Journal
DALTON TRANSACTIONS
Volume -, Issue 33, Pages 4424-4427Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b802259n
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One electron oxidation of dialkyl diselenides and ditellurides is achieved with NO+CF3SO3-. According to ab initio calculations the radical cations have a trans stucture. In the solid state they dimerize to rectangular units [R - Te](4)(2+) and [R - Se](4)(2+). The long Se center dot center dot center dot Se and Te center dot center dot center dot Te bond is obviously due to a pi(*) - pi(*) interaction.
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