Article
Biochemistry & Molecular Biology
Anna Irto, Paola Cardiano, Karam Chand, Rosalia Maria Cigala, Francesco Crea, Concetta De Stefano, Maria Amelia Santos
Summary: By investigating the binding ability of bifunctional 3-hydroxy-4-pyridinones with Cu2+ and Fe3+, different speciation schemes were determined, showcasing the potential selectivity of these ligands towards Fe3+ as promising iron-chelating agents. The study also suggested that 3-hydroxy-4-pyridinones could avoid competition with essential metal cations like Cu2+ and Zn2+, making them advantageous in biological and environmental applications.
Article
Chemistry, Multidisciplinary
Axel Steinbrueck, Adam C. Sedgwick, Hai-Hao Han, Michael Y. Zhao, Sajal Sen, Dan-Ying Huang, Yi Zang, Jia Li, Xiao-Peng He, Jonathan L. Sessler
Summary: In this study, strategic functionalization of the FDA approved chelator deferasirox was conducted to produce organelle-targeting iron chelators with enhanced activity against A549 lung cancer cells. Derivative 8 exhibited improved antiproliferative activity compared to the original compound 1, and was shown to preferentially localize within the lysosome through fluorescent cell imaging.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Medicinal
Minkui Zhang, Li Tang, Liu Jiang, Jun Wei, Yongzhou Hu, Rong Sheng
Summary: The newly designed compounds showed excellent H-3 receptor antagonistic activities and potent self-induced A beta aggregation inhibitory activities in vitro experiments.
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY
(2021)
Article
Neurosciences
Fakhria A. Al-Joufi, Syed Wadood Ali Shah, Mohammad Shoaib, Mehreen Ghias, Shafiullah, Atif Ali Khan Khalil, Syed Babar Jamal, Syed Muhammad Hassan Shah, Muhammad Zahoor
Summary: Flavonoids, particularly compound F5, showed potential as inhibitors of AChE and BuChE enzymes. Molecular docking analysis confirmed their stable binding affinity with the target enzymes. Additionally, these synthesized compounds demonstrated promising effects in ameliorating memory loss in animal models.
Article
Biochemistry & Molecular Biology
Maheshkumar R. Borkar, Elvis A. F. Martis, Santosh Nandan, Rajendra H. Patil, Amruta Shelar, Krishna R. Iyer, Kavita Raikuvar, Deepali Desle, Evans C. Coutinho
Summary: This study reports the synthesis and in vitro evaluation of a series of compounds against Leishmania donovani. The most active compound showed promising antileishmanial activity and stability in rat liver microsomes. Molecular modeling studies suggest a possible binding mechanism with Leishmania donovani topoisomerase 1. These findings highlight the potential of these compounds as antileishmanial agents.
CHEMICO-BIOLOGICAL INTERACTIONS
(2022)
Article
Chemistry, Medicinal
Abdelfattah Faouzi, Alexandre Arnaud, Alexandre Bancet, Caroline Barette, Jordane Preto, Cong Viet Do, Lars Petter Jordheim, Zineb Bousfiha, Thi Thanh Binh Nguyen, Marion Verriere, Amaury Farce, Marie-Odile Fauvarque, Roland Barret, Thierry Lomberget
Summary: Novel heterocyclic derivatives inspired by Combretastatin A-4 were synthesized and evaluated for their biological activities on tubulin polymerization and cell proliferation. Compounds (Z)-4h and (Z)-4j exhibited significant in cellulo tubulin polymerization inhibition and antiproliferative activities. Molecular docking studies were conducted to understand the interactions with the protein target, and apoptotic processes were observed in follicular lymphoma cells.
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Ramkishore Matsa, Parameshwar Makam, Guneswar Sethi, Ahammed Ameen Thottasseri, Aswani Raj Kizhakkandiyil, Krishna Ramadas, Vignesh Mariappan, Agieshkumar Balakrishna Pillai, Tharanikkarasu Kannan
Summary: A series of pyridine appended 2-hydrazinylthiazole derivatives were synthesized and found to have good antimycobacterial activity against Mycobacterium tuberculosis (Mtb). These compounds showed low cytotoxicity and strong binding affinity with the KasA protein of Mtb.
