as counterion binding.
Article
Chemistry, Multidisciplinary
Harmandeep Kaur, Manpreet Singh, Kuldeep Singh, Arvind Kumar, Tejwant Singh Kang
Summary: In order to promote the utilization of abundant biomass in various applications, greener methods for direct conversion into oxidized graphitic materials should be developed. This study presents a new sustainable method for the low-temperature and fast conversion of wheat straw into oxidized graphitic material using a deep eutectic solvent and microwave irradiation. The resulting graphitic material exhibited enhanced enzymatic activity as a nano-support for cellulase immobilization. The ease of dissolution of wheat straw in the deep eutectic solvent and its conversion to enzyme-friendly oxidized graphitic material represents an environmentally friendly and economical approach.
Article
Chemistry, Multidisciplinary
Harmandeep Kaur, Manpreet Singh, Harjinder Singh, Manvir Kaur, Gurbir Singh, Karthikeyan Sekar, Tejwant S. Kang
Summary: The excessive use of non-biodegradable polyethylene (PE) and the resulting environmental pollution are major concerns worldwide. This study proposes a new method for the dissolution and degradation of PE using deep eutectic solvents (DESs) based on lactic acid and zinc chloride. The dissolved PE can be regenerated using water as an antisolvent. The analysis of the regenerated material confirms its similarity to virgin PE, showcasing the potential of this sustainable process.
Article
Materials Science, Multidisciplinary
Pankaj Bharmoria, Shota Hisamitsu, Yoichi Sasaki, Tejwant Singh Kang, Masa-aki Morikawa, Biplab Joarder, Kasper Moth-Poulsen, Hakan Bildirir, Anders Martensson, Nobuhiro Yanai, Nobuo Kimizuka
Summary: A one-step approach to create bioplastics with efficient and durable photon upconversion is reported by encapsulating non-volatile chromophore solutions into collagen-based protein films. These bioplastics exhibit high absolute TTA-UC efficiency and low threshold excitation intensity even in air, with the efficiency retained up to 8.2% after 2 years of storage under ambient conditions.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Chemistry, Physical
Manvir Kaur, Harmandeep Kaur, Manpreet Singh, Gagandeep Singh, Tejwant Singh Kang
Summary: The new IL-based aqueous microemulsions serve as efficient catalytic reactors for cytochrome c, exhibiting enhanced catalytic activity.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)