Journal
DALTON TRANSACTIONS
Volume 43, Issue 34, Pages 12886-12893Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt01199f
Keywords
-
Categories
Funding
- Western Light Talent Training Program of CAS [RCPY201001]
- 973 Program of China [2012CB626803]
- National Natural Science Foundation of China [51302307, U1129301, 51172277, 21101168, 11104344]
- Main Direction Program of Knowledge Innovation of CAS [KJCX2-EW-H03-03]
- Funds for Creative Cross & Cooperation Teams of CAS
- Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period [201130111]
- High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China [201116143]
- Science and Technology Project of Urumqi [G121130002]
- Western Light of Chinese Academy of Sciences [XBBS201217, XBBS201220]
Ask authors/readers for more resources
Two new metal borate-phosphates, Pb4O(BO3)(PO4) (1) and Bi4O3(BO3)(PO4) (2), have been successfully designed and synthesized. The structures of the title compounds were determined by single-crystal X-ray diffraction. The title compounds have similar crystal structures consisting of oxygen-centered (OPb4) or (OBi4) tetrahedra as well as isolated BO3 and PO4 groups. Structural comparison and the Madelung energy calculation indicate that the title compounds also exhibit a strong correlation with the known metal borates and phosphates. In addition, a strategy of BO3-PO4 substitution is proposed for designing new borate-phosphates. Thermal analyses, IR spectroscopy and UV-vis-NIR diffuse reflectance spectroscopy have also been performed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
