Article
Chemistry, Multidisciplinary
Song Yu, Pascal Vermeeren, Trevor A. Hamlin, F. Matthias Bickelhaupt
Summary: The study demonstrates that an external electric field along the reaction axis enhances electrostatic and orbital interactions, lowering the reaction barrier. However, a field perpendicular to the reaction axis stabilizes only one stereoisomer pathway of the reaction.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Physical
Xiangqian Wang, Haiyan Wang, Lifeng Zheng, Chun Zhu, Jin-Xia Liang
Summary: The study systematically investigates Mn-corrolazine-catalyzed CH(4)oxidation and the regulation of its oriented external electric fields using first-principle calculations. The results show that when an external electric field is applied, the reactant and transition state of the oxidation reaction are stabilized, leading to a decrease in activation energy.
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
(2021)
Article
Chemistry, Organic
Ruben Van Lommel, Rik H. Verschueren, Wim M. De Borggraeve, Freija De Vleeschouwer, Thijs Stuyver
Summary: In this study, the authors investigated the effects of an electric field on a set of model radicals with varying complexity. They found that the electric field influenced the intrinsic philicity of the radicals, as measured by the global electrophilicity index, omega. The extent of change in philicity depended on the directionality and strength of the applied electric field, as well as the dipole moment and polarizability of the radicals.
Article
Environmental Sciences
J. Lee, C. Sorensen, J. Lemery, C. F. Workman, H. Linstadt, M. D. Bazilian
Summary: This paper adopts a public health-oriented perspective to review the impact of upstream gas emissions from oil and natural gas on global climate change and local public health. The authors highlight the issues of emissions monitoring and propose options and policy recommendations to address them.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Chemistry, Physical
Tarek Scheele, Tim Neudecker
Summary: Oriented external electric fields have a strong effect on the mechanical force required to activate mechanophores, with the degree of this effect depending on the angle at which the field is applied. Mechanical force amplifies the effect of the electric field on the scissile bond of a mechanophore. Combining methods to simulate molecules in electric fields and applying mechanical force allows for an effective analysis of mechanophores in external electric fields.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Tarek Scheele, Tim Neudecker
Summary: Oriented external electric fields have a strong effect on the mechanical force required to activate mechanophores, lowering the rupture force depending on the angle of application. Mechanical force amplifies the effect of OEEFs on mechanophores.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Review
Crystallography
Niall J. English
Summary: Elucidating the mechanisms of molecular solidification in both homo- and heterogeneous systems, especially the effect of external applied fields like electric fields, is crucial for understanding natural phenomena, conducting state-of-the-art experiments, and optimizing industrial processes.
Review
Chemistry, Physical
Shiyue Wu, Xiaoqing Yang, Heng Jing, Yue Chu, Jianping Yuan, Zhanxia Zhu, Kama Huang
Summary: In this study, the effect of external electric fields on the interaction between sulfur dioxide and water was investigated using density functional theory (DFT) and molecular dynamics (MD) methods. The results showed that the electric field reduces the binding energy between sulfur dioxide and water, inhibits the diffusion of sulfur dioxide, and decreases its solubility.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Thermodynamics
Yong Tang, Qiang Yao, Marien Simeni Simeni, Igor V. Adamovich
Summary: This study investigates the response of counterflow diffusion flames to sub-breakdown DC and AC electric fields, as well as their superposition with ns pulse discharge waveforms in the plane-to-plane electrode geometry. The results show that sub-breakdown DC and low-frequency AC electric fields displace the flame towards the grounded electrode. However, as the AC frequency increases, the flame response becomes less pronounced. Combining a nanosecond pulse discharge with a sub-breakdown DC field generates a diffuse plasma across the entire gap. The rapid plasma self-shielding in the plane-to-plane geometry prevents the detectable flame displacement enhancement observed in other electrode geometries.