Article
Biochemistry & Molecular Biology
Chenxian Hu, Liu Jiang, Li Tang, Minkui Zhang, Rong Sheng
Summary: A novel series of 2-styryl-5-hydroxy-4-pyrone derivatives and analogues were designed and synthesized as multitarget-directed ligands for AD therapy, showing desirable multiple functions and high activity in biological evaluation. Promising compounds exhibited nanomolar IC50 values on H-3 receptor antagonism and efficient activities in metal ion chelating, ABTS scavenging, A beta aggregation inhibition, and disaggregation against A beta self/Cu2+-induced aggregation.
BIOORGANIC & MEDICINAL CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Chanyuan Ye, Rui Xu, Zhongcheng Cao, Qing Song, Guangjun Yu, Yichun Shi, Zhuoling Liu, Xiuxiu Liu, Yong Deng
Summary: A series of designed compounds showed potential multifunctional effects for Alzheimer's disease treatment, with compound 15b exhibiting the highest inhibitory potency and various other beneficial properties such as antioxidant capacity and neuroprotection.
BIOORGANIC CHEMISTRY
(2021)
Article
Pharmacology & Pharmacy
Chang Liu, Xiaodi Kou, Xi Wang, Jianhua Wu, Aihong Yang, Rui Shen
Summary: Alzheimer's disease is the most common type of dementia with unknown etiology. A study explored a hidden multi-target strategy to synthesize compounds for AD therapy, with compound 3 showing the highest selectivity and multiple activities, making it a potential candidate for Alzheimer's disease treatment.
EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES
(2021)
Article
Chemistry, Multidisciplinary
Samia M. M. Al-Muntaser, Ahmed A. A. Al-Karmalawy, Abeer M. M. El-Naggar, Ali Khalil Ali, Nour E. A. Abd El-Sattar, Eslam M. M. Abbass
Summary: In this study, new 4-thiophenyl-pyrazole, pyridine, and pyrimidine derivatives were designed as dual EGFR/VEGFR-2 inhibitors and evaluated for their anticancer and antimicrobial activities. Some of the compounds showed promising anticancer activities and significant dual EGFR/VEGFR-2 inhibition. Additionally, most of the compounds exhibited strong to moderate antibacterial and antifungal effects.
Article
Biochemistry & Molecular Biology
Raluca Pele, Gabriel Marc, Anca Stana, Ioana Ionut, Cristina Nastasa, Brindusa Tiperciuc, Ilioara Oniga, Adrian Pirnau, Laurian Vlase, Ovidiu Oniga
Summary: Considering the damage caused by ROS and RNS in the human body, finding new therapeutic agents with superior efficacy is crucial. Four series of new hybrid molecules were synthesized and evaluated for their antioxidant potential. Some compounds showed stronger antioxidant effects.
Article
Chemistry, Multidisciplinary
Flavia Marszaukowski, Rene T. Boere, Karen Wohnrath
Summary: This study reported the synthesis of a series of triarylphosphines and their chemical oxidation products, as well as the determination of crystal structures. By analyzing phosphine basicity and intermolecular interactions, it was found that one of the compounds exhibited the strongest basicity ever reported. Additionally, the structures were classified based on different types of intermolecular interactions, including classic H-bonding and frustration of H-bonding.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Medicinal
Aida Iraji, Zahra Panahi, Najmeh Edraki, Mahsima Khoshneviszadeh, Mehdi Khoshneviszadeh
Summary: The novel 2-hydroxy-4-methoxybenzohydrazide showed promising tyrosinase inhibitory activity, with 4d being the most potent inhibitor. In vitro experiments and molecular modeling analysis suggested that 4d could be a potential candidate for developing anti-tyrosinase agents.
DRUG DEVELOPMENT RESEARCH
(2021)
Article
Chemistry, Medicinal
Zhipei Sang, Qing Song, Zhongcheng Cao, Yong Deng, Zhenghuai Tan, Li Zhang
Summary: A series of novel dimethylamino chalcone-O-alkylamines derivatives were designed and synthesized as multifunctional agents for AD treatment, with compound TM-6 showing significant inhibitory and disaggregation abilities against Aβ aggregation. The compound also exhibited antioxidant, AChE inhibitory, and MAO-B inhibitory activities, making it a promising lead compound for AD therapy.
