Article
Chemistry, Inorganic & Nuclear
Dinh Cao Huan Do, Nemanja Dordevic, Han Vinh Huynh
Summary: Attempts to prepare mixed isothiocyanato-bis(imido) Mo-VI complexes led to the discovery of post-metathesis rearrangements towards three distinct products. The construction of the [Mo((NBu)-Bu-t)2(NCS)2] core was ultimately possible in the presence of additional stabilizing donors.
INORGANIC CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Nils Boysen, Jan-Lucas Wree, David Zanders, Detlef Rogalla, Denis Oehl, Wolfgang Schuhmann, Anjana Devi
Summary: A new method of synthesizing iridium thin films with high crystallinity and conductivity using metalorganic chemical vapor deposition (MOCVD) was reported. These iridium films demonstrated excellent electrochemical performance for catalytic hydrogen evolution reaction (HER) in acidic solutions.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Inorganic & Nuclear
James D. Parish, Michael W. Snook, Andrew L. Johnson
Summary: A family of tin(ii) heteroleptic complexes and homoleptic systems were successfully synthesized and structurally characterized. NMR spectroscopy and single-crystal X-ray diffraction studies were used for comprehensive characterization. Thermal behavior of the complexes was investigated to determine their suitability as ALD precursors for SnO thin films deposition.
DALTON TRANSACTIONS
(2021)
Article
Physics, Applied
Qingqing Chen, Shaoyan Yang, Chengming Li, Weizhen Yao, Xianglin Liu, Huidan Niu, Rui Yang, Huijie Li, Hongyuan Wei, Lianshan Wang, Zhanguo Wang
Summary: This study reported the deposition of ZrN films on GaN/Si templates using MOCVD and analyzed the effect of substrate temperature on its growth mode, film stress, and electrical properties. Surface morphology and film roughness of the ZrN epilayers were found to vary with substrate temperature. Stress information obtained from XRD diffraction indicated the presence of large in-plane lattice stretching in the ZrN film and compressive stress in the GaN/Si template. XPS analysis showed a clear interface between the ZrN epilayer and GaN/Si template. Hall tests confirmed that the resistivity of the ZrN thin film can reach a minimum value at high temperatures.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2022)
Article
Polymer Science
Jian Tang, Zijian Xu, Zelong Liu, Yuan Fu, Jing Hua
Summary: Aluminum-based transition-metal-free catalysts have been extensively studied for alpha-olefin polymerization, but they face challenges in conjugated dienes polymerization. In this study, we developed a series of aluminum-based catalyst precursors for 1,3-butadiene polymerization, achieving high catalytic activity and selectivity. The microstructures of the resulting polymers could be controlled by adjusting the ligands.
Article
Chemistry, Physical
Chang Gao, Yujing Ran, Qian Guo, Tianrun Wang, Huiping Lu, Zhaotan Jiang, Zhi Wang
Summary: NbNx films were prepared by dual ion beam sputter deposition to modulate their structural and dielectric properties. Assisting ions can improve crystallinity, reduce energy loss, and lead to tunable dual epsilon-near-zero behavior in the films. Tailoring plasmonic properties with assisting ions allows NbNx films to be applied in various fields.
SURFACES AND INTERFACES
(2021)
Article
Chemistry, Inorganic & Nuclear
Michael A. . Land, Goran Bacic, Katherine N. Robertson, Sean T. Barry
Summary: The thermal decomposition mechanism of a series of volatile bis(alkylimido)-dichloromolybdenum(VI) adducts with neutral N,N'-chelating ligands has been investigated, revealing their decomposition pathways and stabilities.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Justin C. Wedal, Joseph W. Ziller, William J. Evans
Summary: In this study, the U(v) imido complex 1 was observed for the first time by crystallography, providing new insights into the reaction mechanisms of U(III) compounds with azide reagents.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Benedikt Koestler, Felix Jungwirth, Luisa Achenbach, Masiar Sistani, Michael Bolte, Hans-Wolfram Lerner, Philipp Albert, Matthias Wagner, Sven Barth
Summary: A series of new mixed-substituted heteronuclear precursors with preformed Si-Ge bonds have been synthesized, showing potential for tailoring physical and chemical properties for the deposition of Si1-xGex coatings through CVD techniques. Partial crystallization of Si1-xGex has been achieved by Ga metal-supported CVD growth.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
A. Roniboss, S. Sindhu, L. John Kennedy, S. Arockiasamy
Summary: Two Schiff's base complexes were synthesized and characterized. The complexes were found to have molecular masses of 580 and 636 Da for 1 and 2 respectively. Both complexes underwent single step volatilization in an inert N-2 atmosphere. Furthermore, complex 2 was successfully used as a precursor for the formation of Co3O4 thin film via a plasma assisted CVD method.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Jeong Min Hwang, Na Yeon Kim, Sunyoung Shin, Ji Hun Lee, Ji Yeon Ryu, Taeyong Eom, Bo Keun Park, Chang Gyoun Kim, Taek-Mo Chung
Summary: Novel Nb(V) tBu-imido/N-alkoxy carboxamide complexes were successfully synthesized and characterized, serving as potential precursors for Nb-containing thin films. These complexes exhibited superior thermal characteristics and were able to be distilled or sublimed for thin film fabrication.
