Article
Green & Sustainable Science & Technology
Muhammet Omer Dis
Summary: The study fills data gaps by establishing a new meteorological station and using Class A evaporation pan observations, and utilizes an artificial intelligence model to process the continuous evaporation data nonlinearly. Evaluation shows that temperature and wind-driven simulations have the highest correlation and performance compared to solely precipitation-based models in predicting evaporation.
Article
Chemistry, Physical
Dibyendu Mahato, Lalita Sharma, Rajesh Srivastava
Summary: This study investigates the elastic scattering of electrons from various ions using a model potential approach. By calculating and analyzing the potential energies, the differential cross sections obtained show prominent interference structures and good agreement with experimental results in selected energy ranges.
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
(2022)
Article
Chemistry, Physical
Johannes Oschwald, David Reger, Stefan Fruehwald, Vera Warmbrunn, Andreas Goerling, Norbert Jux, Thomas Drewello
Summary: Gas-phase complexes of [n]helicenes with n=6, 7 and 8 and the silver(I) cation were generated using electrospray ionization mass spectrometry (ESI-MS). In addition to the well-established [1:1] helicene/Ag+-complex, a [2:1] complex was also formed, where the second helicene attaches to the first helicene via n-n stacking in the pre-formed [1:1] tweezer complex with Ag+.
Article
Computer Science, Information Systems
Nadir Maaroufi, Mehdi Najib, Mohamed Bakhouya
Summary: This article introduces a new forecasting method called FM2I, based on image completion, for time series forecasting. Extensive experimental evaluation shows that FM2I is efficient and accurate in short-term time series forecasting, outperforming methods from M3 and M4 competitions in terms of accuracy.
Article
Chemistry, Multidisciplinary
Yihan Ding, Jianmin Jiao, Baobao Sun, Zhen Yang, Chen Lin, Leyong Wang
Summary: The mixture of p-(methoxy)calix[n]arenes was prepared in one step under basic conditions, and their fully methylated derivatives were also obtained and purified. The single crystal of p-(dimethyloxy)calix[7]arene was successfully obtained and its structure confirmed. Different reaction conditions were investigated to determine the proportion of p-(methoxy)calix[6]-, [7]- and [8]-arenes in the mixture, with the ability to separate p-(methoxy)calix[6]- and [8]-arenes. Additionally, the host-guest interaction of p(dimethyloxy)calix[6]arene with methyl-4,4'-bipyridinium hexafluorophosphate in organic solvents was studied.
CHINESE CHEMICAL LETTERS
(2021)
Article
Biochemistry & Molecular Biology
Anastasia Khandazhinskaya, Barbara Eletskaya, Anton Mironov, Irina Konstantinova, Olga Efremenkova, Sofya Andreevskaya, Tatiana Smirnova, Larisa Chernousova, Evgenia Kondrashova, Alexander Chizhov, Katherine Seley-Radtke, Sergey Kochetkov, Elena Matyugina
Summary: A variety of flexible derivatives of 8-aza-7-deazahypoxanthine were synthesized and screened for antibacterial activity. Some of the compounds showed significant inhibition against the growth of Mycobacterium tuberculosis.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Environmental Sciences
Li Pan, Haoming Xia, Xiaoyang Zhao, Yan Guo, Yaochen Qin
Summary: By utilizing time series data and phenological characteristics, this study extracted winter crop planting information in China in 2019. It shows that the phenology-based algorithm is reliable and accurate for large area crop classification.
