Journal
DALTON TRANSACTIONS
Volume 40, Issue 18, Pages 5073-5077Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01631d
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Funding
- Ministry of Science and Higher Education [NR 05 0005 04/2008]
- Foundation for Polish Science [Ventures/2010-6/3]
- European Regional Development Fund, Operational Program Innovative Economy [2007-2013]
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The first bi- and mononuclear rhodium(I) complexes [{Rh(mu-OSi(8)O(12)(i-Bu)(7))(cod)}(2)] (5), [Rh(cod)(PCy(3))(OSi(8)O(12)(i-Bu)(7))] (6) with a hindered hepta(iso-butyl) silsesquioxyl ligand bonded to the rhodium(I) center through Rh-O-Si bonds have been synthesized and their structures have been solved by spectroscopic methods and X-ray analysis. Their exemplary catalytic properties in silylative coupling of vinylsilanes with styrene are also presented.
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