COMBUSTION AND FLAME
(2022)
Article
Chemistry, Multidisciplinary
Xiangyu Ge, Xiaodong Wu, Qiuyu Shi, Wenzhong Wang
Summary: This study investigated the lubrication performances of polyalkylene glycols, which are insulating oils, under external electric fields. The results showed that these electric fields significantly influenced the lubrication performances and there was an optimal voltage for friction reduction improvement. Surface analysis and experimental results indicated that the formation of adsorption film and the reduction of certain substances contributed to improved friction performance under negative voltage conditions. This work demonstrated the impact of external electric fields on the lubrication performances of insulating oils and proposed a lubrication model for understanding the lubrication mechanisms in electric environments.
Article
Polymer Science
Alina Wettstein, Diddo Diddens, Andreas Heuer
Summary: This study investigates the effects of an external electric field on poly(ethylene oxide) (PEO) doped with lithium-bis-(trifluoromethane)sulfonimide (LiTFSI) salt through extensive atomistic molecular dynamics simulations. The research reveals a transformation in the structure of PEO chains and nonlinear behavior in dynamic properties under the influence of the electric field. Surprisingly, the study shows a slowdown in ion transport instead of enhancement due to structural changes induced by the field application.
Article
Materials Science, Multidisciplinary
Jinrong Huo, Haocong Wei, Ling Fu, Chenxu Zhao, Chaozheng He
Summary: In this study, Pt-M/BC3N2 (M=Ag, Al, Au, Co, Cr, Cu, Fe, Ir, Mn, Mo, Nb, Ni, Pd, Pt, Re, Rh, Ru, Se, Ta, Ti, V, W, Zn, La, Ce, Zr, Hf, Cd, Hg and Y) diatomic catalyst structure was constructed and used to activate Ammonia Borane (AB) under external axial electric field by the First-principles calculation method. It was found that only Pt-M/BC3N2 (M=Al, Zn, Hf, Y) diatomic catalyst can activate the N-H bond in AB, and the effective electric field range is different. Further calculation showed that PtY/BC3N2 diatomic catalyst could not break the B-H bond. Therefore, by sequentially applying an applied electric field, the breakage of the B-H bond in AB and the formation of 1 mol H2 can be achieved with Pt-M/BC3N2 (M=Al, Zn, Hf) diatomic catalyst. This indicates that the electric field can act as a switch for activation of AB molecules.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Energy & Fuels
Jie Chen, Chanjuan Liu, Zhengcai Zhang, Nengyou Wu, Changling Liu, Fulong Ning, Bin Fang, Yizhao Wan, Qingtao Bu, Gaowei Hu
Summary: Strong static electric fields can induce the migration of Na+ and Cl- ions, leading to the decomposition of methane hydrate. Increasing electric field strength enhances the destructive ability of ions to hydrate, resulting in faster decomposition. This study provides insights into a new method for natural gas hydrate extraction and inhibition of hydrate formation in pipelines, as well as the potential of using hydrate as a new ion exchange membrane material in the future.
Article
Chemistry, Multidisciplinary
Jie Wu, Tairen Long, Haiyan Wang, Jin-Xia Liang, Chun Zhu
Summary: This study investigates the reaction mechanism of methane conversion to methanol catalyzed by Fe(IV)-Oxo-Cz and the regulation effect of oriented external electric fields (OEEFs) through density functional calculations. The results show that Fe(IV)-Oxo-Cz can react with methane to form an intermediate, which then forms methanol as the product. OEEFs can effectively regulate the reaction by adjusting the stability of the reactant and the transition state, thereby improving the selectivity of the reaction.
FRONTIERS IN CHEMISTRY
(2022)
Review
Crystallography
Niall J. English
Summary: This article discusses the impact of externally applied electric fields on the properties of crystals, focusing on the role of thermodynamic and kinetic processes in crystals and providing a framework for predictive molecular design to enhance understanding of field crystals.
