Journal
DALTON TRANSACTIONS
Volume 43, Issue 12, Pages 4668-4673Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt52940a
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Funding
- 973 program [2011CB932504, 2012CB821705]
- NSFC [91222105, 21221001]
- NSF of Fujian Province [2011J06005]
- CAS [XDA07070200]
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The functionalization and modification of the ligand 1,3,5-tris(4-carboxyphenyl) benzene (H3BTB) have been realized with amine (NH2-H3BTB) and hydroxy (HO-H3BTB) groups. Three new Cd(II) compounds based on R-H3BTB ligands (R = -NH2 and -OH) have been synthesized and structurally characterized. Compounds 1 and 2 show pillared-layer frameworks and display strong fluorescence emission ability. Compound 3 features a 3D porous framework with trinuclear Cd units linked by the NH2-BTB ligand. The activated framework of 3 has good gas storage and separation properties for CO2 and hydrocarbons.
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