Molybdenum-catalyzed reduction of molecular dinitrogen under mild reaction conditions

Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

(2012) Kazuya Arashiba et al.   ORGANOMETALLICS

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(iv) nitride

(2011) Travis J. Hebden et al.   CHEMICAL COMMUNICATIONS

Dinitrogen Silylation and Cleavage with a Hafnocene Complex

(2011) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum does it again

(2011) Richard R. Schrock   Nature Chemistry

Nitrido complexes step up

(2011) Yoshiaki Nishibayashi   Nature Chemistry

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Carbon-Nitrogen Bond Formation by the Reaction of 1,2-Cumulenes with a Ditantalum Complex Containing Side-On- and End-On-Bound Dinitrogen

(2010) Joachim Ballmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The hydride route to the preparation of dinitrogen complexes

(2010) Joachim Ballmann et al.   CHEMICAL COMMUNICATIONS

Carbon Monoxide-Induced Dinitrogen Cleavage with Group 4 Metallocenes: Reaction Scope and Coupling to N−H Bond Formation and CO Deoxygenation

(2010) Donald J. Knobloch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation

(2009) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Nitrogen Heterocycles Utilizing Molecular Nitrogen as a Nitrogen Source and Attempt to Use Air Instead of Nitrogen Gas

(2009) Miwako Mori   HETEROCYCLES

Alkylation of Dinitrogen in [(HIPTNCH2CH2)3N]Mo Complexes (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3)

(2009) Thomas Kupfer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex

(2009) Donald J. Knobloch et al.   Nature Chemistry

Synthesis and Protonolysis of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ruthenocenyldiphosphines

(2009) Masahiro Yuki et al.   ORGANOMETALLICS

Preparation and Protonation of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands

(2009) Masahiro Yuki et al.   ORGANOMETALLICS

Side-on End-on Bound Dinitrogen: An Activated Bonding Mode That Facilitates Functionalizing Molecular Nitrogen

(2008) Michael D. Fryzuk   ACCOUNTS OF CHEMICAL RESEARCH

Reactions at Surfaces: From Atoms to Complexity (Nobel Lecture)

(2008) Gerhard Ertl   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The chemical mechanism of nitrogenase: calculated details of the intramolecular mechanism for hydrogenation of η2-N2 on FeMo-co to NH3

(2008) Ian Dance   DALTON TRANSACTIONS

Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis

(2008) Masahiro Yuki et al.   ORGANOMETALLICS