Article
Chemistry, Multidisciplinary
Hao Yu, Jiaqi Li, Chuan Shan, Tong Lu, Xin Jiang, Junjuan Shi, Lukasz Wojtas, Houyu Zhang, Ming Wang
Summary: In this study, a strategy for the conformational control of metallo-supramolecular cages via the enhancement of ligand dissymmetry was proposed. Four dissymmetrical ditopic ligands were designed and synthesized, allowing for precise control of assembly conformations to form discrete cis-PdnL2n molecular cages by increasing the dissymmetry of length or angle.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Inorganic & Nuclear
Batoul Hosseinzadeh, Mostafa Ahmadi
Summary: Nature offers a variety of transient interactions, which have inspired the introduction of different supramolecular assemblies in synthetic materials to achieve biomimetic functions. Metal-ligand coordination, as one of the most commonly used transient bonds, plays a crucial role in the design of robust and stimuli-responsive metallo-supramolecular polymer networks (MSPNs). However, the coordination geometry of the metal complex is often overlooked, despite significant advancements in controlling the spatial configuration of supramolecular coordination complexes (SCCs). This article classifies existing reports on the coordination geometry of MSPNs and reviews relevant self-sorting mechanisms of SCCs, highlighting the potential of coordination geometry as a new design parameter in polymeric systems.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Polymer Science
Ivana Sloufova, Tereza Urvalkova, Muriel Hissler, Jiri Vohlidal
Summary: New low-bandgap unimers with different size conjugated linkers were prepared and assembled with Zn(II) and Fe(II) ions to form metallo-supramolecular polymers (MSPs). The Zn-MSPs exhibited luminescence extended deep into the NIR region, while the Fe-MSPs showed a specific damping phenomenon in the resonance Raman spectra. A hypothesis was proposed to explain this phenomenon based on the interplay of various factors.
Article
Polymer Science
Shivani Tripathi, Sayan Halder, Banchhanidhi Prusti, Chanchal Chakraborty, Manab Chakravarty
Summary: This paper introduces a new type of metallo-supramolecular polymeric (MSP) complex prepared using terpyridine (TPY) chelating ligands. A flexible and electron-rich N-heptyldiphenylamine was used as a spacer to form a one-dimensional linear polymer. The structural variation of the MSP was controlled by the conformational and electronic diversity of the TPY units. The resulting MSP showed potential for electrochromism and a tricolor electrochromic device with rapid color switching was successfully prepared.
Article
Chemistry, Physical
Xiaohu Qian, Li Li, Yinan Wang, Zhaowen Tian, Haoyin Zhong, Wei Chen, Tao Chen, Jiajun Fu
Summary: By utilizing dynamic metal-ligand interactions to construct a metallo-supramolecular interphase crosslinked by Zn(II)-2,6-bis(1,2,3-triazol-4-yl)pyridines moieties, the stability issues caused by dendrite growth and water-induced parasitic reactions in aqueous zinc metal batteries can be effectively addressed. The designed metallo-supramolecular interphase with a dynamically crosslinked network shows enhanced mechanical resilience, selective transport of Zn2+ cations, and facilitation of the desolvation process. Additionally, this chemically inert and hydrophobic interphase can effectively reduce water-induced side reactions. As a result, stable Zn plating/stripping for 1200 hours at a high current density and capacity can be achieved, along with improved cycling stability in Zn//MnO2 full cells.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Tun Wu, Zhiyuan Jiang, Xiaobo Xue, Shi-Cheng Wang, Mingzhao Chen, Jun Wang, Haisheng Liu, Jun Yan, Yi-Tsu Chan, Pingshan Wang
Summary: Different 3D supramolecular architectures were formed by the reaction of metallo-organic ligands, with the structure variation determined by the position of the bisterpyridines in the ligand.
