4.7 Article

Iron catalysed nitrosation of olefins to oximes

Journal

DALTON TRANSACTIONS
Volume 43, Issue 1, Pages 38-41

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51764k

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Funding

  1. DST
  2. BRNS [DM/2011/20/37C/13]
  3. UGC
  4. CSIR, New Delhi, India

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Fe(BF4)(2.)6H(2)O/2,6-pyridinedicarboxylic acid catalysed nitrosation of a wide variety of substituted styrenes has been developed in the presence of t-BuONO/NaBH4 under H-2 pressure (10 bar) in MeOH-H2O (5 : 1) to afford corresponding oximes in good to excellent yields.

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