4.7 Article

New rhodamine dimer probes for mercury detection via color changes and enhancement of the fluorescence emission: Fast recognition in cellulose supported devices

Journal

DYES AND PIGMENTS
Volume 101, Issue -, Pages 156-163

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2013.09.019

Keywords

Rhodamine; Mercury ion; Fluorescence; Sensor; Solid support; Aqueous detection

Funding

  1. Scientific Association ProteoMass (Portugal)
  2. University of Sao Paulo through NAP-CatSinQ (Research Core in Catalysis and Chemical Synthesis)
  3. FAPESP

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Two rhodamine dimer compounds exhibiting high selectivity and sensitivity for Hg2+ over other metal cations have been studied in absolute ethanol solution. Increase in the absorption and emission signals with a color change from colorless to pink were observed in both cases. Recognition of Hg2+ with both compounds in the gas phase was also explored. Immobilization of the rhodamine probes in cellulose supported systems to evaluate their efficiency on the fast detection of Hg2+ in aqueous phase was also reported. (C) 2013 Elsevier Ltd. All rights reserved.

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