Article
Chemistry, Physical
P. A. Sosa-Fernandez, S. J. Miedema, H. Bruning, F. A. M. Leermakers, J. W. Post, H. H. M. Rijnaarts
Summary: The hypothesis states that cation exchange membranes (CEMs) face fouling issues when used in desalination of wastewater from the oil and gas industry, affecting their performance. Fouling experiments were conducted on commercial CEMs with varying solutions, demonstrating that fouling primarily occurs in the presence of polyelectrolytes. The study found that changing the direction of current could remove the polyelectrolyte fouling layer, with precipitation occurring on the opposite side of the membrane.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Engineering, Environmental
Xi Wang, Xiaoyu Zhou, Shuang Ma, Zhe Wang, Erqiang Wang, Zengxi Li
Summary: White carbon black (WCB) is an important silica product widely used in industries. However, the production of WCB using the precipitation method generates a large amount of wastewater containing sodium sulfate and silica. This study explores the use of electrodialysis (ED) as a treatment method for WCB wastewater. The results demonstrate that ED is an effective, low energy-cost, and reliable process for treating WCB wastewater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Chemical
Wenyu Xiang, Minyuan Han, Ting Dong, Jingmei Yao, Le Han
Summary: The study on fouling dynamics of APAM towards AEM during ED reveals that monitoring the variation of the solution and membrane properties can help understand the fouling process. Deposition of APAM gradually hinders current transfer, leading to the formation of a gel layer and blockage of free volume, resulting in increased membrane resistance. Water splitting causes significant pH variation, altering the particle size of APAM and accelerating fouling formation.
Article
Engineering, Chemical
Ivan Merino-Garcia, Svetlozar Velizarov
Summary: Ion exchange membranes play a crucial role in various separation processes, but their performance is significantly limited by fouling issues caused by the heterogeneous and multivalent ionic composition of natural feedwaters. Efficient membrane cleaning strategies are essential to control and mitigate the impacts of fouling phenomena, with a focus on membrane type, characterization, and target application. Promising membrane cleaning approaches, including physical, chemical, and mechanical methods, are summarized and discussed in this review.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Mahamuda Akter, Jin-Soo Park
Summary: This study investigates the impact of surface roughness and hydrophilicity on membrane fouling using two types of ion exchange membranes. The commercially available membranes have rough and hydrophilic surfaces, while the lab-made membranes have smooth and hydrophobic surfaces. The fouling tests confirm that electrical attraction is the main cause of membrane fouling, with anionic and cationic foulants affecting anion and cation exchange membranes, respectively. The results show that a rough surface has a higher fouling tendency in short-term tests, but the fouling can be easily mitigated due to the hydrophilic surface. Conversely, a smooth surface initially reduces fouling, but leads to irreversible fouling due to the accumulation of foulants on the hydrophobic surface.
Article
Engineering, Chemical
Mehdi Sedighi, Mohammad Mahdi Behvand Usefi, Ahmad Fauzi Ismail, Mostafa Ghasemi
Summary: Electrodialysis is a membrane separation method that utilizes an electrical potential difference to separate ions in aqueous solutions. It is used in various industries for water desalination, regeneration, and other applications. The process involves ion exchange membranes, electrodes, and spacers to achieve selective mass transport and create a potential difference. This study discusses different aspects of electrodialysis, including its application, structure, membrane types, electrode materials, spacers, and application in wastewater treatment.
Article
Engineering, Environmental
Xin Jin, Keqian Li, Yixiong Wei, Yabo Shang, Lanzhou Xu, Mengwen Liu, Lu Xu, Xue Bai, Xuan Shi, Pengkang Jin, Jina Song, Xiaochang C. Wang
Summary: A novel CM-E-HOC process was proposed for the treatment of polymer-flooding produced water, achieving in situ self-cleaning and higher removal efficiency compared to the CM-EC process. The CM-E-HOC process showed improved coagulation performance due to the increased oxygen-containing functional groups and polymeric Fe species, resulting in better in situ self-cleaning performance and lower filtration resistance.
Article
Biochemistry & Molecular Biology
Kseniia Tsygurina, Evgeniia Pasechnaya, Daria Chuprynina, Karina Melkonyan, Tatyana Rusinova, Victor Nikonenko, Natalia Pismenskaya
Summary: Electrodialysis is a rapid and reagentless method for stabilizing tartrate in wine. However, fouling of ion-exchange membranes by wine components remains a challenge. This study analyzed the effect of ethanol, polyphenols (mainly anthocyanins and proanthocyanidins), and saccharides (fructose) on the fouling of ion-exchange membranes. The results showed that fouling mechanisms and consequences differ in the absence of an electric field and during electrodialysis. A successful cleaning process was developed to prevent biofouling of ion-exchange membranes and enable selective recovery of high antioxidant activity polyphenols.