CHINESE CHEMICAL LETTERS
(2021)
Article
Polymer Science
Andrei Chernyshev, Udit Acharya, Jiri Pfleger, Olga Trhlikova, Jiri Zednik, Jiri Vohlidal
Summary: By assembling four new bis(tpy) unimers with different linkers with Fe2+ ions to metallo-supramolecular polymers, the Fe-MSP films showed excellent optical contrast and coloration efficiency, with Fe-Tt exhibiting the highest performance and potential application in electrochromic devices.
Review
Chemistry, Inorganic & Nuclear
Jack K. Clegg, Feng Li, Leonard F. Lindoy
Summary: Classical 6-diketones have been proven to be excellent chelating ligands for various metal ions across the Periodic Table. Recently, bis-and tris-bidentate derivatives of this ligand class have been increasingly used in diverse studies, resulting in a wide range of metallosupramolecular architectures with interesting properties.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Multidisciplinary
Manas Kumar Bera, Yoshikazu Ninomiya, Masayoshi Higuchi
Summary: The stepwise introduction of three different transition metals into a metallo-supramolecular polymer has successfully led to the synthesis of a polymer with quad-color electrochromic properties. This synthetic method can be extended to fabricate other MSPs with different compositions, exhibiting a broad optical and electrochemical window.
COMMUNICATIONS CHEMISTRY
(2021)
Article
Chemistry, Physical
Zi-Jie Gong, Yemineni S. L. Narayana, Yen-Chun Lin, Wei-Hsiang Huang, Wei-Nien Su, Yi-Pei Li, Masayoshi Higuchi, Wen-Yueh Yu
Summary: In this study, ruthenium-based metallo-supramolecular polymers (Ru-MSPs) were synthesized and used for heterogeneously catalytic transfer hydrogenation of carbonyl compounds. The polymerization process was controlled by adjusting the ligand/metal ratio and synthesis conditions. The coordinatively unsaturated ruthenium atoms were identified as the active sites for carbonyl reduction, and the Ru-MSPs exhibited enhanced activity and reusability compared to monomeric counterparts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Materials Science, Multidisciplinary
Kazuko Fujii, Dines Chandra Santra, Manas Kumar Bera, Takatsugu Wakahara, Ritsuko Nagahata, Masayoshi Higuchi
Summary: In this study, the electrochromic (EC) properties of metallo-supramolecular polymers (MSPs) were improved by forming nanocomposites with a layered inorganic-imidazoline covalently bonded hybrid (LIIm). The nanocomposites exhibited improved mechanical, optical, and gas barrier properties. The findings suggest that nanocomposite thin films can achieve reversible electrochromic behavior.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Polymer Science
Jiaheng Mo, Weijian Wu, Shijie Shan, Danni Li, Rui Li, Yaling Lin, Anqiang Zhang
Summary: Metal-ligand coordination was used to synthesize novel iminocarboxyl-functionalized polysiloxanes with self-healing ability and excellent mechanical properties. The incorporation of zinc ions improved thermal and mechanical properties due to highly dynamic Zn(II)-iminocarboxyl complexation, allowing strain sensitivity in the network.
Article
Engineering, Environmental
Sayan Halder, Siddhant Garg, Chanchal Chakraborty
Summary: Indicative electrochromic supercapatteries with high energy and power densities are gaining attention as a promising renewable energy source. This study developed a non-conjugated pyridinium cation-containing ligand and its metallo-supramolecular polymer. The polymer exhibited excellent electrochromic properties and good supercapacitive behavior, leading to the creation of a hybrid energy storage device with high capacitance, energy density, and cycle stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Polymer Science
Igor Perevyazko, Nina Mikusheva, Alexey Lezov, Alexander Gubarev, Marcel Enke, Andreas Winter, Ulrich S. Schubert, Nikolay Tsvetkov
Summary: This study focuses on the synthesis of poly(methacrylate)-based copolymers and their self-assembly behavior in dilute solutions through supramolecular/coordination interactions with metal ions. The conformational states and hydrodynamic characteristics of the metallo-supramolecular assemblies were determined using various analytical techniques.