Article
Chemistry, Multidisciplinary
Li-Fei Tian, Ming Liu, Li-Xia Chen, Chao Huang, Qian-Jiang Zhu, Kai Chen, Jiang-Lin Zhao, Zhu Tao
Summary: The outer surface interaction of Q[n]s (OSIQ) is a key strategy for constructing supramolecular frameworks. In this study, we have successfully developed a Q[8]/SC[6]A-based supramolecular framework with high stability and selective capture of specific metal cations, which has potential applications in various fields.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Satoru Muramatsu, Keijiro Ohshimo, Yuan Shi, Motoki Kida, Rong Shang, Yohsuke Yamamoto, Fuminori Misaizu, Yoshiya Inokuchi
Summary: In this study, the electronic and geometrical structures of hypervalent penta-coordinate carbon compounds were characterized using gas-phase techniques. The coexistence of tetra- and penta-coordinate isomers was confirmed for a compound with moderately electron-donating ligands, consistent with solution characterizations. This difference depends on the environment and reflects the lower activation barrier of the S(N)2 reaction found in neutral solvent or gas-phase reactions.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Physics, Nuclear
R. Lichtenthaler, O. C. B. Santos, A. Serra, U. Umbelino, K. C. C. Pires, J. R. B. Oliveira, A. Lepine-Szily, P. N. de Faria, V. Morcelle
Summary: The research team at the Radioactive Ion Beams facility in Brasil conducted experiments with secondary radioactive beams He-6, Be-7, Li-8 and B-8, focusing on elastic scattering, reaction measurements, and a preliminary Coulomb excitation experiment.
EUROPEAN PHYSICAL JOURNAL A
(2021)
Article
Virology
Yi Zheng, Youyun Zhao, Yefu Wang, Jun Rao
Summary: Fluorescent quantitative PCR assay is widely used for detecting viral DNA, but a new method has been developed to simultaneously detect HHV-6, 7, and 8. Through blood sample collection and PCR optimization, a triple fluorescent quantitative PCR detection system was constructed for the simultaneous detection of HHV-6, 7, and 8. The method showed good specificity and sensitivity in blood transfusion screening.
Article
Chemistry, Physical
Mhejabeen Sayed, Dilip Kumar Maity, Haridas Pal
Summary: The influence of two versatile macrocyclic hosts, CB7 and CB8, on the photophysical properties of DAPI has been studied. CB7 forms 1:1 dye-host complexes, while CB8 forms both 1:1 and 2:1 complexes. The differential binding stoichiometries of the complexes are responsible for the large differences observed in the photophysical properties of DAPI.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Chemistry, Medicinal
Xavier Fradera, Qiaolin Deng, Abdelganhi Achab, Yudith Garcia, Solomon D. Kattar, Meredeth A. McGowan, Joey L. Methot, Kevin Wilson, Hua Zhou, Lynsey Shaffer, Peter Goldenblatt, Vincent Tong, Martin A. Augustin, Michael D. Altman, Charles A. Lesburg, Sanjiv Shah, Jason D. Katz
Summary: This study describes the discovery and optimization process of a novel series of PI3K-6 selective inhibitors, which were identified using a virtual screening workflow and improved for potency and selectivity guided by structural data. The careful optimization of molecular properties led to compounds with high potency in a whole blood assay.
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Matteo Briganti, Eva Lucaccini, Laura Chelazzi, Samuele Ciattini, Lorenzo Sorace, Roberta Sessoli, Federico Totti, Mauro Perfetti
Summary: The research identified a new trend named the f(n+7) effect, where magnetic complexes differing by seven f electrons exhibit similar magnetic anisotropy orientations. Experiments and theory confirmed the alignment of magnetic reference frames, and explained hidden similarities between ions with seemingly different shapes of magnetic anisotropy.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Inorganic & Nuclear
Nicholas B. Beck, Zhuanling Bai, Jacob P. Brannon, Daniela Gomez Martinez, Dennis Groedler, Brian N. Long, Todd N. Poe, Brian M. Rotermund, Thomas E. Albrecht-Schoenzart, Joseph M. Sperling
Summary: Two polymorphs of neptunium(III) mellitate compounds have been synthesized and characterized, confirming their structure and oxidation state. One polymorph is stable in air, while the other slowly oxidizes.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Tasnim Rahman, Enric Petrus, Mireia Segado, Nicolas P. Martin, Lauren N. Palys, Mark A. Rambaran, C. Andre Ohlin, Carles Bo, May Nyman
Summary: Anomalous solubility behavior of alkali-POMs has been discovered and successfully predicted using computation and simulation, providing guidelines for the discovery of new POMs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Medicinal
Connor A. Lejcher, Eric M. Villa, James T. Fletcher
Summary: This study presents 1,3,4-trisubstituted-1,2,3-triazolium salts exhibiting antimicrobial properties as well as visible emission characteristics. By incorporating various aryl units at the N1 position, visible emission properties were imparted to the salts with significant Stokes shifts. The hydrophobic aryl units showed impact on the minimum inhibitory concentration (MIC) values against bacteria and yeast, which could be adjusted by substituent variation to maintain bioactivity.