Article
Engineering, Chemical
Da Ke, Minjia Wang, Jiancheng Ruan, Xinzhi Chen, Shaodong Zhou
Summary: Continuous preparation of pyromellitic dianhydride (PMDA) from durene was studied using a fixed-bed reactor. The reaction was performed with a phosphorus-vanadium-titanium ternary catalyst, resulting in high selectivity and yield of PMDA. In-situ characterization combined with theoretical calculation was used to uncover the reaction mechanisms, and the significant doping effect was discussed.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Yao Wu, Cong Zhao, Yanzhuang Su, Sason Shaik, Wenzhen Lai
Summary: The copper-dependent formylglycine-generating enzyme (FGE) catalyzes the oxygen-dependent oxidation of specific peptidyl-cysteine residues to formylglycine. Our QM/MM calculations provide a likely mechanism for this transformation, suggesting the involvement of a triplet Cu-II-superoxide complex and a Cu-I-alkylperoxo intermediate. The results also indicate that the aldehyde oxygen of the final product originates from O-2.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Xing Liu, Yunpeng Hou, Fangqi Yang, Yueyue Liu, Haoming Yu, Xinxin Han, Jingwen Chen, Shixia Chen, Shaodong Zhou, Shuguang Deng, Jun Wang
Summary: In this study, novel electrocatalysts Ni@NCNT were synthesized by encapsulating Ni nanoparticles in N-rich carbon nanotubes using chemical vapor deposition method. The optimized Ni@NCNT-700 showed high Faradic efficiency for ethanol synthesis in a wide potential range, with ethanol as the sole liquid product. In-situ Raman and density functional theory calculations revealed that the synergistic effects of Ni nanoparticles and NCNTs lowered the energy barrier for C-C coupling and suppressed *CO desorption.
Article
Chemistry, Physical
Bowei Yuan, Shi-Ya Tang, Shaodong Zhou
Summary: This paper reviews the fundamental aspects of the challenges related to C-H activation in gas-phase cluster reactions. The size effect is found to play a crucial role in regulating both the reactivity and selectivity of the activation processes. The authors discuss the size effect in hydrocarbon oxidation by early transition metal oxides and main group metal oxides, as well as in methane activation mediated by late transition metals, based on mass-spectrometry experiments and quantum chemical calculations.
Article
Chemistry, Multidisciplinary
Xi He, Weili Song, Xuemin Liu, Jiamin Huang, Ruilong Feng, Shaodong Zhou, Jianquan Hong, Xin Ge
Summary: A sustainable and general multicomponent cross-coupling method for the synthesis of 3-chalcogenylindoles from indoles using aryl iodides and elemental sulfur under aqueous micellar conditions is developed. Elemental sulfur serves as an eco-friendly and easy-handling sulfur source, generating thiyl radicals. The synergic effect between Cu catalysts and micelles formed by the sugar-based surfactant GluM stabilizes thiyl radicals, enabling C-S coupling with readily available indoles through single-electron transfer. The aqueous micellar system can be recycled and reused with good yields and can also be extended to the conversion of elemental selenium.
Article
Chemistry, Multidisciplinary
Surajit Kalita, Hagai Bergman, Kshatresh Dutta Dubey, Sason Shaik
Summary: Alzheimer's disease and other neurodegenerative diseases characterized by senile plaques are caused by the accumulation of s-amyloid peptides. This study investigates the behavior of these plaques in the presence of static and oscillating oriented external electric fields using molecular dynamics simulations. The results show that long-term disintegration of the plaques is desirable for therapeutic treatments. Furthermore, the use of oscillating oriented external electric fields leads to irreversible disintegration of the aggregated s-amyloid peptides.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Xuan Zhang, Zikuan Wang, Zhen Li, Sason Shaik, Binju Wang
Summary: This study reveals that the proximal [4Fe-4S] cluster in the reductive dehalogenase PceA can facilitate a proton-coupled electron transfer process to quench the substrate radical. The participation of [4Fe-4S] in mediating a PCET process in RDases is unexpected, although it is well known in reducing Co(II). The Arg305 residue acts as an efficient proton donor for the PCET reactions in RDases.