Article
Chemistry, Physical
Ufuk Atamturk, Eunhwan Jung, Thomas Fischer, Sanjay Mathur
Summary: This study reports on the application of two bismuth alkylthiolates as single-source precursors for Bi2S3 and Bi in the chemical vapor deposition process. Despite similar structural chemistry and composition, these compounds exhibited distinct properties during low-temperature decomposition. The resulting deposits were identified as Bi2S3 and Bi through various analysis techniques, and were found to have excellent orientation and uniform shape.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Inorganic & Nuclear
Kanchana Chatchaipaiboon, Kotohiro Nomura
Summary: New niobium(V)-alkylidene complexes were prepared and found to exhibit superior catalytic activities for ring-opening metathesis polymerization (ROMP) reactions. One of the complexes also showed Z-specific ROMP activity for cis-cyclooctene at high temperature.
Article
Chemistry, Inorganic & Nuclear
Ga Yeon Lee, Seungmin Yeo, Chan-Mi Cho, Seung Hoon Oh, Hyeonbin Park, Bo Keun Park, Seung Uk Son, Taeyong Eom, Taek-Mo Chung
Summary: This paper reports the synthesis of three novel titanium complexes containing amidoxime ligands for the fabrication of titanium nitride (TiN) thin films via atomic layer deposition (ALD). The ligands were successfully synthesized and used to produce the complexes, and the liquid complex 5 was used as a precursor for the synthesis of TiN thin films. The deposition of TiN thin films was achieved with self-limiting growth and resulted in smooth and well-oriented microstructure.
INORGANIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Xuepei Wang, Zhengang Wu, Yingna Wei, Mingming Wu, Ying Chen, Shilei Hu, Yuan Pei, Yi Cui, Dongfeng Lv, Yuejun Chen, Hengyong Wei, Jinglong Bu
Summary: Niobium nitride thin films, synthesized as novel substrates for surface-enhanced Raman spectroscopy via reduction nitridation of Nb(2)O5 thin films, exhibit excellent SERS performance and optical properties, with optimal results achieved at 800 degrees C.
Article
Chemistry, Multidisciplinary
Pia Vervoorts, Julian Keupp, Andreas Schneemann, Claire L. Hobday, Dominik Daisenberger, Roland A. Fischer, Rochus Schmid, Gregor Kieslich
Summary: Flexible metal-organic frameworks (MOFs) exhibit large structural flexibility with temperature or pressure variations, which is of high technological and scientific significance. The targeted design of flexible MOFs requires control over macroscopic thermodynamics determined by microscopic chemical interactions, presenting a challenge. This study reveals configurational entropy from linker side-chain modifications as a crucial factor in determining the thermodynamics of flexible MOFs, offering a new perspective on accessing the free energy landscape in MOFs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Lena Staiger, Tim Kratky, Sebastian Guenther, Ondrej Tomanek, Radek Zboril, Richard W. Fischer, Roland A. Fischer, Mirza Cokoja
Summary: Phosphanes have been found to increase both the reaction rate and selectivity towards olefins, with the ligand's steric and electronic effects playing a crucial role in catalyst performance.
Article
Chemistry, Physical
Min Tu, Benzheng Xia, Dmitry E. Kravchenko, Max Lutz Tietze, Alexander John Cruz, Ivo Stassen, Tom Hauffman, Joan Teyssandier, Steven De Feyter, Zheng Wang, Roland A. Fischer, Benedetta Marmiroli, Heinz Amenitsch, Ana Torvisco, Miriam de J. Velasquez-Hernandez, Paolo Falcaro, Rob Ameloot
Summary: Metal-organic frameworks (MOFs) show disruptive potential in micro- and optoelectronics due to their unique properties. Direct X-ray and electron-beam lithography can achieve high-resolution patterning in MOFs, maintaining their porosity and crystallinity intact for potential integration in miniaturized devices.
Article
Chemistry, Inorganic & Nuclear
Joao Guilherme M. de Carvalho, Roland A. Fischer, Alexander Poethig
Summary: In this study, a dipyridyl-substituted anthraquinone was incorporated into crystalline coordination networks, with the oxidation state of the organic linker selectively controlled and maintained in the solid state through hydrogen bonding. The anthraquinone-anthrahydroquinone redox pair was shown to be reversibly switched even after incorporation in the solid state, with the formation of hydrogen peroxide from molecular oxygen during the oxidation process.
