Cyclometallation of arylimines and nitrogen-containing heterocycles via room-temperature C–H bond activation with arene ruthenium(ii) acetate complexes

Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage

(2012) Yuto Hashimoto et al.   CHEMISTRY LETTERS

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Highly Regio- and Stereoselective Ruthenium(II)-Catalyzed Direct ortho-Alkenylation of Aromatic and Heteroaromatic Aldehydes with Activated Alkenes under Open Atmosphere

(2012) Kishor Padala et al.   ORGANIC LETTERS

Catalytic C–H bond arylation of aryl imines and oxazolines in water with ruthenium(II)-acetate catalyst

(2012) Bin Li et al.   TETRAHEDRON

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group

(2011) Yuto Hashimoto et al.   CHEMISTRY LETTERS

The Scope of Ambiphilic Acetate-Assisted Cyclometallation with Half-Sandwich Complexes of Iridium, Rhodium and Ruthenium

(2011) Youcef Boutadla et al.   CHEMISTRY-A EUROPEAN JOURNAL

C-H Bond Functionalization of Arylpyrimidines Catalyzed by an in situ Generated Ruthenium(II) Carboxylate System and the Construction of Tris(heteroaryl)-Substituted Benzenes

(2011) Bogdan Štefane et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium diacetate-catalysed oxidative alkenylation of C–H bonds in air: synthesis of alkenyl N-arylpyrazoles

(2011) Percia B. Arockiam et al.   GREEN CHEMISTRY

C–H bond functionalisation with [RuH(codyl)2]BF4 catalyst precursor

(2011) Wenbo Li et al.   GREEN CHEMISTRY

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

(2011) Emmanuel Ferrer Flegeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-CatalyzedOrtho-Alkenylation of Aromatic Ketones with Alkenes by C–H Bond Activation

(2011) Kishor Padala et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C−H Bond Cleavage

(2011) Takumi Ueyama et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Sequential Catalysis for the Production of Sterically Hindered Amines: Ru(II)-Catalyzed C–H Bond Activation and Hydrosilylation of Imines

(2011) Bin Li et al.   ACS Catalysis

CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

(2010) Percia B. Arockiam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Alkyne insertion into cyclometallated pyrazole and imine complexes of iridium, rhodium and ruthenium; relevance to catalytic formation of carbo- and heterocycles

(2010) Youcef Boutadla et al.   DALTON TRANSACTIONS

Insertion of nitrene and chalcogenolate groups into the Ir–C σ bond in a cyclometalated iridium(III) complex

(2010) Yiu-Keung Sau et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Chelate-Assisted Oxidative Coupling Reaction of Arylamides and Unactivated Alkenes: Mechanistic Evidence for Vinyl C−H Bond Activation Promoted by an Electrophilic Ruthenium Hydride Catalyst

(2010) Ki-Hyeok Kwon et al.   ORGANOMETALLICS

Reactions of Cyclometalated Oxazoline Half-Sandwich Complexes of Iridium and Ruthenium with Alkynes and CO

(2010) David L. Davies et al.   ORGANOMETALLICS

Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations

(2010) Lutz Ackermann et al.   SYNTHESIS-STUTTGART

Ruthenium(II) Acetate Catalyst for Direct Functionalisation of sp2-CH Bonds with Aryl Chlorides and Access to Tris- Heterocyclic Molecules

(2009) Franc Požgan et al.   ADVANCED SYNTHESIS & CATALYSIS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Diethyl carbonate as a solvent for ruthenium catalysed C–H bond functionalisation

(2009) Percia Arockiam et al.   GREEN CHEMISTRY

Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

(2009) Jonathan F. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C−H Bond Activation Catalyzed by anin SituFormed Cationic Ruthenium Hydride Complex

(2009) Chae S. Yi et al.   ORGANOMETALLICS

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2(M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

(2009) Ling Li et al.   ORGANOMETALLICS

Ortho-selective Arylation of Arylazoles with Aryl Bromides Catalyzed by Ruthenium Complexes

(2008) Shuichi Oi et al.   CHEMISTRY LETTERS

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

(2008) Ismail Özdemir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C−H and C−OH Bond Functionalizations

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

(2008) Lutz Ackermann et al.   ORGANIC LETTERS

Mechanistic Study of Acetate-Assisted C−H Activation of 2-Substituted Pyridines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2

(2008) Youcef Boutadla et al.   ORGANOMETALLICS

Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes

(2008) Shuichi Oi et al.   TETRAHEDRON