MEDICINAL CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Sarah N. Dishman, Croix J. Laconsay, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
Summary: Intramolecular C-H insertions with donor/donor dirhodium carbenes provide a concise and highly stereoselective method to set two contiguous stereocenters in a single step. The study demonstrates that donor/donor carbenes undergo uniquely stereoselective reactions that originate from a stepwise reaction mechanism, in contrast to the analogous concerted reactions of carbenes with one or more electron-withdrawing groups attached.
Article
Physics, Multidisciplinary
Jackson R. Badger, Yundi Quan, Matthew C. Staab, Shuntaro Sumita, Antonio Rossi, Kasey P. Devlin, Kelly Neubauer, Daniel S. Shulman, James C. Fettinger, Peter Klavins, Susan M. Kauzlarich, Dai Aoki, Inna M. Vishik, Warren E. Pickett, Valentin Taufour
Summary: Unconventional superconductors have Cooper pairs with lower symmetries compared to conventional superconductors. This article demonstrates that the time-reversal symmetry breaking in the superconductor LaNiGa2 is enabled by its previously unknown topological electronic band structure. These unique topological features allow LaNiGa2 to break time-reversal symmetry in the absence of other typical ingredients, providing a pathway for identifying a new type of unconventional superconductors based on nonsymmorphic symmetries.
COMMUNICATIONS PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Benjamin D. Bergstrom, Amy T. Merrill, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
Summary: This article reports the first synthesis methods of Panowamycins and their epimers, and reveals the previous structural misassignment of panowamycin A and veramycin F. The researchers achieved these synthesis methods through dirhodium-catalyzed C-H insertion reactions and Wacker oxidation, avoiding the use of protecting groups.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Allan He, Zihao Shen, Haozhe Wang, Weiwei Xie, Zhen Wang, Luis Garay, James C. Fettinger, Raphael P. Hermann, Yimei Zhu, Valentin Taufour, Susan M. Kauzlarich
Summary: The new Eu(5)Al(3)Sh(6) phase has been synthesized as a pure phase with large, high-quality crystals using Sn flux methods. The structure features disordered Al clusters in the form of dual tetrahedra and exhibits unique electronic properties. Evaluation of its properties includes magnetic behavior, oxidation states, and electronic structure calculations.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Inorganic & Nuclear
Wenxing Zou, James C. Fettinger, Petra Vasko, Philip P. Power
Summary: A series of heteroleptic aryl copper(I) thiolato complexes were synthesized and characterized, with some complexes exhibiting unconventional structural arrangements. The structural features and reactivity of the complexes are influenced by the aryl groups present.
Article
Crystallography
Matthieu R. Spriet, Matthew J. Polinski, Brandon Q. Mercado, Eric M. Villa
Summary: Two polyoxometalate-based compounds containing the heptamolybdate anion and cobalt(II) have been synthesized and characterized through X-ray diffraction and spectroscopic analysis. The structures of these compounds are unique and significant within the field of polyoxometalates.