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY
(2021)
Article
Biochemical Research Methods
Lily Li, Julie Rousseau, Maria De Guadalupe Jaraquemada-Pelaez, Xiaozhu Wang, Andrew Robertson, Valery Radchenko, Paul Schaffer, Kuo-Shyan Lin, Francois Benard, Chris Orvig
Summary: The study focuses on the synthesis, characterization, and stability of a new undecadendate chelator H(4)py4pa and its bifunctional analog H(4)py4pa-phenyl-NCS conjugated with the monoclonal antibody Trastuzumab targeting HER2+ cancer. The complex showed excellent affinity for Ac-225 and a high thermodynamic stability, making it a promising candidate for targeted alpha therapy. Incorporation of a short phenyl-NCS linker allowed for easy attachment to Trastuzumab, resulting in excellent in vivo stability and tumor specificity.
BIOCONJUGATE CHEMISTRY
(2021)
Review
Biochemistry & Molecular Biology
Yu-Lan Li, Xiao-Min Zhu, Hong Liang, Chris Orvig, Zhen-Feng Chen
Summary: This review provides a summary of recent progress in ASGPR and GAR-mediated and/or pH-responsive HCC-targeted drug delivery. Multifunctional DDS may enhance anticancer effects, reduce side effects, but further research is needed in investigating MDR of HCC.
CURRENT MEDICINAL CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Luke Wharton, Elena Kurakina, Valery Radchenko, Paul Schaffer, Chris Orvig
Summary: This study compared two structurally related potentially nonadentate chelating ligands to examine the influence of bifunctionalization on their coordination chemistry and metal ion selectivity. Improved synthetic routes were developed for each compound, and radiolabeling studies showed significant differences in their affinity for large radiometal ions. Nuclear magnetic resonance spectroscopy and density functional theory calculations were used to explore the coordination chemistry and conformational analysis of each metal complex. Theoretical simulations revealed notable differences in coordination geometry and denticity, which explained the observed selectivity in metal binding.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Thomas Kostelnik, Hayden Scheiber, Rosita Cappai, Neha Choudhary, Felix Lindheimer, Maria de Guadalupe Jaraquemada-Pelaez, Chris Orvig
Summary: A family of phosphonate-bearing chelators was synthesized and studied for their potential in metal-based (radio)-pharmaceuticals. Both experimental and theoretical approaches were used to investigate the complexation of these ligands with metal ions, highlighting important factors affecting stability constants and structural confirmation.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Neha Choudhary, Hayden Scheiber, Jiale Zhang, Brian O. Patrick, Maria de Guadalupe Jaraquemada-Pelaez, Chris Orvig
Summary: A new octadentate chelator H(4)HBEDpa has been investigated for its chelation properties with trivalent metal ions, showing high metal-sequestering capacity for Fe3+ and susceptibility to hydrolysis for Ga3+ at higher pH. Density functional theory (DFT) calculations validated experimental findings, demonstrating tight binding of Fe(HBEDpa)- in an asymmetric pattern and the formation of octadentate complexes with larger metal ions like Lu3+.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Khrystyna Herasymchuk, Magali Allain, Gregory A. MacNeil, Vincent Carre, Frederic Aubriet, Daniel B. Leznoff, Marc Salle, Sebastien Goeb, Tim Storr
Summary: The study explored the incorporation of a redox-active nickel salen complex into supramolecular structures by coordination-driven self-assembly with homobimetallic ruthenium complexes. The formation of a discrete rectangle and either a rectangle or a catenane depended on the solvent and concentration. Analysis through electrochemical experiments, UV-Vis-NIR absorption, EPR spectroscopy, and DFT calculations confirmed ligand radical formation and provided further insights into the geometric and electronic structures in solution.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Lily Southcott, Lily Li, Brian O. Patrick, Holger Stephan, Maria de Guadalupe Jaraquemada-Pelaez, Chris Orvig