Article
Chemistry, Physical
Yuqi Zheng, Yang Jin, Nan Zhang, Dong Wang, Yang Yang, Meng Zhang, Guohui Wang, Wenjuan Qu, Yuting Wu
Summary: This study investigated the preparation of cation exchange membranes (CEMs) by adding MXene to PVDF and tested the performance of these membranes. The results showed that the addition of MXene can improve the fouling resistance and reduce the membrane resistance, with the 3%wt MXene/PVDF membrane achieving the best performance.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Energy & Fuels
Soo-Jin Han, Jin-Soo Park
Summary: The study investigates the fouling tendency of positively charged, negatively charged, and non-charged surfactants on ion-exchange membranes. It is found that charged foulants in seawater could significantly foul the membranes, while the worst fouling behavior is observed when charged foulants are present in river streams. Through zeta potential measurement, it is demonstrated that the Debye length of charged foulants decreases in seawater streams due to higher ionic strength, leading to lower net electrostatic effect and less fouling tendency in reverse electrodialysis.
Review
Biochemistry & Molecular Biology
Lasaad Dammak, Julie Fouilloux, Myriam Bdiri, Christian Larchet, Estelle Renard, Lassaad Baklouti, Veronika Sarapulova, Anton Kozmai, Natalia Pismenskaya
Summary: Electrodialysis (ED) is highly recommended for water desalination due to its high water recovery and low electricity consumption, but in the food industry, issues such as limitations in IEMs lifetime and organic fouling pose challenges. Classifying and analyzing the fouling phenomena can help in effectively controlling and addressing these issues.
Article
Engineering, Chemical
Francesco Deboli, Bart Van der Bruggen, Mateusz L. Donten
Summary: This work presents a versatile chemistry platform for the fabrication of hierarchical cation and anion exchange membranes (hCEMs and hAEMs) with tuneable transport properties. The hierarchical ion exchange membranes were made by coating and UV crosslinking an acrylic ionomer on top of a PVC-SiO2 porous substrate. The properties and performance of the membranes were found to be dependent on the coating crosslinking density, with higher crosslinking density resulting in better selectivity and performance.
Article
Engineering, Chemical
Yakubu A. Jarma, Ezgi Cermikli, Deniz Ipekci, Esra Altiok, Nalan Kabay
Summary: Two electrodialysis (ED) stacks with different membranes were compared for simultaneous separation and recovery of boron and lithium. The results indicated that under certain operational parameters, the best separation efficiency was achieved at 20 V electrical potential.
Article
Engineering, Chemical
Joonhyeon Kim, Sangha Kim, Rhokyun Kwak
Summary: This study investigates the effects of non-conductive pattern structures on ion transport through ion exchange membranes in electrodialysis (ED). The study identifies two factors, electric view factor and vortex intensity, that control conductive/convective ion transports. Experimental results on a two-dimensional ED platform show that these factors play a significant role in determining current, ion conduction, and salt removal performance.
Article
Engineering, Chemical
Yuanyue Sun, Yuanfa Liu, Xitong Zhang, Wenwen Zhang, Xuan Wang, Yuemeng Yue, Jing Guo, Yue Yu
Summary: A novel CO2-responsive copolymer was successfully synthesized and used in the fabrication of a blend membrane with switchable water flux. The protonation reaction of PDEAEMA segments within the membrane pores after CO2 aeration led to pore shrinkage and reduced water flux. By taking advantage of the CO2-stimulus responsiveness, a green cleaning method using alternate aeration was adopted to clean protein on the membrane surface, achieving a satisfactory flux recovery rate comparable to traditional cleaning methods.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Xingtao Zuo, Wenxin Shi, Zhaodong Tian, Shuili Yu, Shuo Wang, Jiajie He
Article
Engineering, Chemical
J. He, K. Yang, M. Dougherty, C. Li, Y. Wan
DESALINATION AND WATER TREATMENT
(2009)
Article
Ecology
Jiajie He, Mark Dougherty, Abdelaziz AbdelGadir
ECOLOGICAL ENGINEERING
(2013)
Article
Engineering, Environmental
Jiajie He, Mark Dougherty, Richard Zellmer, George Martin
ENVIRONMENTAL ENGINEERING SCIENCE
(2011)
Article
Environmental Sciences
Qian Zhang, Jiajie He, Hongyu Wang, Fang Ma, Kai Yang, Jingbo Wang
ENVIRONMENTAL TECHNOLOGY
(2013)
Article
Environmental Sciences
Jiajie He, Mark Dougherty, Francisco J. Arriaga, Abdelaziz H. AbdelGadir
