Journal
DALTON TRANSACTIONS
Volume 41, Issue 26, Pages 7862-7865Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30176h
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- American Chemical Society Petroleum Research Fund [50395-DNI3]
- Initiative for Renewable Energy and the Environment (UM)
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The three-coordinate Ni(I) complex Ni(Cl)(P-2), where P-2 is the diphosphine (iPr)DPDBFphos, reacts with the acids HCl center dot(dioxane) and 2,6-lutidinium chloride to generate Ni(H)(Cl)(P-2) and Ni(Cl) (2)(P-2). Photolysis of the Ni(H)(X)(P-2) (for X = Cl, Br) results in formation of H-2 and the Ni(I) halide. This reaction also proceeds in reverse when heated.
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