Summary: This study reports a highly stable [Zr(pypa)] complex, synthesized and characterized using various techniques. The complex demonstrates excellent thermodynamic stability and radiolabeling efficiency in vivo, is antibody-compatible, and maintains stability under challenging conditions.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Aidan Ingham, Luke Wharton, Tarek El Sayed, Lily Southcott, Brooke L. McNeil, Maria B. Ezhova, Brian O. Patrick, Maria de Guadalupe Jaraquemada-Pelaez, Chris Orvig
Summary: A new chelator H(2)ampa was designed and synthesized as a potential radiopharmaceutical chelator. The study investigated its coordination behavior with radioactive metals and found that H(2)ampa can effectively coordinate Bi3+, Pb2+, and La3+ ions to form metal complexes, demonstrating its potential application in radiopharmaceutical labeling.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Diego Martelino, Samyadeb Mahato, Warren VandeVen, Nicholas M. Hein, Ryan M. Clarke, Gregory A. MacNeil, Fabrice Thomas, Tim Storr
Summary: The oxidation location (metal or ligand) of Cr-V nitride salen complexes with different para-phenolate substituents was found to determine the reactivity of the nitride. One-electron oxidation results in Cr-VI nitrides and localized Cr-V nitride phenoxyl radicals, while oxidation to CrVI complexes leads to umpolung in reactivity.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Biochemistry & Molecular Biology
Kalvin Kwan, Omar Castro-Sandoval, Christian Gaiddon, Tim Storr
Summary: The p53 protein plays a crucial role in preventing genome mutations, but it is often mutated in cancer, leading to malfunction in the p53 pathway. Mutant p53 protein not only loses its activity, but also tends to unfold and aggregate, forming amyloid aggregates. This review discusses recent advancements in developing small-molecule stabilizers of mutant p53 protein and inhibitors of p53 aggregation.
CURRENT OPINION IN CHEMICAL BIOLOGY
(2023)
Article
Biochemistry & Molecular Biology
Jessica J. Miller, Kalvin Kwan, Christophe Orvain, Georg Mellitzer, Jason Smith, Cristina Lento, Lucienne Nouchikian, Sabrina Omoregbee-Leichnitz, Marie Sabatou, Derek Wilson, Christian Gaiddon, Tim Storr
Summary: The p53 protein is important in cancer prevention, but mutations can compromise its activity. New ligands L5-P and L5-O were found to exhibit significant cytotoxicity in the Y220C mutant cells by generating reactive oxygen species (ROS).
JOURNAL OF INORGANIC BIOCHEMISTRY
(2023)
Review
Biochemistry & Molecular Biology
Jessica J. Miller, Kalvin Kwan, Christian Gaiddon, Tim Storr
Summary: Metal ion dysregulation plays an important role in various diseases, especially cancer. The role of zinc in the function of the p53 protein in cancer is critical. Understanding zinc binding and developing metallochaperones is vital for restoring mutant p53 function.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Lily Southcott, Chris Orvig
Summary: 8-Hydroxyquinoline is a versatile compound with impressive metal chelating abilities, utilized in various fields such as medicine, nuclear medicine, and nanotechnology. Recent research has focused on its potential to chelate larger radiometal ions with longer half-lives and different indications.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Janaina C. Bataglioli, Luiza M. F. Gomes, Camille Maunoir, Jason R. Smith, Houston D. Cole, Julia McCain, Tariq Sainuddin, Colin G. Cameron, Sherri A. McFarland, Tim Storr
Summary: This study investigates the impact of photoactivation of Ru(II) polypyridyl complexes on the aggregation profile of the A beta peptide in Alzheimer's disease. The results show that this process can change the aggregation spectrum of A beta peptide, accelerating the formation of amorphous aggregates and limiting the formation of oligomeric species.
Article
Chemistry, Inorganic & Nuclear
Lily Southcott, Xiaozhu Wang, Luke Wharton, Hua Yang, Valery Radchenko, Manja Kubeil, Holger Stephan, Maria de Guadalupe Jaraquemada-Pelaez, Chris Orvig
Summary: Advances in nuclear medicine depend on chelating ligands that form highly stable and kinetically inert complexes with relevant radiometal ions for use in diagnosis or therapy. A new decadentate ligand, H(5)decaox, showed high affinity for In3+ and Zr4+, promising radiolabeling yields and structural stability in serum.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)