ENVIRONMENTAL TECHNOLOGY
(2013)
Article
Agronomy
Jiajie He, Mark Dougherty, Francisco J. Arriaga, John P. Fulton, Charles W. Wood, Joey N. Shaw, Clifford R. Lange
IRRIGATION SCIENCE
(2013)
Article
Environmental Sciences
Jiajie He, Mark Dougherty, Joey Shaw, John Fulton, Francisco Arriaga
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2011)
Article
Engineering, Civil
Kai Yang, Yingwen Xue, Jiajie He, Xiaojun Yang
JOURNAL OF WATER SUPPLY RESEARCH AND TECHNOLOGY-AQUA
(2008)
Article
Engineering, Environmental
Jiajie He, Clifford R. Lange, Mark Dougherty
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2009)
Article
Engineering, Environmental
Kai Yang, Jiajie He, Mark Dougherty, Xiaojun Yang, Lu Li
WATER SCIENCE AND TECHNOLOGY
(2009)
Article
Engineering, Environmental
Hongyu Wang, Jiajie He, Kai Yang
WATER SCIENCE AND TECHNOLOGY
(2010)
Article
Engineering, Environmental
Xingtao Zuo, Wenxin Shi, Shuili Yu, Jiajie He
WATER SCIENCE AND TECHNOLOGY
(2012)
Article
Environmental Sciences
Qian Zhang, Jiajie He, Hongyu Wang, Kai Yang, Fang Ma
FRESENIUS ENVIRONMENTAL BULLETIN
(2013)
Article
Engineering, Chemical
Arvin Sohrabi, Mousa Meratizaman, Shuli Liu
Summary: This paper simulates and discusses possible solutions to improve the economic and technical performances of a battery-less renewable energy-powered BWRO system under real climate conditions. The study finds that the photovoltaic-based system performs better in terms of specific energy consumption and unused energy ratio.
Article
Engineering, Chemical
Chunlan Pan, Xiaoyin Hu, Vishal Goyal, Theyab R. Alsenani, Salem Alkhalaf, Tamim Alkhalifah, Fahad Alturise, Hamad Almujibah, H. Elhosiny Ali
Summary: This paper introduces a novel waste heat recovery method using the hot flue gas from a ship's engine to produce liquefied hydrogen while meeting the ship's air-conditioning requirement. A comprehensive feasibility assessment is conducted and an artificial neural network with a multiobjective grey wolf optimization method is used for optimization. The findings indicate the highest mean sensitivity index of the flash temperature and the best optimization scenario for exergy efficiency, CO2 emission reduction, and liquefied hydrogen cost.
Article
Engineering, Chemical
Daniele Chinello, Jan Post, Louis C. P. M. de Smet
Summary: In this study, PVDF-based anion-exchange membranes were designed to selectively separate nitrate from chloride. Experimental data showed that increasing the concentration of PVDF enhanced nitrate transport but also increased the membrane electrical resistance. The selectivity of nitrate was found to be independent of the membrane thickness and mainly driven by the increased affinity between the anion and the membrane.
Article
Engineering, Chemical
Umar Noor, Muhammad Fayyaz Farid, Ammara Sharif, Amna Saleem, Zubair Nabi, Muhammad Furqan Mughal, Kiran Abbas, Toheed Ahmed
Summary: Global water scarcity is increasing, and water desalination is an important solution. Multifunctional advanced materials, such as membrane materials and solar-driven desalination, play a crucial role in water desalination. Additionally, these materials can be used for water purification, wastewater treatment, and pollutant elimination.
Article
Engineering, Chemical
Emrah Gumus
Summary: With growing global concerns about climate change and environmental impacts, the use of nuclear energy in naval vessels offers a cleaner and more efficient solution to reduce emissions and address water and energy supply challenges. This study explores a novel system that combines a nuclear-driven supercritical carbon dioxide power cycle with reverse osmosis cogeneration to meet the water and electricity demands in maritime operations, enhancing the sustainability, efficiency, and self-sufficiency of naval vessels. The results indicate that the system has the potential to be a viable and effective solution for naval operations.
Article
Engineering, Chemical
Dao Thi Thanh Huyen, Saikat Sinha Ray, Young -Nam Kwon
Summary: This study focuses on the modification of a commercially available polyamide thin-film composite membrane with a zwitterionic material to enhance its fouling resistance. The modified membrane shows improved salt rejection and reduced permeability compared to the pristine membrane. Fouling tests demonstrate that the modified membrane has a lower fouling ratio and higher recovery ratio. The enhanced antifouling characteristics are attributed to the improved hydrophilicity resulting from the zwitterionic brushes and the salting-in effect.
