Journal
DALTON TRANSACTIONS
Volume 47, Issue 38, Pages 13641-13646Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt03104e
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Funding
- National Science Foundation of China [21531002, 21720102004]
- Shanghai Science Technology Committee [13JC1400600]
- Alexander von Humboldt Foundation
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A binuclear iridium complex, (Cp-2*Ir-2(CH2O)C2B10H8) (6), with a unique metal-metal bond has been synthesized and fully characterized. Importantly, this complex is constructed via selective C-H and B(3)-H bond activation on the carborane precursor. Additionally, when the proligand (2-pyridine)(o-carboranyl)methanol ligand was combined with a half-sandwich iridium complex, selective B(6)-H bond activation or metal-carbon bond formation can be induced by the use of different bases. And the rhodium complex constructed from (2-pyridine)(o-carboranyl)methanol ligand containing a metal-carbon bond has been obtained and fully characterized.
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