Journal
DALTON TRANSACTIONS
Volume 42, Issue 46, Pages 16264-16267Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51642c
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Funding
- CSIR, India
- Department of Science and Technology (DST), India [SR/S1/IC-38/2010]
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Nitrogen dioxide ((NO2)-N-center dot) induces tyrosine nitration through a radical mechanism in biological systems. Two copper(II) complexes, 1 and 2, with ligands L-1 and L-2 [L-1 = 2,4-di-tert-butyl-6-(((2-(dimethylamino)ethyl)(isopropyl)amino)methyl)phenol; L-2 = 6,6'-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2,4-di-tert-butylphenol)], respectively, have been made to react with (NO2)-N-center dot. In both cases, the reduction of the copper(II) center was observed in the presence of (NO2)-N-center dot which induces phenol ring nitration through nitronium ion (NO2+) formation.
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