Article
Chemistry, Multidisciplinary
Yu Jia, Wen-Li Guan, Juan Liu, Jian-Peng Hu, Bingbing Shi, Hong Yao, You-Ming Zhang, Tai-Bao Wei, Qi Lin
Summary: A novel conductive supramolecular polymer metallogel (PQ-Ag) was developed for sensitive detection of hydrazine hydrate (DH) in water and air. The metallogel PQ-Ag enables multi-channel detection of DH through naked-eye, fluorescence, and electrochemical methods. It has a detection limit lower than the standard of the US EPA for DH in drinking water and can be conveniently and efficiently used for DH detection and alert in water and air using sound and light alarms.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Manas Kumar Bera, Yoshikazu Ninomiya, Masayoshi Higuchi
Summary: The stepwise introduction of three different transition metals into a metallo-supramolecular polymer has successfully led to the synthesis of a polymer with quad-color electrochromic properties. This synthetic method can be extended to fabricate other MSPs with different compositions, exhibiting a broad optical and electrochemical window.
COMMUNICATIONS CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Dines Chandra Santra, Sanjoy Mondal, Takefumi Yoshida, Yoshikazu Ninomiya, Masayoshi Higuchi
Summary: Metallo-supramolecular polymers (MSPs) composed of a metal ion and ditopic ligand have been developed for electrochromic display applications, with polyRu-LBip showing promising properties of low redox potential, reversible color changes, and high durability. The controlled design of the ligand, tetrakis(N-methylbenzimidazolyl)bipyridine (L-Bip), has significantly improved the optical contrast, response time, and coloration efficiency of the solid-state EC device, indicating great potential for practical applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Polymer Science
Kazuko Fujii, Manas Kumar Bera, Dines Chandra Santra, Masayoshi Higuchi
Summary: By forming nanocomposites of polyFe and LIIm, the electrochromic properties can be improved and the memory properties can be enhanced without reducing the contrast in transmittance. The composites exhibit redox waves in the cyclic voltammograms and are estimated to be diffusion controlled.
Article
Chemistry, Physical
Zi-Jie Gong, Yemineni S. L. Narayana, Yen-Chun Lin, Wei-Hsiang Huang, Wei-Nien Su, Yi-Pei Li, Masayoshi Higuchi, Wen-Yueh Yu
Summary: In this study, ruthenium-based metallo-supramolecular polymers (Ru-MSPs) were synthesized and used for heterogeneously catalytic transfer hydrogenation of carbonyl compounds. The polymerization process was controlled by adjusting the ligand/metal ratio and synthesis conditions. The coordinatively unsaturated ruthenium atoms were identified as the active sites for carbonyl reduction, and the Ru-MSPs exhibited enhanced activity and reusability compared to monomeric counterparts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Multidisciplinary
Ravi Ranjan Pandey, Yashvant Kashyap, Anshu Andola, Hideyuki Nakanishi, Rakesh K. Pandey
Summary: We have developed a unique asymmetric supercapacitor design by combining a vertically aligned Ni-Co alloy-type nanowire (NiCoNW) array electrode with a graphene flakes (GFs) electrode. This design allows the device to operate at a high working potential window of 2.0 V. The improved performance of the device is attributed to the asymmetric design and the high charge transfer in the NiCoNWs. The optimized presence of Co in the alloy enhances the rate of hydroxide formation during the gas evolution reaction. The use of GFs to modify the graphite electrode provides a more stable response at high current densities. We achieved a high capacitance of 339 F/cm(3) and observed remarkable cycling retention of approximately 100% after 10000 continuous potential cycles.
