4.7 Article

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

Journal

DALTON TRANSACTIONS
Volume 43, Issue 1, Pages 34-37

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt52762j

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Funding

  1. Engineering and Physical Sciences Research Council [EP/J018090/1, EP/H004823/1] Funding Source: researchfish
  2. EPSRC [EP/H004823/1, EP/J018090/1] Funding Source: UKRI

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A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.

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