Journal
DALTON TRANSACTIONS
Volume 40, Issue 10, Pages 2167-2169Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01052a
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of the Japanese Government [20350028]
- MEXT of Japan [2107]
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The cobalt(II) compounds with long alkyl chains, [Co(C12-terpy)(2)](BF4)(2)center dot EtOH center dot 0.5H(2)O(1 center dot EtOH center dot 0.5H(2)O) and [Co(C12-terpy)(2)](BF4)(2) (1) was synthesized and characterized. The compound 1 center dot EtOH center dot 0.5H(2)O exhibits a re-entrant spin crossover. The compound 1 exhibits the re-entrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.
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