Synthesis of γ-amidine-functionalized dianionic β-diketiminato lanthanide amides and trianionic β-diketiminato Na/Sm heterobimetallic complexes and their reactivity in polymerization of l-lactide

Reactivity of Dianionic β-Diketiminato Samarium Amide LSmN(SiMe3)2(THF) (L = {(2,6-iPr2C6H3)NC(CH2)CHC(CH3)N(2,6-iPr2C6H3)}2–) toward ArC≡N (Ar = C6H5, p-MeOC6H4) and Ph2C═C═NtBu: A Facile Route for Modification of Dianionic β-Diketiminato Ligands

(2013) Peng Liu et al.   ORGANOMETALLICS

Syntheses and structures of lanthanide borohydrides supported by a bridged bis(amidinate) ligand and their high activity for controlled polymerization of ε-caprolactone, l-lactide and rac-lactide

(2012) Wenbo Li et al.   DALTON TRANSACTIONS

Divalent Lanthanide Complexes Supported by the Bridged Bis(amidinates) L [L = Me3SiN(Ph)CN(CH2)3NC(Ph)NSiMe3]: Synthesis, Molecular Structures and One-Electron-Transfer Reactions

(2012) Lijuan Yan et al.   INORGANIC CHEMISTRY

Syntheses of lanthanide monochloride and monoborohydride complexes supported by bridged bis(guanidinate) ligand and the use of borohydride complexes in polymerization of cyclic esters

(2012) Xingmin Zhang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of Dianionic β-Diketiminate Lanthanide Amides L′LnN(SiMe3)2(THF) by Deprotonation of the β-Diketiminate Ligand L (L = {[(2,6-iPr2C6H3)NC(CH3)]2CH}−) and the Transformation with [HNEt3][BPh4] to the Cationic Samarium Amide [LSmN(SiMe3)2][BPh4]

(2012) Peng Liu et al.   ORGANOMETALLICS

Formation of N-heterocyclic, donor-stabilized borenium ions

(2011) Chika I. Someya et al.   CHEMICAL COMMUNICATIONS

Elegant approach to spacer arranged silagermylene and bis(germylene) compounds

(2011) Sankaranarayana Pillai Sarish et al.   CHEMICAL COMMUNICATIONS

The first bridged lanthanide carbene complex formed through reduction of carbodiimide by diamine-bis(phenolate) ytterbium(ii) complex and its reactivity to phenylisocyanate

(2011) Zhu Du et al.   CHEMICAL COMMUNICATIONS

Synthesis and molecular structure of piperazidine-bridged bis(phenolate) samarium(ii) complex and its reactivity to carbodiimides

(2011) Zhu Du et al.   DALTON TRANSACTIONS

Deprotonation of β-Diketiminate in Sterically Demanding β-(Diketiminato)lanthanide Complexes: Influence of Lanthanide Metals

(2011) Rui Jiao et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Activation of Carbodiimide and Transformation with Amine to Guanidinate Group by Ln(OAr)3(THF)2(Ln: Lanthanide and Yttrium) and Ln(OAr)3(THF)2as a Novel Precatalyst for Addition of Amines to Carbodiimides: Influence of Aryloxide Group

(2011) Yang Cao et al.   INORGANIC CHEMISTRY

Reactivity of N-Heterocyclic Germylene Toward Ammonia and Water

(2011) Wenyuan Wang et al.   ORGANOMETALLICS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Steric control of the reduction of carbodiimides by samarium(ii) and the synthesis of very crowded samarium(iii) complexes

(2010) Marcus L. Cole et al.   DALTON TRANSACTIONS

Controlled synthesis of mononuclear or binuclear aryloxo ytterbium complexes supported by β-diketiminate ligand and their activity for polymerization of ε-caprolactone and L-lactide

(2010) Hongxia Chen et al.   DALTON TRANSACTIONS

Synthesis and characterization of anionic rare-earth metal amides stabilized by phenoxy-amido ligands and their catalytic behavior for the polymerization of lactide

(2010) Min Lu et al.   DALTON TRANSACTIONS

Synthesis and characterization of amine bridged bis(phenolate) lanthanide aryloxides and their application in the polymerization of lactide

(2010) Kun Nie et al.   DALTON TRANSACTIONS

Isomerization of an N-Heterocyclic Germylene to an Azagermabenzen-1-ylidene and Its Coupling to a Unique Bis(germylene)§

(2010) Shenglai Yao et al.   ORGANOMETALLICS

Lanthanide Alkyl Complexes Supported by a Piperazidine-Bridged Bis(phenolato) Ligand: Synthesis, Structural Characterization, and Catalysis for the Polymerization ofl-Lactide andrac-Lactide

(2010) Yunjie Luo et al.   ORGANOMETALLICS

Ring-Opening Polymerization ofrac-Lactide by Bis(phenolate)amine-Supported Samarium Borohydride Complexes: An Experimental and DFT Study

(2010) Hellen E. Dyer et al.   ORGANOMETALLICS

Lanthanide amidinates and guanidinates: from laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films

(2009) Frank T. Edelmann   CHEMICAL SOCIETY REVIEWS

Cleavage of a N−H Bond of Ammonia at Room Temperature by a Germylene

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

Dehydrogenation of LGeH by a LewisN-Heterocyclic Carbene Borane Pair under the Formation of L′Ge and its Reactions with B(C6F5)3and Trimethylsilyl Diazomethane: An Unprecedented Rearrangement of a Diazocompound to an Isonitrile

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

Synthesis, Structure, and Reaction Chemistry of Samarium(II), Europium(II), and Ytterbium(II) Complexes of the Unsymmetrical Benzamidinate Ligand [PhC(NSiMe3)(NC6H3Pri2-2,6)]−

(2009) Shuang Yao et al.   INORGANIC CHEMISTRY

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes

(2009) Yun Xiong et al.   ORGANOMETALLICS

Stable Compounds of Composition LGe(II)R (R = OH, PhO, C6F5O, PhCO2) Prepared by Nucleophilic Addition Reactions

(2009) Anukul Jana et al.   ORGANOMETALLICS

Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C–H bond activation

(2008) Shenglai Yao et al.   CHEMICAL COMMUNICATIONS