Article
Materials Science, Multidisciplinary
Kazuko Fujii, Dines Chandra Santra, Manas Kumar Bera, Takatsugu Wakahara, Ritsuko Nagahata, Masayoshi Higuchi
Summary: In this study, the electrochromic (EC) properties of metallo-supramolecular polymers (MSPs) were improved by forming nanocomposites with a layered inorganic-imidazoline covalently bonded hybrid (LIIm). The nanocomposites exhibited improved mechanical, optical, and gas barrier properties. The findings suggest that nanocomposite thin films can achieve reversible electrochromic behavior.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jian Zhang, Satya Ranjan Jena, Masayoshi Higuchi
Summary: This study presents an electrical color printing approach using electrochromic metallosupramolecular polymers to achieve rewritable image printing. The printed information has a long retention time, high stability, and can be naturally erased under humid conditions.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Chemistry, Physical
Xinran Su, Rakesh K. Pandey, Junhao Ma, Wei Chun Lim, Chi Kit Ao, Changhui Liu, Hideyuki Nakanishi, Siowling Soh
Summary: This manuscript introduces a smart and multifunctional coating based on two-dimensional graphene oxide flakes. The coating can self-assemble and disassemble flexibly, and exhibits stimuli-responsive behavior. Upon contact with water, the coating expands and forms wrinkles, which disappear when the water evaporates. This stimuli-responsiveness can be controlled by temperature or pressure. The results demonstrate that simple 2D flakes can assemble into macroscopic materials with interactive and multifunctional operations.
Article
Polymer Science
Masayoshi Higuchi, Yukio Fujii
Summary: This study successfully developed a designed and flexible electrochromic display device with memory property, which can be used as energy-saving smart windows or digital signages. The display changes were controlled by the etching pattern using mechanical etching technique.
JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY
(2021)
Article
Engineering, Electrical & Electronic
Masayoshi Higuchi, Yukio Fujii, Yoji Hisamatsu
Summary: Metallo-supramolecular polymers (MSPs) are a novel type of electrochromic (EC) materials that show reversible color changes between orange and pale green. The color changes are caused by metal-to-ligand charge transfer (MLCT) absorption. Insulating films can enhance the display effect on EC devices.
ITE TRANSACTIONS ON MEDIA TECHNOLOGY AND APPLICATIONS
(2021)
Article
Engineering, Electrical & Electronic
Hsin-Che Lu, Li-Yin Hsiao, Sheng-Yuan Kao, Yuki Seino, Dines Chandra Santra, Kuo-Chuan Ho, Masayoshi Higuchi
Summary: Durable electrochromic devices driven at 0.8 V were successfully fabricated using the complementary chromic combination of Fe(II)-based metallo-supramolecular polymer (polyFe) and Prussian blue analogues (PBAs). By utilizing polyFe and NiHCF as the EC pair, a dramatic decrease in driving voltage was achieved, with S-ECD showing better durability in long term stability tests.
ACS APPLIED ELECTRONIC MATERIALS
(2021)
Article
Engineering, Electrical & Electronic
Yemineni S. L. Narayana, Sanjoy Mondal, Utpal Rana, Yoshikazu Ninomiya, Dines Chandra Santra, Takefumi Yoshida, Masayoshi Higuchi
Summary: The three-dimensionally hyperbranched Fe(II)-based metallo-supramolecular polymer (polyFe3-D) was synthesized in one step for development of durable electrochromic materials, showing wide absorption, large optical contrast, and high coloration efficiency. The polyFe3-D exhibited reversible redox reactions in cyclic voltammetry and covered a wide visible region with MLCT absorptions, demonstrating high quality and stability.
ACS APPLIED ELECTRONIC MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Md Delwar Hossain, Chanchal Chakraborty, Utpal Rana, Sanjoy Mondal, Hans-Juergen Holdt, Masayoshi Higuchi
ACS APPLIED POLYMER MATERIALS
(2020)
Article
Materials Science, Multidisciplinary
Yemineni S. L. Narayana, Utpal Rana, Chanchal Chakraborty, Takefumi Yoshida, Masayoshi Higuchi
ACS APPLIED POLYMER MATERIALS
(2020)
Article
Biochemistry & Molecular Biology
Manas Kumar Bera, Yoshikazu Ninomiya, Masayoshi Higuchi
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)