Article
Engineering, Chemical
Niklas Koeller, Lukas Mankertz, Selina Finger, Christian J. Linnartz, Matthias Wessling
Summary: This study presents a methodology to scale up Flow-electrode Capacitive Deionization (FCDI) technology from lab-scale to pilot-scale systems. By increasing membrane area and using a stacking approach, the FCDI modules were successfully scaled up and achieved a salt transfer rate comparable to lab-scale systems. This provides a foundation for future assessments of energy demand and economics.
Article
Engineering, Chemical
Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han
Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.
Article
Engineering, Chemical
Zhiqiang Zhang, Ruifeng Deng, Jiao Zhang, Lu She, Guangfeng Wei, Renyong Jia, Pengyu Xiang, Siqing Xia
Summary: A transmembrane electro-chemisorption system with authigenic acid and base was developed for enhancing ammonia recovery from strong ammonia wastewater. The system efficiently transformed ammonium into free ammonia, which was then adsorbed and recovered through transmembrane chemisorption. This system yielded pure (NH4)2SO4 product and produced valuable byproducts of pure hydrogen and oxygen. Higher applied voltage resulted in better ammonia recovery.
Article
Engineering, Chemical
Alena Popova, Sandrine Boivin, Takuji Shintani, Takahiro Fujioka
Summary: This study aimed to produce a high-integrity RO membrane by forming a polyamide skin layer on a TE support layer, in order to enhance the integrity of the membrane and improve the microbiological safety of potable water reuse.
Article
Engineering, Chemical
Sanjana Yagnambhatt, Saber Khanmohammadi, Jonathan Maisonneuve
Summary: This study investigates the concept of using heat to enhance reverse osmosis (RO) desalination. The effect of temperature on water permeate flux, specific energy, permeate quality, and applied operating pressures is evaluated using an analytical model. The results suggest that under specific conditions, the tradeoff between savings in mechanical pump work and thermal energy input in thermally-enhanced RO can be favorable, leading to overall energy savings.
Article
Engineering, Chemical
Jiangju Si, Chenrui Xue, Shun Li, Linchao Yang, Weiwei Li, Jie Yang, Jihong Lan, Ningbo Sun
Summary: To meet the huge demand for lithium resources, there is an urgent need to develop a new efficient technology for lithium recovery from salt-lake brines. In this study, a selective membrane capacitive deionization system is reported, which achieves high lithium recovery capacity and rate through the use of materials with efficient intercalated pseudo-capacitance and a high specific area porous carbon. The use of a modified thin-coated membrane allows for selective Li+ recovery, and adjusting the concentrations of Li+ and Mg2+ in the feed solution enables higher Li+/Mg2+ selectivity.
Article
Engineering, Chemical
Mohamed R. Salem, R. Y. Sakr, Ghazy M. R. Assassa, Omar A. Aly
Summary: This research proposes a new method of using wasted thermal energies as an additional heating source for solar still distillation units (SSDUs) to increase productivity and reduce pollution and global warming. By testing two SSDUs, the study shows that heating airflow can raise temperatures, enhance freshwater production, and improve system thermal efficiency.
Article
Engineering, Chemical
Qimeng Sun, Miao Sun, Linyan Yang, Yuan Gao, Xinghai Zhou, Lihua Lyu, Chunyan Wei
Summary: This study presents an innovative design and fabrication of a fabric-based conical roll (FCR) evaporator, which enables low-temperature evaporation and achieves high evaporation efficiency with excellent thermal management ability. The evaporator has demonstrated advanced light-harvesting capability and can produce freshwater that meets drinking water standards, showing great potential for applications in desalination and sewage treatment.
Article
Engineering, Chemical
Yidong Zhang, Wangfang Deng, Meiyan Wu, Chao Liu, Guang Yu, Qiu Cui, Pedram Fatehi, Chunlin Xu, Bin Li
Summary: In this study, a novel polydopamine-functionalized lignin-containing pulp foam evaporator with high-efficiency desalination and multi-contaminant adsorption capabilities was designed. The foam evaporator showed excellent light absorption, water absorption, thermal conductivity, and chelation abilities, allowing for solar evaporation and contaminant adsorption synergistically. It also exhibited potential applications in metal ion concentration and contaminated seawater treatments, and demonstrated superior biodegradability compared to poly-styrene foam. This foam material holds promise for developing multifunctional photo-thermal systems for solar-driven water purification.