Journal
DALTON TRANSACTIONS
Volume 41, Issue 26, Pages 7977-7983Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30676j
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Funding
- American Chemical Society Petroleum Research Fund
- University of Delaware Research Foundation
- University of Delaware
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048367] Funding Source: National Science Foundation
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The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDCMes)PdMe2 towards CO2 has been investigated. In the presence of trace H2O, this reaction yields the corresponding methyl bicarbonate complex (MDCMes)PdMe(O2COH), which goes on to give the corresponding kappa(2)-carbonato complex upon crystallization (MDCMes)Pd(CO3). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.
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