Article
Chemistry, Multidisciplinary
Thomas Weiske
Summary: This article provides selected personal reminiscences from Prof. Helmut Schwarz's decades of interaction with his research group, in celebration of his 80th birthday.
ISRAEL JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Zhanfeng Wang, Binju Wang, Wenwen Diao, Peng Wu, Junfeng Li, Yuzhuang Fu, Zhiyong Guo, Zexing Cao, Sason Shaik
Summary: P450 TleB catalyzes the oxidative cyclization of a dipeptide, resulting in the formation of indolactam V. Understanding the catalytic mechanism is important for future design and engineering of similar reactions using P450 enzymes.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Agronomy
Xin Wang, Shaodong Zhou, Jie Wang, Wenxin Lin, Xiaolei Yao, Jiaqing Su, Haiyang Li, Chao Fang, Fanjiang Kong, Yuefeng Guan
Summary: This study investigated the genetic basis of biomass accumulation in soybean plants. It identified 10 loci and 47 candidate genes related to biomass traits, and highlighted a potential candidate gene for future soybean breeding.
MOLECULAR BREEDING
(2023)
Article
Chemistry, Multidisciplinary
Bowei Yuan, Jingxiang Zou, Mincheng Yu, Shaodong Zhou
Summary: Gas-phase reactions of [LnO](+) with methane have been studied using ICPMS and quantum chemical calculations. It was found that [EuO](+) and [YbO](+) exhibit the highest reactivity and a novel HAT process was revealed.
SCIENCE CHINA-CHEMISTRY
(2023)
Article
Multidisciplinary Sciences
Jinming Fan, Chao Qian, Shaodong Zhou
Summary: This paper presents a corrected group contribution (CGC)-molecule contribution (MC)-Bayesian neural network (BNN) protocol for accurate prediction of absorption spectra. By combining BNN with CGC methods, accurate and efficient prediction of full absorption spectra of various molecules is achieved using a small dataset for training.
Article
Chemistry, Physical
Yanyan Liu, Shuyue Wang, Minghao Sun, Min Ling, Shaodong Zhou, Chengdu Liang
Summary: This study reports a method of inducing homogeneous lithium deposition by minimizing the surface energy discrepancy of lithium crystal faces, successfully achieving dendrite-free lithium anode and exhibiting excellent electrochemical performance in symmetric cells and full cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Lanxiang Yang, Shuyue Wang, Chao Qian, Shaodong Zhou
Summary: The synthesis and high performance of VS4-140 material in electrocatalytic nitrogen reduction are reported. First-principles calculations reveal the different behaviors of VS2 and VS4-140 in terms of reaction mechanism and electronic origins.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Jiapeng Ji, Yunpeng Hou, Shiyu Zhou, Tong Qiu, Liang Zhang, Lu Ma, Chao Qian, Shaodong Zhou, Chengdu Liang, Min Ling
Summary: This study investigates the oxygen evolution reaction (OER) activity of single-atom catalysts (SACs) and reveals that oxygen-coordinated atomic metal species exhibit unique catalytic properties due to the weaker M-O bond compared to the M-N bond. A series of metal-oxygen-carbon structured low-nucleus clusters (LNCs) were successfully anchored on the surface of multiwalled carbon nanotubes (M-MWCNTs) using a low-temperature gas transfer method. The synthesized Ni-MWCNTs electrocatalyst demonstrates excellent OER activity and stability under alkaline conditions, surpassing the performances of Co-MWCNTs, Fe-MWCNTs, and RuO2. Density functional theory calculations reveal that the oxidation of low-nucleus Ni clusters lowers the energy barrier of the OER rate-limiting step, making the OER process more energy-efficient. This study presents a novel versatile platform for large-scale manufacturing of oxygen-coordinated LNC catalysts.
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)