INORGANIC CHEMISTRY
(2021)
Review
Chemistry, Physical
Weijin Li, Soumya Mukherjee, Baohui Ren, Rong Cao, Roland A. Fischer
Summary: Open framework materials (OFMs) in the form of thin films have great potential as electrocatalysts, but their development is still in its early stages, with a need for further research. Controlling the thickness, roughness, and particle sizes of the films is crucial for their electrocatalytic activities.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Anna Lisa Semrau, Philip M. Stanley, Dominik Huber, Michael Schuster, Bauke Albada, Han Zuilhof, Mirza Cokoja, Roland A. Fischer
Summary: Vectorial catalysis, controlling multi-step reactions in a programmed sequence with defined spatial localization, is a challenging goal in bio-inspired catalysis research. This study demonstrates the integration of two different surface-anchored nanometer-sized metal-organic frameworks in a microfluidic device for modeling vectorial catalysis, achieving full conversion and high turnover frequencies in a two-step cascade reaction.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Physical
Haneesh Saini, Eva Otyepkova, Andreas Schneemann, Radek Zboril, Michal Otyepka, Roland A. Fischer, Kolleboyina Jayaramulu
Summary: Oil contaminated water is a global issue, and metal-organic frameworks (MOFs) with special wettability show promising potential for oil/water separation. Their highly tunable structure and properties make them suitable for various applications in oily water treatment.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Review
Electrochemistry
Soumya Mukherjee, Shujin Hou, Sebastian A. Watzele, Batyr Garlyyev, Weijin Li, Aliaksandr S. Bandarenka, Roland A. Fischer
Summary: Taking into account the United Nations Sustainable Development Goal 7 on affordable and clean energy, metal-organic frameworks (MOFs) and derived materials have attracted research interest in electrocatalysis. This review summarizes recent advances in MOF-based electrocatalysts exclusively prepared through indirect post-treatments.
Review
Electrochemistry
Xing Ding, Theophilus Kobina Sarpey, Shujin Hou, Batyr Garlyyev, Weijin Li, Roland A. Fischer, Aliaksandr S. Bandarenka
Summary: Understanding processes, phenomena, and mechanisms at the electrode/electrolyte interface is crucial for optimizing electrochemical systems. The introduction of sub-microsecond laser pulses has simplified the investigation of the electrochemical interface, and the laser-induced current transient and laser-induced potential transient techniques have proven to be valuable tools.
Article
Chemistry, Multidisciplinary
Shujin Hou, Lili Xu, Xing Ding, Regina M. Kluge, Theophilus Kobina Sarpey, Richard W. Haid, Batyr Garlyyev, Soumya Mukherjee, Julien Warnan, Max Koch, Shengli Zhang, Weijin Li, Aliaksandr S. Bandarenka, Roland A. Fischer
Summary: Understanding the electrode/electrolyte interface is crucial for optimizing electrocatalytic performances. The nature of alkali metal cations has been found to have a profound impact on the oxygen evolution activity of SURMOF derived electrocatalysts based on NiFe(OOH). The effects of cation-dependent electric double layer properties on activity were studied using a laser-induced current transient technique. Electrolyte composition can be used to maximize the performance of SURMOF derivatives in electrochemical water splitting.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Patricia Heiss, Julius Hornung, Christian Gemel, Roland A. Fischer
Summary: The formation of Hume-Rothery-inspired intermetallic and all-hydrocarbon-ligated Ni/E clusters (E = Al, Ga) was studied using a combinatorial, coordination-modulated approach. Insight into the chemical complexity generated during cluster nucleation and growth was obtained through mass spectrometric monitoring of the reaction solutions.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Zhiying Fan, Lena Staiger, Karina Hemmer, Zheng Wang, Weijia Wang, Qianjie Xie, Lunjia Zhang, Alexander Urstoeger, Michael Schuster, Johannes A. Lercher, Mirza Cokoja, Roland A. Fischer
Summary: The embedding of metal nanoparticles in metal-organic frameworks (MOFs) is crucial in catalysis research, as it prevents agglomeration and allows for functionalization of the MOF matrix to optimize the chemical environment. In this study, Pd nanoparticles were incorporated into the MOF CuBTC by encapsulation, and the hydrophobicity was adjusted by using functionalized linkers. These modifications significantly improved the catalytic activity, suggesting that channel engineering is an efficient way to optimize metal@MOF catalysts.
CELL REPORTS PHYSICAL SCIENCE
(2022)
Review
Chemistry, Multidisciplinary
Soumya Mukherjee, K. K. R. Datta, Roland A. Fischer
Summary: Water, while essential for life, negatively impacts the performance of solid adsorbents/catalysts in its vapor and liquid forms. Recent advancements in high surface hydrophobicity have led to the realization of water-stable MOFs. The critical analysis of hydrophobic MOFs and their composites provides a promising outlook for future applications in energy and environmental sustainability.
TRENDS IN CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Maximilian Muhr, Patricia Heiss, Max Schuetz, Raphael Buehler, Christian Gemel, Mathias H. Linden, H. Bernhard Linden, Roland A. Fischer
Summary: The new setup combining a ThermoFisher Exactive Plus Orbitrap Mass Spectrometer with a LIFDI source allows for the analysis of sensitive organometallic complexes. The detection of oxygen traces and mass spectrometric analysis of Cu/Al cluster mixtures are successfully conducted using this setup.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Werner R. Heinz, Dominik Staude, David Mayer, Hana Bunzen, Roland A. Fischer
Summary: The study successfully synthesized univalent Ru-HKUST-1 samples using a controlled secondary building unit approach, resulting in high crystalline domain sizes, compositional purity, and BET surface area close to the ideal HKUST-1 parent structure.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)