4.7 Article

A porphyrin derivative from cardanol as a diesel fluorescent marker

Journal

DYES AND PIGMENTS
Volume 82, Issue 1, Pages 26-30

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2008.10.015

Keywords

Porphyrin; Cardanol; Marker; Fluorescent marker; Fuel marker; Diesel marker

Funding

  1. Thai Research Fund [MRG4980059]
  2. Center of Excellence for Petroleum, Petrochemicals
  3. Advanced Materials (NCE-PPAM)
  4. Graduate School, Chulalongkorn University

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A novel porphyrin fluorescent marker from a naturally occurring substance, cardanol, is presented. Synthetic routes were investigated to obtain an aldehyde precursor derived from cardanol and the target porphyrin; the conditions for porphyrin formation, choice of acid and reaction time were optimized. The resulting meso-tetrakis(2-methoxy-4-pentadecylphenyl)porphyrin exhibits high solubility in diesel fuel and its strong fluorescence was observed as two characteristic signals; the porphyrin marker was stable in diesel for at least 3 months. The physical properties of the diesel were unaffected by the presence of the porphyrinic marker at a concentration of 2 ppm. (c) 2008 Elsevier Ltd. All rights reserved.

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