Article
Chemistry, Multidisciplinary
Lilia M. Baldauf, James C. Fettinger, Marilyn M. Olmstead, Kamran B. Ghiassi, Alan L. Balch
Summary: Two new cocrystals, named 1 and 2, were discovered with a clamshell arrangement of two porphyrins surrounding a central C70 molecule. Cocrystal 1 has a unique double-clamshell arrangement, while cocrystal 2 has a simple clamshell arrangement.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Inorganic & Nuclear
Rongqing Shang, Allan He, Elizabeth L. Kunz Wille, Na Hyun Jo, James C. Fettinger, Paul C. Canfield, Susan M. Kauzlarich
Summary: The solid solutions of Yb14ZnSb11 with different RE3+ elements were prepared to investigate the intermediate valency of Yb in Yb14ZnSb11. The substitution of Yb with RE3+ elements can impact the valency of Yb ions. Large crystals were grown using Sn-flux, the structure and magnetic susceptibility were studied. The results showed that all compounds crystallize in the Ca14AlSb11 structure type and the RE3+ ions exhibit a size-dependent preference for substitution at the Yb site.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Connor P. McLoughlin, James C. Fettinger, Philip P. Power
Summary: Six new transition-metal aryloxides were synthesized and characterized to compare the steric and dispersive characteristics of their substituents. The results show that the -C6H2-2,4,6-Cy-3 substituent has higher dispersive energy donor properties and influences the thermal stability. Complexes 1 and 2 exhibit high thermal stability and short-contact H···H interactions, while complexes 5 and 6 have a lower association number due to the lower dispersion energy donor properties of the -OC6H3-2,6-Pr-i (2) ligand.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Alice C. Phung, James C. Fettinger, Philip P. Power
Summary: A series of ferriostannylenes with different iron and/or tin substituents were synthesized and their structures and spectroscopic properties were investigated. The results showed that the substituents have significant effects on the structure and properties of the compounds.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Leo W. T. Parsons, James C. C. Fettinger, Louise A. A. Berben
Summary: This study explores N-alkylation and N-metallation of pyridine to understand how metal-ligand complexes can mimic NAD(+) redox chemistry. The syntheses of substituted dipyrazolylpyridine (pz(2)P) compounds (pz(2)P)Me+ (1(+)) and (pz(2)P)GaCl2+ (2(+)) are reported and compared with previous transition element pz(2)P complexes. Cyclic voltammetry measurements show that cationic 1(+) and 2(+) exhibit irreversible reduction events at an anodic potential of SIM;900 mV, unlike the neutral pz(2)P complexes of divalent metals.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Mingchun Gao, Jose M. Ruiz, Emily Jimenez, Anna Lo, Croix J. Laconsay, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
Summary: Substrates designed for 1,4-C-H insertion to produce benzocyclobutenes underwent a unique elimination reaction, resulting in the formation of ortho-quinone dimethide (o-QDM) intermediates that further participated in Diels-Alder or hetero-Diels-Alder cycloadditions. The analogous benzylic acetals or ethers, on the other hand, bypassed the C-H insertion pathway and, after hydride transfer, underwent a de-aromatizing elimination reaction to form o-QDM at ambient temperature. The resulting dienes exhibited high diastereo- and regio-selectivity when involved in various cycloaddition reactions. This method represents a rare example of catalytic o-QDM generation without the involvement of a benzocyclobutene, and it offers a mild and ambient temperature approach to access these valuable intermediates. DFT calculations provided support for the proposed mechanism. Furthermore, this methodology was successfully applied to the synthesis of (+/-)-isolariciresinol with an overall yield of 41%.
Article
Chemistry, Multidisciplinary
Wenxing Zou, Kristian L. Mears, James C. Fettinger, Philip P. Power
Summary: Thermal Sn-C cleavage in diarylstannylene Sn(Ar-iPr4)(2) was used to generate radicals for alkyne arylstannylation. The reaction produced aryl vinyl stannylene complexes with different substituents and a known distannene.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)
